The synthesis of the given compound from benzene is to be suggested. Concept introduction: Electrophiles are electron-deficient species that has positive or partially positive charge. Lewis acids are electrophiles that accept electron pair. Nucleophiles are electron-rich species that has negative or partially negative charge. Lewis bases are nucleophiles that donate electron pair. Free radical is an atom, molecule, or ion that has unpaired electrons, which makes it highly chemically reactive. Substitution reaction: A reaction in which one of the hydrogen atoms of a hydrocarbon or a functional group is substituted by any other functional group is called substitution reaction. Elimination reaction: A reaction in which two substituent groups are detached and a double bond is formed is called elimination reaction. Addition reaction: It is the reaction in which unsaturated bonds are converted to saturated molecules by the addition of molecules. The electrophilic aromatic substitution reaction is the reaction between benzene and chlorine, or bromine, in the presence of a catalyst. Electrophilic substitution reaction is the type of reaction in which an electrophile displaces hydrogen from the compound. Nucleophilic aromatic substitution reaction is based on the addition-elimination mechanism. Activating groups give substitution at the ortho and para positions. Chlorine is the activating group. It gives two products; one ortho substituted, and the other para substituted.

Question

Want to see the full answer?

Answer 1

Question

Chapter 21, Problem 39P

Interpretation Introduction

Interpretation:

The synthesis of the given compound from benzene is to be suggested.

Concept introduction:

Electrophiles are electron-deficient species that has positive or partially positive charge. Lewis acids are electrophiles that accept electron pair.

Nucleophiles are electron-rich species that has negative or partially negative charge. Lewis bases are nucleophiles that donate electron pair.

Free radical is an atom, molecule, or ion that has unpaired electrons, which makes it highly chemically reactive.

Substitution reaction: A reaction in which one of the hydrogen atoms of a hydrocarbon or a functional group is substituted by any other functional group is called substitution reaction.

Elimination reaction: A reaction in which two substituent groups are detached and a double bond is formed is called elimination reaction.

Addition reaction: It is the reaction in which unsaturated bonds are converted to saturated molecules by the addition of molecules.

The electrophilic aromatic substitution reaction is the reaction between benzene and chlorine, or bromine, in the presence of a catalyst.

Electrophilic substitution reaction is the type of reaction in which an electrophile displaces hydrogen from the compound.

Nucleophilic aromatic substitution reaction is based on the addition-elimination mechanism.

Activating groups give substitution at the ortho and para positions.

Chlorine is the activating group. It gives two products; one ortho substituted, and the other para substituted.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

6. Match each of the lettered items in the column on the left with the most appropriate numbered item(s) in the column on the right. Some of the numbered items may be used more than once and some not at all. a. Z = 37 1. b. Mn 2. C. Pr element in period 5 and group 14 element in period 5 and group 15 d. S e. [Rn] 7s¹ f. d block metal 3. highest metallic character of all the elements 4. paramagnetic with 5 unpaired electrons 5. 4f36s2 6. isoelectronic with Ca²+ cation 7. an alkaline metal 8. an f-block element

Draw all formal charges on the structures below as is and draw 1 resonance structure that is more stable.

Part II. xiao isolated a compound TAD (Ca H 10 N₂) from tobacco and obtained its IR spectrum. Xiao proposed a chemical structure shown below: % Transmittance 4000 3500 3000 2500 2000 Wavenumber (cm-1) 1500 1000 (a) Explain why her proposed structure is inconsistent with the IR spectrum obtained (b) TAD exists as a tautomer of the structure xiao proposed. Draw the structure and explain why it is more compatible with the obtained spectrum. (C) what is the possible source for the fairly intense signal at 1621cm1