Introduction to General, Organic and Biochemistry
11th Edition
ISBN: 9781285869759
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher: Cengage Learning
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Chapter 3, Problem 3.99P
3-99 Knowing what you do about covalent bonding in compounds of carbon, nitrogen, and oxygen and given the fact that silicon is just below carbon in the Periodic Table, phosphorus is just below nitrogen, and sulfur is just below oxygen, predict the molecular formula for the compound formed by (a) silicon and chlorine, (b) phosphorus and hydrogen, and (c) sulfur and hydrogen.
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Write the formula of the compound that will be formed between
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6. Write formulas for the following compounds, all of which contain polyatomic ions.
(i)
strontium sulfate
(ii)
copper(II) nitrate
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calcium carbonate
(iv)
potassium hydroxide
(v)
iron(III) cyanide
(vi)
zinc nitrite
(vii)
ammonium phosphate
(viii) rubidium sulfite
(ix)
sodium peroxide
(x)
potassium dichromate
(хі)
sodium amide
(xii) potassium permanganate
(xiii) lead(II) chromate
(xiv) aluminium sulfate
(xv)
lithium phosphate
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barium sulfate
(xvii) strontium hydrogencarbonate
Chapter 3 Solutions
Introduction to General, Organic and Biochemistry
Ch. 3.2 - Problem 3-1 Show how the following chemical...Ch. 3.4 - Problem 3-2 Judging from their relative positions...Ch. 3.5 - Problem 3-3 Write the formulas for the ionic...Ch. 3.6 - Problem 3-4 Name these binary ionic compounds: (a)...Ch. 3.6 - Prob. 3.5PCh. 3.6 - Problem 3-6 Give each binary compound a systematic...Ch. 3.6 - Problem 3-7 Name these ionic compounds, each of...Ch. 3.7 - Prob. 3.8PCh. 3.7 - Prob. 3.9PCh. 3.7 - Prob. 3.10P
Ch. 3.7 - Prob. 3.11PCh. 3.8 - Prob. 3.12PCh. 3.9 - Prob. 3.13PCh. 3.9 - Prob. 3.14PCh. 3.10 - Problem 3-15 Predict all bond angles for these...Ch. 3.11 - Problem 3-16 Which of these molecules are polar?...Ch. 3 - 3-17 Answer true or false. (a) The octet rule...Ch. 3 - 3-18 How many electrons must each atom gain or...Ch. 3 - 3-19 Show how each chemical change obeys the octet...Ch. 3 - 3-20 Show how each chemical change obeys the octet...Ch. 3 - 3-21 Write the formula for the most stable ion...Ch. 3 - 3-22 Why is Li- not a stable ion?Ch. 3 - 3-23 Predict which ions are stable: (a) (b) (c)...Ch. 3 - 3-24 Predict which ions are stable: (a) Br2- (b)...Ch. 3 - 3-25 Why are carbon and silicon reluctant to form...Ch. 3 - 3-26 Table 3-2 shows the following ions of copper:...Ch. 3 - 3-27 Answer true or false. (a) For Group lA and...Ch. 3 - 3-28 Name each polyatomic ion. (a) HCO3- (b) NO2-...Ch. 3 - 3-29 Answer true or false. (a) According to the...Ch. 3 - Prob. 3.30PCh. 3 - 3-31 Why does electronegativity generally increase...Ch. 3 - 3-32 Judging from their relative positions in the...Ch. 3 - Prob. 3.33PCh. 3 - 3-34 Which of these bonds is the most polar? The...Ch. 3 - 3-35 Classify each bond as nonpolar covalent,...Ch. 3 - 3-36 Classify each bond as nonpolar covalent,...Ch. 3 - 3-37 Answer true or false. (a) An ionic bond is...Ch. 3 - 3-38 Complete the chart by writing formulas for...Ch. 3 - 3-39 Write a formula for the ionic compound formed...Ch. 3 - Prob. 3.40PCh. 3 - 3-41 Describe the structure of sodium chloride in...Ch. 3 - 3-42 What is the charge on each ion in these...Ch. 3 - 3-43 Write the formula for the compound formed...Ch. 3 - 3-44 Write the formula for the ionic compound...Ch. 3 - 3-45 Which formulas are not correct? For each that...Ch. 3 - 3-46 Which formulas are not correct? For each that...Ch. 3 - 3-47 Answer true or false. (a) The name of a...Ch. 3 - 3-48 Potassium chloride and potassium bicarbonate...Ch. 3 - Prob. 3.49PCh. 3 - 3-50 Name the polyatomic ion(s) in each compound....Ch. 3 - 3-51 Write the formulas for the ions present in...Ch. 3 - Prob. 3.52PCh. 3 - 3-53 Write formulas for the following ionic...Ch. 3 - 3-54 Write formulas for the following ionic...Ch. 3 - Prob. 3.55PCh. 3 - 3-56 How many covalent bonds are normally formed...Ch. 3 - 3-57 What is: (a) A single bond? (b) A double...Ch. 3 - 3-58 In Section 2-3B, we saw that there are seven...Ch. 3 - Prob. 3.59PCh. 3 - Prob. 3.60PCh. 3 - Prob. 3.61PCh. 3 - Prob. 3.62PCh. 3 - 3-63 What is the difference between (a) a bromine...Ch. 3 - 3-64 Acetylene (C2H2), hydrogen cyanide (HCN), and...Ch. 3 - Prob. 3.65PCh. 3 - 3-66 Why can’t second-row elements have more than...Ch. 3 - 3-67 Why does nitrogen have three bonds and one...Ch. 3 - 3-68 Draw a Lewis structure of a covalent compound...Ch. 3 - Prob. 3.69PCh. 3 - 3-70 Draw a Lewis structure of a covalent compound...Ch. 3 - Prob. 3.71PCh. 3 - Prob. 3.72PCh. 3 - Prob. 3.73PCh. 3 - 3-74 Answer true or false. (a) A binary covalent...Ch. 3 - Prob. 3.75PCh. 3 - Prob. 3.76PCh. 3 - 3-77 Ozone, O3, is an unstable blue gas with a...Ch. 3 - 3-78 Nitrous oxide, N20, laughing gas, is a...Ch. 3 - 3-79 Answer true or false. (a) The letters VSEPR...Ch. 3 - Prob. 3.80PCh. 3 - Prob. 3.81PCh. 3 - 3-82 Hydrogen and nitrogen combine in different...Ch. 3 - Prob. 3.83PCh. 3 - Prob. 3.84PCh. 3 - Prob. 3.85PCh. 3 - Prob. 3.86PCh. 3 - 3-87 Consider the molecule boron trffluoride, BF3....Ch. 3 - Prob. 3.88PCh. 3 - 3-89 Is it possible for a molecule to have no...Ch. 3 - Prob. 3.90PCh. 3 - Prob. 3.91PCh. 3 - Prob. 3.92PCh. 3 - Prob. 3.93PCh. 3 - Prob. 3.94PCh. 3 - Prob. 3.95PCh. 3 - Prob. 3.96PCh. 3 - Prob. 3.97PCh. 3 - Prob. 3.98PCh. 3 - 3-99 Knowing what you do about covalent bonding in...Ch. 3 - Prob. 3.100PCh. 3 - Prob. 3.101PCh. 3 - Prob. 3.102PCh. 3 - Prob. 3.103PCh. 3 - Prob. 3.104PCh. 3 - 3-105 Consider the structure of Vitamin E shown...Ch. 3 - 3-106 Consider the structure of Penicillin G shown...Ch. 3 - 3-107 Ephedrine, a molecule at one time found in...Ch. 3 - Prob. 3.108PCh. 3 - 3-109 Until several years ago, the two...Ch. 3 - 3-110 Name and write the formula for the fluorine...Ch. 3 - Prob. 3.111PCh. 3 - Prob. 3.112PCh. 3 - Prob. 3.113PCh. 3 - Prob. 3.114PCh. 3 - Prob. 3.115PCh. 3 - Prob. 3.116PCh. 3 - Prob. 3.117PCh. 3 - Prob. 3.118PCh. 3 - 3-119 Perchloroethylene, which is a liquid at room...Ch. 3 - 3-120 Vinyl chloride is the starting material for...Ch. 3 - 3-121 Tetrafluoroethylene is the starting material...Ch. 3 - 3-122 Some of the following structural formulas...Ch. 3 - 3-123 Sodium borohydride, NaBH4, has found wide...Ch. 3 - Prob. 3.124PCh. 3 - Prob. 3.125PCh. 3 - Prob. 3.126PCh. 3 - 3-127 Amoxicillin is an antibiotic used to treat...Ch. 3 - Prob. 3.128P
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- 3-77 Ozone, O3, is an unstable blue gas with a characteristic pungent odor. In an ozone molecule, the connectivity of the atoms is OOO and both OO bonds are equivalent. (a) How many valence electrons must be present in an acceptable Lewis structure for an ozone molecule? (b) Write two equivalent resonance contributing structures for ozone. Be certain to show any positive or negative charges that may be present in your contributing structures. By equivalent contributing structures, we mean that each has the same pattern of bonding. (c) Show by the use of curved arrows how the first of your contributing structures may be converted to the second. (d) Based on your contributing structures, predict the OOO bond angle in ozone. (e) Explain why the following is not an acceptable contributing structure for an ozone molecule:arrow_forward3-119 Perchloroethylene, which is a liquid at room temperature, is one of the most widely used solvents for commercial dry cleaning. It is sold for this purpose under several trade names, including Perciene®. Does this molecule have polar bonds? Is it a polar molecule? Does it have a dipole?arrow_forward2-98 Explain how the ionization energy of atoms changes when proceeding down a group of the Periodic Table and explain why this change occurs.arrow_forward
- 2-97 Explain why the Ca3+ ion is not found in chemical compounds.arrow_forward2-59 You are presented with a Lewis dot structure of element X as X.. To which two groups in the Periodic Table might this element belong?arrow_forward3-63 What is the difference between (a) a bromine atom, (b) a bromine molecule, and (c) a bromide ion? Draw the Lewis structure for each.arrow_forward
- 3-54 Write formulas for the following ionic compounds: (a) Ammonium hydrogen sulfite (b) Magnesium acetate (c) Strontium dihydrogen phosphate (d) Silver carbonate (e) Strontium chloride (f) Barium permanganate (g) Aluminum perchioratearrow_forward3-78 Nitrous oxide, N20, laughing gas, is a colorless, nontoxic, tasteless, and odorless gas. It is used as an inhalation anesthetic in dental and other surgeries. Because nitrous oxide is soluble in vegetable oils (fats), it is used commercially as a propellant in whipped toppings Nitrous oxide dissolves in fats. The gas is added under pressure to cans of whipped topping. When the valve is opened, the gas expands, thus expanding (whipping) the topping and forcing it out of the can. (a) How many valence electrons are present in a molecule of N20? (b) Write two equivalent contributing structures for this molecule. The connectivity in nitrous oxide is NNO. (c) Explain why the following is not an acceptable contributing structure:arrow_forwardPredict which of the following compounds are ionic and which are covalent, based on the location of their constituent atoms in the periodic table: (a) CI2CO (b) MnO (c) Nd3 (d) CoBr2 (e) K2S (f) CO (g) CaF2 (h) HI (j) CaO (j) IBr (k) CO2arrow_forward
- Calculate the molecular mass of the compounds represented by the chemical structures. Round to the hundredths place. Lines represent bonds between adjacent atoms. Caffeine molecular mass of caffeine: CH, amu H,C CH CH3 Epinephrine molecular mass of epinephrine: amu HO-CH-CH,-NH-CH, HC CH HC, HO, ОН Question Sourco: McOarrow_forwardCan you please help me with these two question ?arrow_forwardWrite formulas for ionic compounds. (a) What is the formula of the ionic compound expected to form between the elements sodium and fluorine? (b) What is the formula of the compound formed between the ions Co²+ and SO₂²? (c) What ions make up the ionic compound Zn(CN)₂? Cation formula Anion formulaarrow_forward
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