Concept explainers
(a)
Interpretation: The highest-energy species in the reactants and the highest-energy species in the products should be circled and explanation about reason behind no uphill curve even when generation of oxygen with a uni-negative charge occurs in below reaction should be given.
Concept introduction: Energetics of a reaction describes the energy associated with different components during the process of reaction. Energy diagram is a plot of energy along y-axis and reaction coordinate along x axis. Reaction proceeds when the reactant molecules collide and have proper orientation. The pathway from reactant to product involves transition state. A transition state is a hypothetical state that gives clear picture of the orientation of reactant molecules during collision that is a process of the bonds formed and broken during the reaction. Transition state is the highest energy state of a reaction.
The intermediate involved usually have higher potential energy than reactants species as they are formed transiently and fall back to form products that are more stable and hence reduced in potential energy.
(d)
Interpretation: Energy diagram that best describes the below reaction should be identified.
Concept introduction: Energetics of a reaction describes the energy associated with different components during the process of reaction. Energy diagram is a plot of energy along y-axis and reaction coordinate along x axis. Reaction proceeds when the reactant molecules collide and have proper orientation. The pathway from reactant to product involves transition state. A transition state is a hypothetical state that gives clear picture of the orientation of reactant molecules during collision that is a process of the bonds formed and broken during the reaction. Transition state is the highest energy state of a reaction.
The intermediate involved usually have higher potential energy than reactants species as they are formed transiently and fall back to form products that are more stable and hence reduced in potential energy.
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Organic Chemistry: A Guided Inquiry
- For each reaction below, decide if the first stable organic product that forms in solution will create a new C - C bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. NH2 Домове Will the first product that forms in this reaction create a new C - C bond? ? O Yes Ο No Will the first product that forms in this reaction create a new C - C bond? Yes ○ No Click and drag to start drawing a structure. : Хarrow_forwardDraw both resonance structures of the most stable carbocation intermediate in the reaction shown. + HCI You do not have to consider stereochemistry. • Do not include anionic counter-ions, e.g., I, in your answer. • • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right Separate resonance structures using the symbol from the drop-down menu. ← - CHA ? n ChemDoodlearrow_forwardFor each reaction below, decide if the first stable organic product that forms in solution will create a new C-C bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions just focus on the first stable product you expect to form in solution. MgBr NH2 MgCl ? Will the first product that forms in this reaction create a new C-C bond? Yes No Will the first product that forms in this reaction create a new C-C bond? Yes No Click and drag to start drawing a structure. Π : X G P 5arrow_forward
- Draw the major 1,2- and 1,4-addition products obtained in the reaction shown. Assume that both are derived from the most stable carbocation intermediate. +. HBr You do not have to consider stereochemistry. •You do not have to explicitly draw H atoms. If the 1,2- and 1,4- addition products are the same due to symmetry, only draw one structure. Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. • Separate multiple products using the - sign from the drop-down menu. C. opy a3te, P.arrow_forward2. For each of the following pair of reactions, CIRCLE the reaction that will occur faster (A or B). A A A H. 1 Br Br CH3ONa CH3OH NaCN ACN Nal DMSO B B B |||||| Br CI Br CH3ONa CH3OH NaCN ACN Nal DMSOarrow_forwardDraw both resonance structures of the most stable carbocation intermediate in the reaction shown. Please circle the one I need to draw in the space below.arrow_forward
- Draw the simplest mechanism possible for the reaction below. You may need to re-draw structures to show bond lines or lone pairs.arrow_forwardGiven the reactant Br−Br, add curved arrows to show homolytic bond cleavage, then draw the expected product. Be sure to add any charges and nonbonding electrons that result from the cleavage.arrow_forwardDrawing Reaction Mechanism Arrowsarrow_forward
- Part 1 Identify any nucleophiles and electrophiles in this reaction. How will they react together? Do all curved arrows start at an electron-rich site and point toward an electron-poor site? Did you add non-zero charges and lone pair electrons to all appropriate atoms? Does the overall charge and number of atoms remain consistent from step-to-step? To bring a box back to its original status, click on the reset button in the top left corner of the drawing window. x i :0:arrow_forwardWrite the systematic (IUPAC) name for each of the following organic molecules: structure OH CH3 CH3-C-CH₂-CH-CH3 OH CH3 CH3 HỌ–CH,—CH–CH,—CH–CH2–CH2CH2CH2OH CH3 HO–CH2CHCH3 name 0 0 0arrow_forwardFor each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. NH2 MgBr Will the first product that forms in this reaction create a new CC bond? 1。 MgBr 00 Yes ○ No ? Will the first product that forms in this reaction create a new CC bond? ○ Yes ○ No. Click and drag to start drawing a structure. ✗ ח' :arrow_forward
- Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning