Q4: Rank the relative nucleophilicity of halide ions in water solution and DMF solution, respectively. F CI Br | Q5: Determine which of the substrates will and will not react with NaSCH3 in an SN2 reaction to have a reasonable yield of product. NH2 Br Br Br .OH Br
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- Arrange these structures in decre asing order of reactivity towards bromin ation. NH2 NO2 Br CHa 2. OA) 1>3>4>2 O B) 2>4>3>1 OC) 3>1>2>4 () D) 1>4>3>2In what way(s) does the carbon-group-bonded-to metal of an organometallic compound behave? Select one: ⒸA Oxidizing agent O O B. Acid (proton donor) C. Base (proton acceptor) D. Carbon nucleophile E. Carbon electrophile Both C and D Which of the following is NOT an organometallic compound?Select the starting material(s) (SM) that would be expected to give Q as the major elimination product. H;CO", HOCH3 SM -Ph Q Br Ph Ph Br Ph Br I II III II I and II I and III ||
- This reaction does not follow the expected theory. Given what you know about substitution/elimination, what is the expected mechanism this reaction should follow? Suggest why that is not what happens and give the actual product of the reaction. Br ткон sQuestion 4Which of the following statements is/are true about an SN2 reaction? Select one: O A. All of the statements are true. B. Changing the identity of the leaving group changes the rate of the reaction. OC. The reaction is fastest with 1º halides. O D. The reaction follows an overall 2nd order rate law.
- QUESTION 2 The preparation of a Wittig salt from an alky halide and triphenylphosphine proceeds by a(n) O A. E2 O B. Sn2 OC. E1 O D. free radical O E. Sn1 mechanism. QUESTION 3 Which resonance structure is more reactive as a nucleophile? Ph Ph O A. 1 O B. 2 OC. both are equally reactive Click Save and Submit to save and submit. Click Save All Answers to save all answers. o search F10 F1 F2 F3 F4 F5 F6 23 2 3 4. 7 8 W Y UIDraw the energy diagram of the following reaction. Label and draw the reactants, intermediates, and products. Label the transition state of the rate limiting step and draw the transition state of the rate determining step. Is it a concerted or stepwise reaction? Write the rate law for this reaction. How do we increase the reaction rate? If we use deutrium-tert-butyl bromide such as (CD3)3CBr instead of (CH3)3CBr, will it increase or decrease the reaction rate, or is there no meaningful rate change? Write reasons for your answer. Draw mechanisms for reactions by drawing arrows and intermediates.2. In the following reactions identify the nucleophile by writing Nu on the atom that does the attacking. Then circle the atom that is the leaving group in the electrophile. a. b. N Br F + + Na Me Iton MeOH olapidmolo-1 ydw niele, brinsw Insbrta staulis pach Maiy book

