(a) Interpretation: The given statements are true or false should be determined. Concept Introduction: Polarity of any molecule depends on electronegativity of atoms that forms covalent bonds. Depending upon the difference in electronegativity of atoms, polar or nonpolar molecule is determined. Polar molecule has electronegativity between 0.5 and 1.4 whereas in nonpolar molecule, it is less than 0.5.

Question

Q6: Predict the effect of the changes given on the rate of the reaction below. CH3OH CH3Cl + NaOCH3 → CH3OCH3 + NaCl a) Change the substrate from CH3CI to CH31: b) Change the nucleophile from NaOCH 3 to NaSCH3: c) Change the substrate from CH3CI to (CH3)2CHCI: d) Change the solvent from CH3OH to DMSO.

Answer 1

Question

Chapter 3, Problem 3.85P

Interpretation Introduction

(a)

Interpretation:

The given statements are true or false should be determined.

Concept Introduction:

Polarity of any molecule depends on electronegativity of atoms that forms covalent bonds. Depending upon the difference in electronegativity of atoms, polar or nonpolar molecule is determined. Polar molecule has electronegativity between 0.5 and 1.4 whereas in nonpolar molecule, it is less than 0.5.

Interpretation Introduction

(b)

Interpretation:

The given statements are true or false should be determined.

Concept Introduction:

Polarity of any molecule depends on electronegativity of atoms that forms covalent bonds. Depending upon the difference in electronegativity of atoms, polar or nonpolar molecule is determined. Polar molecule has electronegativity between 0.5 and 1.4 whereas in nonpolar molecule, it is less than 0.5.

Interpretation Introduction

(c)

Interpretation:

The given statements are true or false should be determined.

Concept Introduction:

Polarity of any molecule depends on electronegativity of atoms that forms covalent bonds. Depending upon the difference in electronegativity of atoms, polar or nonpolar molecule is determined. Polar molecule has electronegativity between 0.5 and 1.4 whereas in nonpolar molecule, it is less than 0.5.

Interpretation Introduction

(d)

Interpretation:

The given statements are true or false should be determined.

Concept Introduction:

Polarity of any molecule depends on electronegativity of atoms that forms covalent bonds. Depending upon the difference in electronegativity of atoms, polar or nonpolar molecule is determined. Polar molecule has electronegativity between 0.5 and 1.4 whereas in nonpolar molecule, it is less than 0.5.

Interpretation Introduction

(e)

Interpretation:

The given statements are true or false should be determined.

Concept Introduction:

Polarity of any molecule depends on electronegativity of atoms that forms covalent bonds. Depending upon the difference in electronegativity of atoms, polar or nonpolar molecule is determined. Polar molecule has electronegativity between 0.5 and 1.4 whereas in nonpolar molecule, it is less than 0.5.

Interpretation Introduction

(f)

Interpretation:

The given statements are true or false should be determined.

Concept Introduction:

Polarity of any molecule depends on electronegativity of atoms that forms covalent bonds. Depending upon the difference in electronegativity of atoms, polar or nonpolar molecule is determined. Polar molecule has electronegativity between 0.5 and 1.4 whereas in nonpolar molecule, it is less than 0.5.

Interpretation Introduction

(g)

Interpretation:

The given statements are true or false should be determined.

Concept Introduction:

Polarity of any molecule depends on electronegativity of atoms that forms covalent bonds. Depending upon the difference in electronegativity of atoms, polar or nonpolar molecule is determined. Polar molecule has electronegativity between 0.5 and 1.4 whereas in nonpolar molecule, it is less than 0.5.

Interpretation Introduction

(h)

Interpretation:

The given statements are true or false should be determined.

Concept Introduction:

Polarity of any molecule depends on electronegativity of atoms that forms covalent bonds. Depending upon the difference in electronegativity of atoms, polar or nonpolar molecule is determined. Polar molecule has electronegativity between 0.5 and 1.4 whereas in nonpolar molecule, it is less than 0.5.

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Q6: Predict the effect of the changes given on the rate of the reaction below. CH3OH CH3Cl + NaOCH3 → CH3OCH3 + NaCl a) Change the substrate from CH3CI to CH31: b) Change the nucleophile from NaOCH 3 to NaSCH3: c) Change the substrate from CH3CI to (CH3)2CHCI: d) Change the solvent from CH3OH to DMSO.

Q3: Arrange each group of compounds from fastest SN2 reaction rate to slowest SN2 reaction rate. a) CI Cl فيكم H3C-Cl A B C D Br Br b) A B C Br H3C-Br D

Q2: Group these solvents into either protic solvents or aprotic solvents. Acetonitrile (CH3CN), H₂O, Acetic acid (CH3COOH), Acetone (CH3COCH3), CH3CH2OH, DMSO (CH3SOCH3), DMF (HCON(CH3)2), CH3OH

Answer 2

Question

Chapter 3, Problem 3.85P

Interpretation Introduction

(a)

Interpretation:

The given statements are true or false should be determined.

Concept Introduction:

Polarity of any molecule depends on electronegativity of atoms that forms covalent bonds. Depending upon the difference in electronegativity of atoms, polar or nonpolar molecule is determined. Polar molecule has electronegativity between 0.5 and 1.4 whereas in nonpolar molecule, it is less than 0.5.

Interpretation Introduction

(b)

Interpretation:

The given statements are true or false should be determined.

Concept Introduction:

Polarity of any molecule depends on electronegativity of atoms that forms covalent bonds. Depending upon the difference in electronegativity of atoms, polar or nonpolar molecule is determined. Polar molecule has electronegativity between 0.5 and 1.4 whereas in nonpolar molecule, it is less than 0.5.

Interpretation Introduction

(c)

Interpretation:

The given statements are true or false should be determined.

Concept Introduction:

Polarity of any molecule depends on electronegativity of atoms that forms covalent bonds. Depending upon the difference in electronegativity of atoms, polar or nonpolar molecule is determined. Polar molecule has electronegativity between 0.5 and 1.4 whereas in nonpolar molecule, it is less than 0.5.

Interpretation Introduction

(d)

Interpretation:

The given statements are true or false should be determined.

Concept Introduction:

Polarity of any molecule depends on electronegativity of atoms that forms covalent bonds. Depending upon the difference in electronegativity of atoms, polar or nonpolar molecule is determined. Polar molecule has electronegativity between 0.5 and 1.4 whereas in nonpolar molecule, it is less than 0.5.

Interpretation Introduction

(e)

Interpretation:

The given statements are true or false should be determined.

Concept Introduction:

Polarity of any molecule depends on electronegativity of atoms that forms covalent bonds. Depending upon the difference in electronegativity of atoms, polar or nonpolar molecule is determined. Polar molecule has electronegativity between 0.5 and 1.4 whereas in nonpolar molecule, it is less than 0.5.

Interpretation Introduction

(f)

Interpretation:

The given statements are true or false should be determined.

Concept Introduction:

Polarity of any molecule depends on electronegativity of atoms that forms covalent bonds. Depending upon the difference in electronegativity of atoms, polar or nonpolar molecule is determined. Polar molecule has electronegativity between 0.5 and 1.4 whereas in nonpolar molecule, it is less than 0.5.

Interpretation Introduction

(g)

Interpretation:

The given statements are true or false should be determined.

Concept Introduction:

Polarity of any molecule depends on electronegativity of atoms that forms covalent bonds. Depending upon the difference in electronegativity of atoms, polar or nonpolar molecule is determined. Polar molecule has electronegativity between 0.5 and 1.4 whereas in nonpolar molecule, it is less than 0.5.

Interpretation Introduction

(h)

Interpretation:

The given statements are true or false should be determined.

Concept Introduction:

Polarity of any molecule depends on electronegativity of atoms that forms covalent bonds. Depending upon the difference in electronegativity of atoms, polar or nonpolar molecule is determined. Polar molecule has electronegativity between 0.5 and 1.4 whereas in nonpolar molecule, it is less than 0.5.

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Answer 3

Question

Chapter 3, Problem 3.85P

Interpretation Introduction

(a)

Interpretation:

The given statements are true or false should be determined.

Concept Introduction:

Polarity of any molecule depends on electronegativity of atoms that forms covalent bonds. Depending upon the difference in electronegativity of atoms, polar or nonpolar molecule is determined. Polar molecule has electronegativity between 0.5 and 1.4 whereas in nonpolar molecule, it is less than 0.5.

Interpretation Introduction

(b)

Interpretation:

The given statements are true or false should be determined.

Concept Introduction:

Polarity of any molecule depends on electronegativity of atoms that forms covalent bonds. Depending upon the difference in electronegativity of atoms, polar or nonpolar molecule is determined. Polar molecule has electronegativity between 0.5 and 1.4 whereas in nonpolar molecule, it is less than 0.5.

Interpretation Introduction

(c)

Interpretation:

The given statements are true or false should be determined.

Concept Introduction:

Polarity of any molecule depends on electronegativity of atoms that forms covalent bonds. Depending upon the difference in electronegativity of atoms, polar or nonpolar molecule is determined. Polar molecule has electronegativity between 0.5 and 1.4 whereas in nonpolar molecule, it is less than 0.5.

Interpretation Introduction

(d)

Interpretation:

The given statements are true or false should be determined.

Concept Introduction:

Polarity of any molecule depends on electronegativity of atoms that forms covalent bonds. Depending upon the difference in electronegativity of atoms, polar or nonpolar molecule is determined. Polar molecule has electronegativity between 0.5 and 1.4 whereas in nonpolar molecule, it is less than 0.5.

Interpretation Introduction

(e)

Interpretation:

The given statements are true or false should be determined.

Concept Introduction:

Polarity of any molecule depends on electronegativity of atoms that forms covalent bonds. Depending upon the difference in electronegativity of atoms, polar or nonpolar molecule is determined. Polar molecule has electronegativity between 0.5 and 1.4 whereas in nonpolar molecule, it is less than 0.5.

Interpretation Introduction

(f)

Interpretation:

The given statements are true or false should be determined.

Concept Introduction:

Polarity of any molecule depends on electronegativity of atoms that forms covalent bonds. Depending upon the difference in electronegativity of atoms, polar or nonpolar molecule is determined. Polar molecule has electronegativity between 0.5 and 1.4 whereas in nonpolar molecule, it is less than 0.5.

Interpretation Introduction

(g)

Interpretation:

The given statements are true or false should be determined.

Concept Introduction:

Polarity of any molecule depends on electronegativity of atoms that forms covalent bonds. Depending upon the difference in electronegativity of atoms, polar or nonpolar molecule is determined. Polar molecule has electronegativity between 0.5 and 1.4 whereas in nonpolar molecule, it is less than 0.5.

Interpretation Introduction

(h)

Interpretation:

The given statements are true or false should be determined.

Concept Introduction:

Polarity of any molecule depends on electronegativity of atoms that forms covalent bonds. Depending upon the difference in electronegativity of atoms, polar or nonpolar molecule is determined. Polar molecule has electronegativity between 0.5 and 1.4 whereas in nonpolar molecule, it is less than 0.5.

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Answer 4

Question

Chapter 3, Problem 3.85P

Interpretation Introduction

(a)

Interpretation:

The given statements are true or false should be determined.

Concept Introduction:

Polarity of any molecule depends on electronegativity of atoms that forms covalent bonds. Depending upon the difference in electronegativity of atoms, polar or nonpolar molecule is determined. Polar molecule has electronegativity between 0.5 and 1.4 whereas in nonpolar molecule, it is less than 0.5.

Interpretation Introduction

(b)

Interpretation:

The given statements are true or false should be determined.

Concept Introduction:

Polarity of any molecule depends on electronegativity of atoms that forms covalent bonds. Depending upon the difference in electronegativity of atoms, polar or nonpolar molecule is determined. Polar molecule has electronegativity between 0.5 and 1.4 whereas in nonpolar molecule, it is less than 0.5.

Interpretation Introduction

(c)

Interpretation:

The given statements are true or false should be determined.

Concept Introduction:

Polarity of any molecule depends on electronegativity of atoms that forms covalent bonds. Depending upon the difference in electronegativity of atoms, polar or nonpolar molecule is determined. Polar molecule has electronegativity between 0.5 and 1.4 whereas in nonpolar molecule, it is less than 0.5.

Interpretation Introduction

(d)

Interpretation:

The given statements are true or false should be determined.

Concept Introduction:

Polarity of any molecule depends on electronegativity of atoms that forms covalent bonds. Depending upon the difference in electronegativity of atoms, polar or nonpolar molecule is determined. Polar molecule has electronegativity between 0.5 and 1.4 whereas in nonpolar molecule, it is less than 0.5.

Interpretation Introduction

(e)

Interpretation:

The given statements are true or false should be determined.

Concept Introduction:

Polarity of any molecule depends on electronegativity of atoms that forms covalent bonds. Depending upon the difference in electronegativity of atoms, polar or nonpolar molecule is determined. Polar molecule has electronegativity between 0.5 and 1.4 whereas in nonpolar molecule, it is less than 0.5.

Interpretation Introduction

(f)

Interpretation:

The given statements are true or false should be determined.

Concept Introduction:

Polarity of any molecule depends on electronegativity of atoms that forms covalent bonds. Depending upon the difference in electronegativity of atoms, polar or nonpolar molecule is determined. Polar molecule has electronegativity between 0.5 and 1.4 whereas in nonpolar molecule, it is less than 0.5.

Interpretation Introduction

(g)

Interpretation:

The given statements are true or false should be determined.

Concept Introduction:

Polarity of any molecule depends on electronegativity of atoms that forms covalent bonds. Depending upon the difference in electronegativity of atoms, polar or nonpolar molecule is determined. Polar molecule has electronegativity between 0.5 and 1.4 whereas in nonpolar molecule, it is less than 0.5.

Interpretation Introduction

(h)

Interpretation:

The given statements are true or false should be determined.

Concept Introduction:

Polarity of any molecule depends on electronegativity of atoms that forms covalent bonds. Depending upon the difference in electronegativity of atoms, polar or nonpolar molecule is determined. Polar molecule has electronegativity between 0.5 and 1.4 whereas in nonpolar molecule, it is less than 0.5.

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Answer 5

Chapter 3, Problem 3.85P

Interpretation Introduction

(a)

Interpretation:

The given statements are true or false should be determined.

Concept Introduction:

Polarity of any molecule depends on electronegativity of atoms that forms covalent bonds. Depending upon the difference in electronegativity of atoms, polar or nonpolar molecule is determined. Polar molecule has electronegativity between 0.5 and 1.4 whereas in nonpolar molecule, it is less than 0.5.

Interpretation Introduction

(b)

Interpretation:

The given statements are true or false should be determined.

Concept Introduction:

Polarity of any molecule depends on electronegativity of atoms that forms covalent bonds. Depending upon the difference in electronegativity of atoms, polar or nonpolar molecule is determined. Polar molecule has electronegativity between 0.5 and 1.4 whereas in nonpolar molecule, it is less than 0.5.

Interpretation Introduction

(c)

Interpretation:

The given statements are true or false should be determined.

Concept Introduction:

Polarity of any molecule depends on electronegativity of atoms that forms covalent bonds. Depending upon the difference in electronegativity of atoms, polar or nonpolar molecule is determined. Polar molecule has electronegativity between 0.5 and 1.4 whereas in nonpolar molecule, it is less than 0.5.

Interpretation Introduction

(d)

Interpretation:

The given statements are true or false should be determined.

Concept Introduction:

Polarity of any molecule depends on electronegativity of atoms that forms covalent bonds. Depending upon the difference in electronegativity of atoms, polar or nonpolar molecule is determined. Polar molecule has electronegativity between 0.5 and 1.4 whereas in nonpolar molecule, it is less than 0.5.

Interpretation Introduction

(e)

Interpretation:

The given statements are true or false should be determined.

Concept Introduction:

Polarity of any molecule depends on electronegativity of atoms that forms covalent bonds. Depending upon the difference in electronegativity of atoms, polar or nonpolar molecule is determined. Polar molecule has electronegativity between 0.5 and 1.4 whereas in nonpolar molecule, it is less than 0.5.

Interpretation Introduction

(f)

Interpretation:

The given statements are true or false should be determined.

Concept Introduction:

Polarity of any molecule depends on electronegativity of atoms that forms covalent bonds. Depending upon the difference in electronegativity of atoms, polar or nonpolar molecule is determined. Polar molecule has electronegativity between 0.5 and 1.4 whereas in nonpolar molecule, it is less than 0.5.

Interpretation Introduction

(g)

Interpretation:

The given statements are true or false should be determined.

Concept Introduction:

Polarity of any molecule depends on electronegativity of atoms that forms covalent bonds. Depending upon the difference in electronegativity of atoms, polar or nonpolar molecule is determined. Polar molecule has electronegativity between 0.5 and 1.4 whereas in nonpolar molecule, it is less than 0.5.

Interpretation Introduction

(h)

Interpretation:

The given statements are true or false should be determined.

Concept Introduction:

Polarity of any molecule depends on electronegativity of atoms that forms covalent bonds. Depending upon the difference in electronegativity of atoms, polar or nonpolar molecule is determined. Polar molecule has electronegativity between 0.5 and 1.4 whereas in nonpolar molecule, it is less than 0.5.

Answer 6

Chapter 3, Problem 3.85P

Interpretation Introduction

(a)

Interpretation:

The given statements are true or false should be determined.

Concept Introduction:

Polarity of any molecule depends on electronegativity of atoms that forms covalent bonds. Depending upon the difference in electronegativity of atoms, polar or nonpolar molecule is determined. Polar molecule has electronegativity between 0.5 and 1.4 whereas in nonpolar molecule, it is less than 0.5.

Answer 7

Chapter 3, Problem 3.85P

Interpretation Introduction

(a)

Interpretation:

The given statements are true or false should be determined.

Concept Introduction:

Polarity of any molecule depends on electronegativity of atoms that forms covalent bonds. Depending upon the difference in electronegativity of atoms, polar or nonpolar molecule is determined. Polar molecule has electronegativity between 0.5 and 1.4 whereas in nonpolar molecule, it is less than 0.5.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The given statements are true or false should be determined.

Concept Introduction:

Polarity of any molecule depends on electronegativity of atoms that forms covalent bonds. Depending upon the difference in electronegativity of atoms, polar or nonpolar molecule is determined. Polar molecule has electronegativity between 0.5 and 1.4 whereas in nonpolar molecule, it is less than 0.5.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The given statements are true or false should be determined.

Concept Introduction:

Polarity of any molecule depends on electronegativity of atoms that forms covalent bonds. Depending upon the difference in electronegativity of atoms, polar or nonpolar molecule is determined. Polar molecule has electronegativity between 0.5 and 1.4 whereas in nonpolar molecule, it is less than 0.5.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The given statements are true or false should be determined.

Concept Introduction:

Polarity of any molecule depends on electronegativity of atoms that forms covalent bonds. Depending upon the difference in electronegativity of atoms, polar or nonpolar molecule is determined. Polar molecule has electronegativity between 0.5 and 1.4 whereas in nonpolar molecule, it is less than 0.5.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The given statements are true or false should be determined.

Concept Introduction:

Polarity of any molecule depends on electronegativity of atoms that forms covalent bonds. Depending upon the difference in electronegativity of atoms, polar or nonpolar molecule is determined. Polar molecule has electronegativity between 0.5 and 1.4 whereas in nonpolar molecule, it is less than 0.5.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The given statements are true or false should be determined.

Concept Introduction:

Polarity of any molecule depends on electronegativity of atoms that forms covalent bonds. Depending upon the difference in electronegativity of atoms, polar or nonpolar molecule is determined. Polar molecule has electronegativity between 0.5 and 1.4 whereas in nonpolar molecule, it is less than 0.5.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The given statements are true or false should be determined.

Concept Introduction:

Polarity of any molecule depends on electronegativity of atoms that forms covalent bonds. Depending upon the difference in electronegativity of atoms, polar or nonpolar molecule is determined. Polar molecule has electronegativity between 0.5 and 1.4 whereas in nonpolar molecule, it is less than 0.5.

Answer 14

Interpretation Introduction

(e)

Interpretation:

The given statements are true or false should be determined.

Concept Introduction:

Polarity of any molecule depends on electronegativity of atoms that forms covalent bonds. Depending upon the difference in electronegativity of atoms, polar or nonpolar molecule is determined. Polar molecule has electronegativity between 0.5 and 1.4 whereas in nonpolar molecule, it is less than 0.5.

Answer 15

Interpretation Introduction

(e)

Interpretation:

The given statements are true or false should be determined.

Concept Introduction:

Polarity of any molecule depends on electronegativity of atoms that forms covalent bonds. Depending upon the difference in electronegativity of atoms, polar or nonpolar molecule is determined. Polar molecule has electronegativity between 0.5 and 1.4 whereas in nonpolar molecule, it is less than 0.5.

Answer 16

Interpretation Introduction

(f)

Interpretation:

The given statements are true or false should be determined.

Concept Introduction:

Polarity of any molecule depends on electronegativity of atoms that forms covalent bonds. Depending upon the difference in electronegativity of atoms, polar or nonpolar molecule is determined. Polar molecule has electronegativity between 0.5 and 1.4 whereas in nonpolar molecule, it is less than 0.5.

Answer 17

Interpretation Introduction

(f)

Interpretation:

The given statements are true or false should be determined.

Concept Introduction:

Polarity of any molecule depends on electronegativity of atoms that forms covalent bonds. Depending upon the difference in electronegativity of atoms, polar or nonpolar molecule is determined. Polar molecule has electronegativity between 0.5 and 1.4 whereas in nonpolar molecule, it is less than 0.5.

Answer 18

Interpretation Introduction

(g)

Interpretation:

The given statements are true or false should be determined.

Concept Introduction:

Polarity of any molecule depends on electronegativity of atoms that forms covalent bonds. Depending upon the difference in electronegativity of atoms, polar or nonpolar molecule is determined. Polar molecule has electronegativity between 0.5 and 1.4 whereas in nonpolar molecule, it is less than 0.5.

Answer 19

Interpretation Introduction

(g)

Interpretation:

The given statements are true or false should be determined.

Concept Introduction:

Polarity of any molecule depends on electronegativity of atoms that forms covalent bonds. Depending upon the difference in electronegativity of atoms, polar or nonpolar molecule is determined. Polar molecule has electronegativity between 0.5 and 1.4 whereas in nonpolar molecule, it is less than 0.5.

Answer 20

Interpretation Introduction

(h)

Interpretation:

The given statements are true or false should be determined.

Concept Introduction:

Polarity of any molecule depends on electronegativity of atoms that forms covalent bonds. Depending upon the difference in electronegativity of atoms, polar or nonpolar molecule is determined. Polar molecule has electronegativity between 0.5 and 1.4 whereas in nonpolar molecule, it is less than 0.5.

Answer 21

Interpretation Introduction

(h)

Interpretation:

The given statements are true or false should be determined.

Concept Introduction:

Polarity of any molecule depends on electronegativity of atoms that forms covalent bonds. Depending upon the difference in electronegativity of atoms, polar or nonpolar molecule is determined. Polar molecule has electronegativity between 0.5 and 1.4 whereas in nonpolar molecule, it is less than 0.5.

Answer 22

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Answer 23

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Answer 24

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Answer 27

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Answer 33

Ch. 3.2 - Problem 3-1 Show how the following chemical...Ch. 3.4 - Problem 3-2 Judging from their relative positions...Ch. 3.5 - Problem 3-3 Write the formulas for the ionic...Ch. 3.6 - Problem 3-4 Name these binary ionic compounds: (a)...Ch. 3.6 - Prob. 3.5P Ch. 3.6 - Problem 3-6 Give each binary compound a systematic...Ch. 3.6 - Problem 3-7 Name these ionic compounds, each of...Ch. 3.7 - Prob. 3.8P Ch. 3.7 - Prob. 3.9P Ch. 3.7 - Prob. 3.10P

Solution Summary: The author explains that polarity of any molecule depends on electronegativity of atoms that forms covalent bonds.

Chapter 3 Solutions