Introduction to General, Organic and Biochemistry
11th Edition
ISBN: 9781285869759
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher: Cengage Learning
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Chapter 3, Problem 3.65P
Interpretation Introduction
Interpretation:
The reason should be determined why hydrogen can’t have more than two electrons in its valence shell.
Concept Introduction:
The octet rule states that atoms of a variety of elements enter into chemical combination so as to reach the configuration of eight electrons in their outermost shell. They do so by either transference of electrons or by mutual sharing of electrons.
A covalent bond is formed by sharing of same number of electrons between two atoms to complete their octet. Atoms taking part in covalent bond formation may share one, two or three electron pairs thus forming single, double and triple bond respectively.
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For the decomposition reaction of N2O5(g): 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed:
N2O5 NO2 + NO3 (K1) | NO2 + NO3 → N2O5 (k-1) | NO2 + NO3 NO2 + O2 + NO (k2) | NO + N2O51 NO2 + NO2 + NO2 (K3)
→
Give the expression for the acceptable rate.
→
→
(A).
d[N205]
dt
==
2k,k₂[N₂O₂]
k₁+k₁₂
(B).
d[N2O5]
=-k₁[N₂O] + k₁[NO₂] [NO3] - k₂[NO₂]³
dt
(C).
d[N2O5]
=-k₁[N₂O] + k [NO] - k₂[NO] [NO]
d[N2O5]
(D).
=
dt
= -k₁[N2O5] - k¸[NO][N₂05]
dt
Do not apply the calculations, based on the approximation of the stationary state, to make them perform correctly. Basta discard
the 3 responses that you encounter that are obviously erroneous if you apply the formula to determine the speed of a reaction.
R lactam or lactone considering as weak acid or weak base and why
81. a. Propose a mechanism for the following reaction:
OH
CH2=CHCHC=N
b. What is the product of the following reaction?
HO
H₂O
N=CCH2CH2CH
OH
HO
CH3CCH=CH2
H₂O
C=N
82. Unlike a phosphonium ylide that reacts with an aldehyde or a ketone to form an alkene a sulfonium ulia
Chapter 3 Solutions
Introduction to General, Organic and Biochemistry
Ch. 3.2 - Problem 3-1 Show how the following chemical...Ch. 3.4 - Problem 3-2 Judging from their relative positions...Ch. 3.5 - Problem 3-3 Write the formulas for the ionic...Ch. 3.6 - Problem 3-4 Name these binary ionic compounds: (a)...Ch. 3.6 - Prob. 3.5PCh. 3.6 - Problem 3-6 Give each binary compound a systematic...Ch. 3.6 - Problem 3-7 Name these ionic compounds, each of...Ch. 3.7 - Prob. 3.8PCh. 3.7 - Prob. 3.9PCh. 3.7 - Prob. 3.10P
Ch. 3.7 - Prob. 3.11PCh. 3.8 - Prob. 3.12PCh. 3.9 - Prob. 3.13PCh. 3.9 - Prob. 3.14PCh. 3.10 - Problem 3-15 Predict all bond angles for these...Ch. 3.11 - Problem 3-16 Which of these molecules are polar?...Ch. 3 - 3-17 Answer true or false. (a) The octet rule...Ch. 3 - 3-18 How many electrons must each atom gain or...Ch. 3 - 3-19 Show how each chemical change obeys the octet...Ch. 3 - 3-20 Show how each chemical change obeys the octet...Ch. 3 - 3-21 Write the formula for the most stable ion...Ch. 3 - 3-22 Why is Li- not a stable ion?Ch. 3 - 3-23 Predict which ions are stable: (a) (b) (c)...Ch. 3 - 3-24 Predict which ions are stable: (a) Br2- (b)...Ch. 3 - 3-25 Why are carbon and silicon reluctant to form...Ch. 3 - 3-26 Table 3-2 shows the following ions of copper:...Ch. 3 - 3-27 Answer true or false. (a) For Group lA and...Ch. 3 - 3-28 Name each polyatomic ion. (a) HCO3- (b) NO2-...Ch. 3 - 3-29 Answer true or false. (a) According to the...Ch. 3 - Prob. 3.30PCh. 3 - 3-31 Why does electronegativity generally increase...Ch. 3 - 3-32 Judging from their relative positions in the...Ch. 3 - Prob. 3.33PCh. 3 - 3-34 Which of these bonds is the most polar? The...Ch. 3 - 3-35 Classify each bond as nonpolar covalent,...Ch. 3 - 3-36 Classify each bond as nonpolar covalent,...Ch. 3 - 3-37 Answer true or false. (a) An ionic bond is...Ch. 3 - 3-38 Complete the chart by writing formulas for...Ch. 3 - 3-39 Write a formula for the ionic compound formed...Ch. 3 - Prob. 3.40PCh. 3 - 3-41 Describe the structure of sodium chloride in...Ch. 3 - 3-42 What is the charge on each ion in these...Ch. 3 - 3-43 Write the formula for the compound formed...Ch. 3 - 3-44 Write the formula for the ionic compound...Ch. 3 - 3-45 Which formulas are not correct? For each that...Ch. 3 - 3-46 Which formulas are not correct? For each that...Ch. 3 - 3-47 Answer true or false. (a) The name of a...Ch. 3 - 3-48 Potassium chloride and potassium bicarbonate...Ch. 3 - Prob. 3.49PCh. 3 - 3-50 Name the polyatomic ion(s) in each compound....Ch. 3 - 3-51 Write the formulas for the ions present in...Ch. 3 - Prob. 3.52PCh. 3 - 3-53 Write formulas for the following ionic...Ch. 3 - 3-54 Write formulas for the following ionic...Ch. 3 - Prob. 3.55PCh. 3 - 3-56 How many covalent bonds are normally formed...Ch. 3 - 3-57 What is: (a) A single bond? (b) A double...Ch. 3 - 3-58 In Section 2-3B, we saw that there are seven...Ch. 3 - Prob. 3.59PCh. 3 - Prob. 3.60PCh. 3 - Prob. 3.61PCh. 3 - Prob. 3.62PCh. 3 - 3-63 What is the difference between (a) a bromine...Ch. 3 - 3-64 Acetylene (C2H2), hydrogen cyanide (HCN), and...Ch. 3 - Prob. 3.65PCh. 3 - 3-66 Why can’t second-row elements have more than...Ch. 3 - 3-67 Why does nitrogen have three bonds and one...Ch. 3 - 3-68 Draw a Lewis structure of a covalent compound...Ch. 3 - Prob. 3.69PCh. 3 - 3-70 Draw a Lewis structure of a covalent compound...Ch. 3 - Prob. 3.71PCh. 3 - Prob. 3.72PCh. 3 - Prob. 3.73PCh. 3 - 3-74 Answer true or false. (a) A binary covalent...Ch. 3 - Prob. 3.75PCh. 3 - Prob. 3.76PCh. 3 - 3-77 Ozone, O3, is an unstable blue gas with a...Ch. 3 - 3-78 Nitrous oxide, N20, laughing gas, is a...Ch. 3 - 3-79 Answer true or false. (a) The letters VSEPR...Ch. 3 - Prob. 3.80PCh. 3 - Prob. 3.81PCh. 3 - 3-82 Hydrogen and nitrogen combine in different...Ch. 3 - Prob. 3.83PCh. 3 - Prob. 3.84PCh. 3 - Prob. 3.85PCh. 3 - Prob. 3.86PCh. 3 - 3-87 Consider the molecule boron trffluoride, BF3....Ch. 3 - Prob. 3.88PCh. 3 - 3-89 Is it possible for a molecule to have no...Ch. 3 - Prob. 3.90PCh. 3 - Prob. 3.91PCh. 3 - Prob. 3.92PCh. 3 - Prob. 3.93PCh. 3 - Prob. 3.94PCh. 3 - Prob. 3.95PCh. 3 - Prob. 3.96PCh. 3 - Prob. 3.97PCh. 3 - Prob. 3.98PCh. 3 - 3-99 Knowing what you do about covalent bonding in...Ch. 3 - Prob. 3.100PCh. 3 - Prob. 3.101PCh. 3 - Prob. 3.102PCh. 3 - Prob. 3.103PCh. 3 - Prob. 3.104PCh. 3 - 3-105 Consider the structure of Vitamin E shown...Ch. 3 - 3-106 Consider the structure of Penicillin G shown...Ch. 3 - 3-107 Ephedrine, a molecule at one time found in...Ch. 3 - Prob. 3.108PCh. 3 - 3-109 Until several years ago, the two...Ch. 3 - 3-110 Name and write the formula for the fluorine...Ch. 3 - Prob. 3.111PCh. 3 - Prob. 3.112PCh. 3 - Prob. 3.113PCh. 3 - Prob. 3.114PCh. 3 - Prob. 3.115PCh. 3 - Prob. 3.116PCh. 3 - Prob. 3.117PCh. 3 - Prob. 3.118PCh. 3 - 3-119 Perchloroethylene, which is a liquid at room...Ch. 3 - 3-120 Vinyl chloride is the starting material for...Ch. 3 - 3-121 Tetrafluoroethylene is the starting material...Ch. 3 - 3-122 Some of the following structural formulas...Ch. 3 - 3-123 Sodium borohydride, NaBH4, has found wide...Ch. 3 - Prob. 3.124PCh. 3 - Prob. 3.125PCh. 3 - Prob. 3.126PCh. 3 - 3-127 Amoxicillin is an antibiotic used to treat...Ch. 3 - Prob. 3.128P
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