Organic Chemistry
11th Edition
ISBN: 9781118133576
Author: T. W. Graham Solomons, Craig Fryhle
Publisher: Wiley, John & Sons, Incorporated
expand_more
expand_more
format_list_bulleted
Concept explainers
Videos
Textbook Question
Chapter 21, Problem 16P
Describe a simple chemical test that could be used to distinguish between members of each of the following pairs of compounds:
(a) 4-Chlorophenol and 4-chloro-1-methylbenzene
(b) 4-Methylphenol and 4-methylbenzoic acid
(c) 4-Methylphenol and 2,4,6-trinitrophenol
(d) Ethyl phenyl ether and 4-ethylphenol
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
3. Titanium(III) chloride can be used to catalyze the polymerization of ethylene. It is prepared by hydrogen reduction of
Titanium(IV) chloride. Reaction of hydrogen gas with titanium(IV) chloride gas produces solid titanium(III) chloride and
hydrogen chloride gas.
(a) Write a BALANCED chemical reaction for the preparation of titanium(III) chloride
(b) A 250 L reaction vessel at 325°C is filled with hydrogen gas to a pressure of 1.3 atm. Titanium(IV) chloride is then added
to bring the total pressure to 3.00 atm. How many grams of titanium(III) chloride will be produced after completion of the
reaction?
(c) What will be the pressure of the resulting hydrogen chloride gas that is also produced?
1. Sodium azide (NaN3) is the primary chemical substance used in automobile air bags. Upon impact, the decomposition of
sodium azide is initiated to produce sodium metal and nitrogen gas which then inflates the bag. How many liters of
nitrogen gas are produced at 1.15 atm and 30.0°C when 145.0 grams of sodium azide decomposes?
2. Calcium carbonate (such as that in limestone) reacts with aqueous hydrochloric acid to produce carbon dioxide, aqueous
calcium chloride and water. How many liters of carbon dioxide are produced at 20°C and 745 torr when 3.583 grams of
calcium carbonate is dissolved in solution containing 1.550 grams of hydrochloric acid?
Show all work (where appropriate) for full credit.
1. Describe (steps, equipment and quantities) how to accurately prepare 250.0 mL of a 0.0075
M solution of NaCl (aq) from a 500 mL, 0.0500 M stock solution.
2. Describe (steps, equipment and quantities) how to accurately prepare 250.0 mL of a 0.0075
M solution of NaCl (aq) from 100 g of solid NaCl.
Chapter 21 Solutions
Organic Chemistry
Ch. 21 - PRACTICE PROBLEM
21.1 If we examine Table 21.1, we...Ch. 21 - PRACTICE PROBLEM If we examine Table 21.1, we see...Ch. 21 - Prob. 3PPCh. 21 - PRACTICE PROBLEM
21.4 Predict the products of each...Ch. 21 - Prob. 5PPCh. 21 - PRACTICE PROBLEM
21.6 What are compounds A and B...Ch. 21 - Prob. 7PPCh. 21 - PRACTICE PROBLEM Outline a possible synthesis of...Ch. 21 - PRACTICE PROBLEM 1-Fluoro-2,4-dinitrobenzene is...Ch. 21 - PRACTICE PROBLEM
21.10 When o-chlorotoluene is...
Ch. 21 - PRACTICE PROBLEM When 2-bromo-1,3-dimethylbenzene...Ch. 21 - PRACTICE PROBLEM (a) Outline a step-by-step...Ch. 21 - Rank the following in order of increasing acidity.Ch. 21 - Prob. 14PCh. 21 - Prob. 15PCh. 21 - Describe a simple chemical test that could be used...Ch. 21 - Prob. 17PCh. 21 - Predict the product of the following reactions.Ch. 21 - 21.19 A synthesis of the β-receptor blocker called...Ch. 21 - Prob. 20PCh. 21 - When m-chlorotoluene is treated with sodium amide...Ch. 21 - Prob. 22PCh. 21 - Prob. 23PCh. 21 - Prob. 24PCh. 21 - Prob. 25PCh. 21 - Prob. 26PCh. 21 - Prob. 27PCh. 21 - Prob. 28PCh. 21 - Prob. 29PCh. 21 - Prob. 30PCh. 21 - Prob. 31PCh. 21 - 21.32 A compound X (C10H14O) dissolves in aqueous...Ch. 21 - 21.33 Compound Z (C5H10O) decolorizes bromine in...Ch. 21 - Explain why, in the case shown, the allyl group...Ch. 21 - In protic solvents the naphthoxide ion (I) is...Ch. 21 - Prob. 36PCh. 21 - Prob. 37PCh. 21 - Prob. 38PCh. 21 - Prob. 39PCh. 21 - Prob. 40PCh. 21 - 21.41 Compound W was isolated from a marine...Ch. 21 - 21.42 Phenols generally are not changed on...Ch. 21 - 21.43 Open the molecular model file for benzyne...Ch. 21 - Which of the following would be the strongest...Ch. 21 - What products would you expect from the following...Ch. 21 - Prob. 3QCh. 21 - Prob. 4QCh. 21 - 21.5 Complete the following synthesis:
Ch. 21 - Prob. 6QCh. 21 - 21.7 Select the stronger acid.
Additional Science Textbook Solutions
Find more solutions based on key concepts
Identify each of the following reproductive barriers as prezygotic or postzygotic. a. One lilac species lives o...
Campbell Essential Biology with Physiology (5th Edition)
WHAT IF? Is allopatric speciation more likely to occur on an island close to a mainland or on a more isolated i...
Campbell Biology in Focus (2nd Edition)
What are the two types of bone marrow, and what are their functions?
Human Anatomy & Physiology (2nd Edition)
1.4 Consider the two spheres shown here, one made of silver and the other of aluminum.
What is the mass of eac...
Chemistry: The Central Science (14th Edition)
53. This reaction was monitored as a function of time:
A plot of In[A] versus time yields a straight ...
Chemistry: Structure and Properties (2nd Edition)
2 Of the uterus, small intestine, spinal cord, and heart, which is/are in the dorsal body cavity?
Anatomy & Physiology (6th Edition)
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- 5. An unlabeled gas cylinder was recently found in the laboratory. A sample of the gas was removed and analyzed. A 500.0 mL sample of the gas at 15°C and a pressure of 736 mmHg was found to weigh 2.688 g. Determine the molar mass of the gas. What element is the gas?arrow_forward4. Nitrogen gas is commonly sold in 49.0 L steal cylinders at a pressure of 150 atm. (a) How many moles of nitrogen are in the container if the temperature of the cylinder is 21°C. (b) How many moles of nitrogen will there be if the container above is heated to 100°C? (careful here) (c) What is the mass of nitrogen gas in the cylinder in part (a)? (d) What volume would the nitrogen occupy at 21°C, if the pressure was reduced to 1.02 atm? (e) What would be the pressure of the nitrogen gas in the cylinder when the temperature is raised to 39°C?arrow_forward6. A 0.4550 g sample of an unknown organic compound with the empirical formula CH2O was placed into a 150.0 ml vessel and was vaporized into a gas. At 175.0°C, the pressure of the vaporized compound was measured at 941.1 torr. (a) Determine the molar mass of the compound (b) Determine the molecular formula of the compound.arrow_forward
- Don't used Ai solutionarrow_forward3. A particular reaction calls for 2.40 g of chloride ion. The only source of chloride ion available is a 0.00300 M stock solution of strontium chloride. How much (in L) of this solution is needed for this reaction?arrow_forwardAbsorption Spectrum of NaphthaleneTitle: Understanding the Absorption Spectrum of NaphthaleneGraph: Show a graph with labeled peaks indicating the absorption spectrum of naphthalene in a suitable solventarrow_forward
- Show work...don't give Ai generated solutionarrow_forwardShow work..don't give Ai generated and copy the answer anywhere.arrow_forwardthis is an inorganic chemistry question please answer accordindly!! its just one question with parts till (n) JUST ONE QUESTION with its parts spread out in the form of different images attached 2 IMAGES ATTACHED PLEASE SEE BOTH, please answer EACH part till the end and dont just provide wordy explanations wherever asked for structures, graphs or diagrams, please DRAW DRAW them on a paper and post clearly!! answer the full question with all details as needed EACH PART CLEARLY please or let another expert handle it thanks!! im reposting this please solve all parts and drawit not just word explanations!!arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Chapter 4 Alkanes and Cycloalkanes Lesson 2; Author: Linda Hanson;https://www.youtube.com/watch?v=AL_CM_Btef4;License: Standard YouTube License, CC-BY
Chapter 4 Alkanes and Cycloalkanes Lesson 1; Author: Linda Hanson;https://www.youtube.com/watch?v=PPIa6EHJMJw;License: Standard Youtube License