(a) Interpretation: The Lewis structure for cyclopropane having molecular formula C 3 H 6 is to be drawn. Concept Introduction: During the formation of a compound each atom tends to lose, gain or share enough electrons to achieve an electronic configuration having eight valence electrons. This rule is also known as octet rule. The number of electrons present in outermost shell of an atom which are available for bonding are known as valence electrons. For a molecule, total number of valence electrons will be sum of valence electrons of each atom present in the molecule. A Lewis structure is representation of distribution of electrons on each atom of the molecule. Some of the electrons are shared by atoms to form bonds and some exist as lone pair which do not take part in bonding.

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Answer 1

Question

Chapter 3, Problem 3.128P

Interpretation Introduction

(a)

Interpretation:

The Lewis structure for cyclopropane having molecular formula C₃ H₆ is to be drawn.

Concept Introduction:

During the formation of a compound each atom tends to lose, gain or share enough electrons to achieve an electronic configuration having eight valence electrons. This rule is also known as octet rule. The number of electrons present in outermost shell of an atom which are available for bonding are known as valence electrons. For a molecule, total number of valence electrons will be sum of valence electrons of each atom present in the molecule.

A Lewis structure is representation of distribution of electrons on each atom of the molecule. Some of the electrons are shared by atoms to form bonds and some exist as lone pair which do not take part in bonding.

Interpretation Introduction

(b)

Interpretation:

Using VSEPR Theory, the geometry of each central atom present in given structure of Cyclopropane is to be identified.

Concept Introduction:

Bond angles in the molecules can be predicted by using valence shell electron pair repulsion (VSEPR) model. According to this model, the valence electrons of an atom are involved in the formation of single, double or triple bond. The valence electrons can also be unshared and exist as lone pair on atoms. The combination forms a negatively charged region of electron density around a nucleus. Since, like charges do not attract, the region of electron density around a nucleus spread out so that each atom is as far away from each other at different angles.

Interpretation Introduction

(c)

Interpretation:

Using VSEPR theory, the various relative bond angles associated with each central atom of the Cyclopropane molecule is to be determined.

Concept Introduction:

Bond angles in the molecules can be predicted by using valence shell electron pair repulsion (VSEPR) model. According to this model, the valence electrons of an atom are involved in the formation of single, double or triple bond. The valence electrons can also be unshared and exist as lone pair on atoms. The combination forms a negatively charged region of electron density around a nucleus. Since, like charges do not attract, the region of electron density around a nucleus spread out so that each atom is as far away from each other at different angles.

Interpretation Introduction

(d)

Interpretation:

Observing the given the shape and size of the Cyclopropane ring, the bond angle for C−C−C is to be predicted.

Concept Introduction:

Bond angle of the molecules can be predicted by using valence shell electron pair repulsion (VSEPR) model.

Interpretation Introduction

(e)

Interpretation:

A proper explanation with reason is to be given, why cyclopropane is considerably less stable than other three-carbon compounds that do not contain a ring.

Concept Introduction:

Bond angle of the molecules can be predicted by using valence shell electron pair repulsion (VSEPR) model.

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Draw the Lewis structure of C2H4O

a) 5. Circle all acidic (and anticoplanar to the Leaving group) protons in the following molecules, Solve these elimination reactions, and identify the major and minor products where appropriate: 20 points + NaOCH3 Br (2 product

Answer 2

Question

Chapter 3, Problem 3.128P

Interpretation Introduction

(a)

Interpretation:

The Lewis structure for cyclopropane having molecular formula C₃ H₆ is to be drawn.

Concept Introduction:

During the formation of a compound each atom tends to lose, gain or share enough electrons to achieve an electronic configuration having eight valence electrons. This rule is also known as octet rule. The number of electrons present in outermost shell of an atom which are available for bonding are known as valence electrons. For a molecule, total number of valence electrons will be sum of valence electrons of each atom present in the molecule.

A Lewis structure is representation of distribution of electrons on each atom of the molecule. Some of the electrons are shared by atoms to form bonds and some exist as lone pair which do not take part in bonding.

Interpretation Introduction

(b)

Interpretation:

Using VSEPR Theory, the geometry of each central atom present in given structure of Cyclopropane is to be identified.

Concept Introduction:

Bond angles in the molecules can be predicted by using valence shell electron pair repulsion (VSEPR) model. According to this model, the valence electrons of an atom are involved in the formation of single, double or triple bond. The valence electrons can also be unshared and exist as lone pair on atoms. The combination forms a negatively charged region of electron density around a nucleus. Since, like charges do not attract, the region of electron density around a nucleus spread out so that each atom is as far away from each other at different angles.

Interpretation Introduction

(c)

Interpretation:

Using VSEPR theory, the various relative bond angles associated with each central atom of the Cyclopropane molecule is to be determined.

Concept Introduction:

Bond angles in the molecules can be predicted by using valence shell electron pair repulsion (VSEPR) model. According to this model, the valence electrons of an atom are involved in the formation of single, double or triple bond. The valence electrons can also be unshared and exist as lone pair on atoms. The combination forms a negatively charged region of electron density around a nucleus. Since, like charges do not attract, the region of electron density around a nucleus spread out so that each atom is as far away from each other at different angles.

Interpretation Introduction

(d)

Interpretation:

Observing the given the shape and size of the Cyclopropane ring, the bond angle for C−C−C is to be predicted.

Concept Introduction:

Bond angle of the molecules can be predicted by using valence shell electron pair repulsion (VSEPR) model.

Interpretation Introduction

(e)

Interpretation:

A proper explanation with reason is to be given, why cyclopropane is considerably less stable than other three-carbon compounds that do not contain a ring.

Concept Introduction:

Bond angle of the molecules can be predicted by using valence shell electron pair repulsion (VSEPR) model.

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Answer 3

Question

Chapter 3, Problem 3.128P

Interpretation Introduction

(a)

Interpretation:

The Lewis structure for cyclopropane having molecular formula C₃ H₆ is to be drawn.

Concept Introduction:

During the formation of a compound each atom tends to lose, gain or share enough electrons to achieve an electronic configuration having eight valence electrons. This rule is also known as octet rule. The number of electrons present in outermost shell of an atom which are available for bonding are known as valence electrons. For a molecule, total number of valence electrons will be sum of valence electrons of each atom present in the molecule.

A Lewis structure is representation of distribution of electrons on each atom of the molecule. Some of the electrons are shared by atoms to form bonds and some exist as lone pair which do not take part in bonding.

Interpretation Introduction

(b)

Interpretation:

Using VSEPR Theory, the geometry of each central atom present in given structure of Cyclopropane is to be identified.

Concept Introduction:

Bond angles in the molecules can be predicted by using valence shell electron pair repulsion (VSEPR) model. According to this model, the valence electrons of an atom are involved in the formation of single, double or triple bond. The valence electrons can also be unshared and exist as lone pair on atoms. The combination forms a negatively charged region of electron density around a nucleus. Since, like charges do not attract, the region of electron density around a nucleus spread out so that each atom is as far away from each other at different angles.

Interpretation Introduction

(c)

Interpretation:

Using VSEPR theory, the various relative bond angles associated with each central atom of the Cyclopropane molecule is to be determined.

Concept Introduction:

Bond angles in the molecules can be predicted by using valence shell electron pair repulsion (VSEPR) model. According to this model, the valence electrons of an atom are involved in the formation of single, double or triple bond. The valence electrons can also be unshared and exist as lone pair on atoms. The combination forms a negatively charged region of electron density around a nucleus. Since, like charges do not attract, the region of electron density around a nucleus spread out so that each atom is as far away from each other at different angles.

Interpretation Introduction

(d)

Interpretation:

Observing the given the shape and size of the Cyclopropane ring, the bond angle for C−C−C is to be predicted.

Concept Introduction:

Bond angle of the molecules can be predicted by using valence shell electron pair repulsion (VSEPR) model.

Interpretation Introduction

(e)

Interpretation:

A proper explanation with reason is to be given, why cyclopropane is considerably less stable than other three-carbon compounds that do not contain a ring.

Concept Introduction:

Bond angle of the molecules can be predicted by using valence shell electron pair repulsion (VSEPR) model.

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Answer 4

Question

Chapter 3, Problem 3.128P

Interpretation Introduction

(a)

Interpretation:

The Lewis structure for cyclopropane having molecular formula C₃ H₆ is to be drawn.

Concept Introduction:

During the formation of a compound each atom tends to lose, gain or share enough electrons to achieve an electronic configuration having eight valence electrons. This rule is also known as octet rule. The number of electrons present in outermost shell of an atom which are available for bonding are known as valence electrons. For a molecule, total number of valence electrons will be sum of valence electrons of each atom present in the molecule.

A Lewis structure is representation of distribution of electrons on each atom of the molecule. Some of the electrons are shared by atoms to form bonds and some exist as lone pair which do not take part in bonding.

Interpretation Introduction

(b)

Interpretation:

Using VSEPR Theory, the geometry of each central atom present in given structure of Cyclopropane is to be identified.

Concept Introduction:

Bond angles in the molecules can be predicted by using valence shell electron pair repulsion (VSEPR) model. According to this model, the valence electrons of an atom are involved in the formation of single, double or triple bond. The valence electrons can also be unshared and exist as lone pair on atoms. The combination forms a negatively charged region of electron density around a nucleus. Since, like charges do not attract, the region of electron density around a nucleus spread out so that each atom is as far away from each other at different angles.

Interpretation Introduction

(c)

Interpretation:

Using VSEPR theory, the various relative bond angles associated with each central atom of the Cyclopropane molecule is to be determined.

Concept Introduction:

Bond angles in the molecules can be predicted by using valence shell electron pair repulsion (VSEPR) model. According to this model, the valence electrons of an atom are involved in the formation of single, double or triple bond. The valence electrons can also be unshared and exist as lone pair on atoms. The combination forms a negatively charged region of electron density around a nucleus. Since, like charges do not attract, the region of electron density around a nucleus spread out so that each atom is as far away from each other at different angles.

Interpretation Introduction

(d)

Interpretation:

Observing the given the shape and size of the Cyclopropane ring, the bond angle for C−C−C is to be predicted.

Concept Introduction:

Bond angle of the molecules can be predicted by using valence shell electron pair repulsion (VSEPR) model.

Interpretation Introduction

(e)

Interpretation:

A proper explanation with reason is to be given, why cyclopropane is considerably less stable than other three-carbon compounds that do not contain a ring.

Concept Introduction:

Bond angle of the molecules can be predicted by using valence shell electron pair repulsion (VSEPR) model.

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Answer 5

Chapter 3, Problem 3.128P

Interpretation Introduction

(a)

Interpretation:

The Lewis structure for cyclopropane having molecular formula C₃ H₆ is to be drawn.

Concept Introduction:

During the formation of a compound each atom tends to lose, gain or share enough electrons to achieve an electronic configuration having eight valence electrons. This rule is also known as octet rule. The number of electrons present in outermost shell of an atom which are available for bonding are known as valence electrons. For a molecule, total number of valence electrons will be sum of valence electrons of each atom present in the molecule.

A Lewis structure is representation of distribution of electrons on each atom of the molecule. Some of the electrons are shared by atoms to form bonds and some exist as lone pair which do not take part in bonding.

Interpretation Introduction

(b)

Interpretation:

Using VSEPR Theory, the geometry of each central atom present in given structure of Cyclopropane is to be identified.

Concept Introduction:

Bond angles in the molecules can be predicted by using valence shell electron pair repulsion (VSEPR) model. According to this model, the valence electrons of an atom are involved in the formation of single, double or triple bond. The valence electrons can also be unshared and exist as lone pair on atoms. The combination forms a negatively charged region of electron density around a nucleus. Since, like charges do not attract, the region of electron density around a nucleus spread out so that each atom is as far away from each other at different angles.

Interpretation Introduction

(c)

Interpretation:

Using VSEPR theory, the various relative bond angles associated with each central atom of the Cyclopropane molecule is to be determined.

Concept Introduction:

Bond angles in the molecules can be predicted by using valence shell electron pair repulsion (VSEPR) model. According to this model, the valence electrons of an atom are involved in the formation of single, double or triple bond. The valence electrons can also be unshared and exist as lone pair on atoms. The combination forms a negatively charged region of electron density around a nucleus. Since, like charges do not attract, the region of electron density around a nucleus spread out so that each atom is as far away from each other at different angles.

Interpretation Introduction

(d)

Interpretation:

Observing the given the shape and size of the Cyclopropane ring, the bond angle for C−C−C is to be predicted.

Concept Introduction:

Bond angle of the molecules can be predicted by using valence shell electron pair repulsion (VSEPR) model.

Interpretation Introduction

(e)

Interpretation:

A proper explanation with reason is to be given, why cyclopropane is considerably less stable than other three-carbon compounds that do not contain a ring.

Concept Introduction:

Bond angle of the molecules can be predicted by using valence shell electron pair repulsion (VSEPR) model.

Answer 6

Chapter 3, Problem 3.128P

Interpretation Introduction

(a)

Interpretation:

The Lewis structure for cyclopropane having molecular formula C₃ H₆ is to be drawn.

Concept Introduction:

During the formation of a compound each atom tends to lose, gain or share enough electrons to achieve an electronic configuration having eight valence electrons. This rule is also known as octet rule. The number of electrons present in outermost shell of an atom which are available for bonding are known as valence electrons. For a molecule, total number of valence electrons will be sum of valence electrons of each atom present in the molecule.

A Lewis structure is representation of distribution of electrons on each atom of the molecule. Some of the electrons are shared by atoms to form bonds and some exist as lone pair which do not take part in bonding.

Answer 7

Chapter 3, Problem 3.128P

Interpretation Introduction

(a)

Interpretation:

The Lewis structure for cyclopropane having molecular formula C₃ H₆ is to be drawn.

Concept Introduction:

During the formation of a compound each atom tends to lose, gain or share enough electrons to achieve an electronic configuration having eight valence electrons. This rule is also known as octet rule. The number of electrons present in outermost shell of an atom which are available for bonding are known as valence electrons. For a molecule, total number of valence electrons will be sum of valence electrons of each atom present in the molecule.

A Lewis structure is representation of distribution of electrons on each atom of the molecule. Some of the electrons are shared by atoms to form bonds and some exist as lone pair which do not take part in bonding.

Answer 8

Interpretation Introduction

(b)

Interpretation:

Using VSEPR Theory, the geometry of each central atom present in given structure of Cyclopropane is to be identified.

Concept Introduction:

Bond angles in the molecules can be predicted by using valence shell electron pair repulsion (VSEPR) model. According to this model, the valence electrons of an atom are involved in the formation of single, double or triple bond. The valence electrons can also be unshared and exist as lone pair on atoms. The combination forms a negatively charged region of electron density around a nucleus. Since, like charges do not attract, the region of electron density around a nucleus spread out so that each atom is as far away from each other at different angles.

Answer 9

Interpretation Introduction

(b)

Interpretation:

Using VSEPR Theory, the geometry of each central atom present in given structure of Cyclopropane is to be identified.

Concept Introduction:

Bond angles in the molecules can be predicted by using valence shell electron pair repulsion (VSEPR) model. According to this model, the valence electrons of an atom are involved in the formation of single, double or triple bond. The valence electrons can also be unshared and exist as lone pair on atoms. The combination forms a negatively charged region of electron density around a nucleus. Since, like charges do not attract, the region of electron density around a nucleus spread out so that each atom is as far away from each other at different angles.

Answer 10

Interpretation Introduction

(c)

Interpretation:

Using VSEPR theory, the various relative bond angles associated with each central atom of the Cyclopropane molecule is to be determined.

Concept Introduction:

Bond angles in the molecules can be predicted by using valence shell electron pair repulsion (VSEPR) model. According to this model, the valence electrons of an atom are involved in the formation of single, double or triple bond. The valence electrons can also be unshared and exist as lone pair on atoms. The combination forms a negatively charged region of electron density around a nucleus. Since, like charges do not attract, the region of electron density around a nucleus spread out so that each atom is as far away from each other at different angles.

Answer 11

Interpretation Introduction

(c)

Interpretation:

Using VSEPR theory, the various relative bond angles associated with each central atom of the Cyclopropane molecule is to be determined.

Concept Introduction:

Bond angles in the molecules can be predicted by using valence shell electron pair repulsion (VSEPR) model. According to this model, the valence electrons of an atom are involved in the formation of single, double or triple bond. The valence electrons can also be unshared and exist as lone pair on atoms. The combination forms a negatively charged region of electron density around a nucleus. Since, like charges do not attract, the region of electron density around a nucleus spread out so that each atom is as far away from each other at different angles.

Answer 12

Interpretation Introduction

(d)

Interpretation:

Observing the given the shape and size of the Cyclopropane ring, the bond angle for C−C−C is to be predicted.

Concept Introduction:

Bond angle of the molecules can be predicted by using valence shell electron pair repulsion (VSEPR) model.

Answer 13

Interpretation Introduction

(d)

Interpretation:

Observing the given the shape and size of the Cyclopropane ring, the bond angle for C−C−C is to be predicted.

Concept Introduction:

Bond angle of the molecules can be predicted by using valence shell electron pair repulsion (VSEPR) model.

Answer 14

Interpretation Introduction

(e)

Interpretation:

A proper explanation with reason is to be given, why cyclopropane is considerably less stable than other three-carbon compounds that do not contain a ring.

Concept Introduction:

Bond angle of the molecules can be predicted by using valence shell electron pair repulsion (VSEPR) model.

Answer 15

Interpretation Introduction

(e)

Interpretation:

A proper explanation with reason is to be given, why cyclopropane is considerably less stable than other three-carbon compounds that do not contain a ring.

Concept Introduction:

Bond angle of the molecules can be predicted by using valence shell electron pair repulsion (VSEPR) model.

Answer 16

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Answer 17

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Answer 18

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Answer 19

Ch. 3.2 - Problem 3-1 Show how the following chemical...Ch. 3.4 - Problem 3-2 Judging from their relative positions...Ch. 3.5 - Problem 3-3 Write the formulas for the ionic...Ch. 3.6 - Problem 3-4 Name these binary ionic compounds: (a)...Ch. 3.6 - Prob. 3.5P Ch. 3.6 - Problem 3-6 Give each binary compound a systematic...Ch. 3.6 - Problem 3-7 Name these ionic compounds, each of...Ch. 3.7 - Prob. 3.8P Ch. 3.7 - Prob. 3.9P Ch. 3.7 - Prob. 3.10P

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(d)

Interpretation:

Observing the given the shape and size of the Cyclopropane ring, the bond angle for C−C−C is to be predicted.

Concept Introduction:

Bond angle of the molecules can be predicted by using valence shell electron pair repulsion (VSEPR) model.

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Chapter 3 Solutions

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(d) Interpretation: Observing the given the shape and size of the Cyclopropane ring, the bond angle for C−C−C is to be predicted. Concept Introduction: Bond angle of the molecules can be predicted by using valence shell electron pair repulsion (VSEPR) model.

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Chapter 3 Solutions

(d)

Interpretation:

Observing the given the shape and size of the Cyclopropane ring, the bond angle for C−C−C is to be predicted.

Concept Introduction:

Bond angle of the molecules can be predicted by using valence shell electron pair repulsion (VSEPR) model.