Organic Chemistry
Organic Chemistry
11th Edition
ISBN: 9781118133576
Author: T. W. Graham Solomons, Craig Fryhle
Publisher: Wiley, John & Sons, Incorporated
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Chapter 21, Problem 5PP
Interpretation Introduction

Interpretation:

The alternative mechanism suggested for Claisen rearrangement of allyl phenyl ether is to be explained.

Concept introduction:

Claisen rearrangement is the reaction in which allyl phenyl ether is heated at 200°C, and rearrangement of the allyl group takes place on the phenyl ring. An unstable intermediate is formed in the reaction.

Friedel-Crafts alkylation is the reaction in which a phenyl ring reacts with an alkyl halide to form alkyl benzene as product. This reaction is an electrophilic aromatic substitution reaction.

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McLafferty Rearrangement: Label alpha (), beta (), and gamma () on the molecule. Draw mechanismarrows to describe the process of the rearrangement. What functional group is lost during the rearrangement? What new functional group is made from the ketone/aldehyde you started with? What stabilizing chemical theory causes (allows) rearrangement to happen?
Don't used hand raiting and don't used Ai solution
Don't used hand raiting

Chapter 21 Solutions

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