The difference between rate determining step and other steps in a multistep reaction mechanism has to be given and also the effect of rate determining step in observed rate law has to be given.

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Chapter 12, Problem 12.87SP

Interpretation Introduction

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The difference between rate determining step and other steps in a multistep reaction mechanism has to be given and also the effect of rate determining step in observed rate law has to be given.

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Instructions: Complete the questions in the space provided. Show all your work 1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure the initial reaction rate and the starting concentrations of the reactions for 4 trials. BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l) Initial rate Trial [BrO3] [H*] [Br] (mol/L) (mol/L) | (mol/L) (mol/L.s) 1 0.10 0.10 0.10 8.0 2 0.20 0.10 0.10 16 3 0.10 0.20 0.10 16 4 0.10 0.10 0.20 32 a. Based on the above data what is the rate law expression? b. Solve for the value of k (make sure to include proper units) 2. The proposed reaction mechanism is as follows: i. ii. BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq) HBrO³ (aq) + H* (aq) → H₂BrO3* (aq) iii. H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l) [Fast] [Medium] [Slow] iv. Br₂O₂ (aq) + 4H*(aq) + 4Br‍(aq) → 3Br₂ (l) + H2O (l) [Fast] Evaluate the validity of this proposed reaction. Justify your answer.

Answer 2

Question

Chapter 12, Problem 12.87SP

Interpretation Introduction

Interpretation:

The difference between rate determining step and other steps in a multistep reaction mechanism has to be given and also the effect of rate determining step in observed rate law has to be given.

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Answer 3

Question

Chapter 12, Problem 12.87SP

Interpretation Introduction

Interpretation:

The difference between rate determining step and other steps in a multistep reaction mechanism has to be given and also the effect of rate determining step in observed rate law has to be given.

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Answer 4

Question

Chapter 12, Problem 12.87SP

Interpretation Introduction

Interpretation:

The difference between rate determining step and other steps in a multistep reaction mechanism has to be given and also the effect of rate determining step in observed rate law has to be given.

Expert Solution & Answer

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Answer 5

Chapter 12, Problem 12.87SP

Interpretation Introduction

Interpretation:

The difference between rate determining step and other steps in a multistep reaction mechanism has to be given and also the effect of rate determining step in observed rate law has to be given.

Answer 6

Chapter 12, Problem 12.87SP

Interpretation Introduction

Interpretation:

The difference between rate determining step and other steps in a multistep reaction mechanism has to be given and also the effect of rate determining step in observed rate law has to be given.

Answer 7

Chapter 12, Problem 12.87SP

Interpretation Introduction

Interpretation:

The difference between rate determining step and other steps in a multistep reaction mechanism has to be given and also the effect of rate determining step in observed rate law has to be given.

Answer 8

Expert Solution & Answer

Answer 9

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Answer 11

Ch. 12.1 - The oxidation of iodide ion by arsenic acid,...Ch. 12.1 - Prob. 12.2P Ch. 12.2 - Consider the last two reactions in Table 12.2....Ch. 12.3 - The oxidation of iodide ion by hydrogen peroxide...Ch. 12.3 - Prob. 12.5P Ch. 12.3 - Prob. 12.6CP Ch. 12.4 - Prob. 12.7P Ch. 12.4 - Prob. 12.8P Ch. 12.5 - Prob. 12.9P Ch. 12.5 - Prob. 12.10CP

The difference between rate determining step and other steps in a multistep reaction mechanism has to be given and also the effect of rate determining step in observed rate law has to be given.

Solution Summary: The author explains the difference between rate determining step and other steps in a multistep reaction mechanism.

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Interpretation:

The difference between rate determining step and other steps in a multistep reaction mechanism has to be given and also the effect of rate determining step in observed rate law has to be given.

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Chapter 12 Solutions

The difference between rate determining step and other steps in a multistep reaction mechanism has to be given and also the effect of rate determining step in observed rate law has to be given.

Solution Summary: The author explains the difference between rate determining step and other steps in a multistep reaction mechanism.

Videos

Interpretation: The difference between rate determining step and other steps in a multistep reaction mechanism has to be given and also the effect of rate determining step in observed rate law has to be given.

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Chapter 12 Solutions

Interpretation:

The difference between rate determining step and other steps in a multistep reaction mechanism has to be given and also the effect of rate determining step in observed rate law has to be given.