General Chemistry: Atoms First
2nd Edition
ISBN: 9780321809261
Author: John E. McMurry, Robert C. Fay
Publisher: Prentice Hall
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Chapter 12, Problem 12.88SP
(a)
Interpretation Introduction
Interpretation:
The chemical equation for the overall reaction has to be written.
(b)
Interpretation Introduction
Interpretation:
The intermediate of the given reaction has to be identified.
(c)
Interpretation Introduction
Interpretation:
The molecularity of the given each elementary reaction has to be given.
Concept introduction:
Molecularity of reaction:
Unimolecular: A molecule (reactant) undergoes rearrangement itself to give one or more products is said to be unimolecuar reactions.
Bimolecular: Two molecules (reactants) undergo collisions to give one or more products is said to be bimolecular reactions.
Termolecular: Three molecules undergo collision to give one or more products is said to be termolecular reactions.
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Students have asked these similar questions
Propose syntheses of the following compounds starting with benzene or toluene. Assume ortho and
isomers can be separated.
a.
b.
O₂N-
Cl
COOH
para
0. Propose syntheses to carry out each of the following conversions. Assume ortho and para isomers can
be separated
a.
Br
b.
COOH
CH3
NH₂
PABA
(active ingredient in some sunscreens)
H3C
H
C=C
CH3
H
m-chloroperoxybenzoic acid
CH2Cl2, rt
C-C--.
H3CH2CC
H
H3C CH3
Cl₂
H₂O
NaOH
H₂O
D.
S-
E.
CH3
H₂O₂, H₂O
It
CH₂O Na
+
CHI
F.
HI, H₂O
heat
G.
4
OH
CH3CHCH3 + ICH2CH3
1. NaH
(CH3)3COH
(CH3)3 COCHCH2CH3
2.
CH3
5. Show how the ether below could be prepared from toluene and any other necessary reagents. Show all
reagents and all intermediate structures.
H3C-
H3C-
CI
OCH2CH3
Chapter 12 Solutions
General Chemistry: Atoms First
Ch. 12.1 - The oxidation of iodide ion by arsenic acid,...Ch. 12.1 - Prob. 12.2PCh. 12.2 - Consider the last two reactions in Table 12.2....Ch. 12.3 - The oxidation of iodide ion by hydrogen peroxide...Ch. 12.3 - Prob. 12.5PCh. 12.3 - Prob. 12.6CPCh. 12.4 - Prob. 12.7PCh. 12.4 - Prob. 12.8PCh. 12.5 - Prob. 12.9PCh. 12.5 - Prob. 12.10CP
Ch. 12.6 - Prob. 12.11PCh. 12.6 - Prob. 12.12PCh. 12.6 - Prob. 12.13PCh. 12.6 - Prob. 12.14PCh. 12.7 - Prob. 12.15PCh. 12.9 - Prob. 12.16CPCh. 12.10 - Prob. 12.17PCh. 12.11 - Prob. 12.18PCh. 12.12 - Prob. 12.19PCh. 12.13 - Prob. 12.20PCh. 12.13 - Prob. 12.21PCh. 12.14 - Prob. 12.22CPCh. 12.15 - Prob. 12.23PCh. 12 - The following reaction is first order in A (red...Ch. 12 - Consider the first-order decomposition of A...Ch. 12 - Prob. 12.26CPCh. 12 - The following pictures represent the progress of...Ch. 12 - Prob. 12.28CPCh. 12 - Prob. 12.29CPCh. 12 - The relative rates of the reaction A + B AB in...Ch. 12 - Prob. 12.31CPCh. 12 - Prob. 12.32CPCh. 12 - Prob. 12.33CPCh. 12 - Prob. 12.34SPCh. 12 - Prob. 12.35SPCh. 12 - Prob. 12.36SPCh. 12 - Prob. 12.37SPCh. 12 - Prob. 12.38SPCh. 12 - Prob. 12.39SPCh. 12 - Prob. 12.40SPCh. 12 - The oxidation of 2-butanone (CH3COC2H5) by the...Ch. 12 - Prob. 12.42SPCh. 12 - The reaction 2 NO(g) + 2 H2(g) N2(g) + 2 H2O(g)...Ch. 12 - Bromomethane is converted to methanol in an...Ch. 12 - The oxidation of Br by BRO3, in acidic solution is...Ch. 12 - Prob. 12.46SPCh. 12 - Prob. 12.47SPCh. 12 - Prob. 12.48SPCh. 12 - Prob. 12.49SPCh. 12 - The initial rates listed in the following table...Ch. 12 - Prob. 12.51SPCh. 12 - Prob. 12.52SPCh. 12 - The rearrangement of methyl isonitrile (CH3NC) to...Ch. 12 - Prob. 12.54SPCh. 12 - What is the half-life (in hours) of the reaction...Ch. 12 - Prob. 12.56SPCh. 12 - Prob. 12.57SPCh. 12 - Prob. 12.58SPCh. 12 - What is the half-life (in days) of the reaction in...Ch. 12 - Prob. 12.60SPCh. 12 - Prob. 12.61SPCh. 12 - Prob. 12.62SPCh. 12 - Prob. 12.63SPCh. 12 - Prob. 12.64SPCh. 12 - Prob. 12.65SPCh. 12 - Prob. 12.66SPCh. 12 - Prob. 12.67SPCh. 12 - Prob. 12.68SPCh. 12 - Prob. 12.69SPCh. 12 - Prob. 12.70SPCh. 12 - Prob. 12.71SPCh. 12 - Prob. 12.72SPCh. 12 - Prob. 12.73SPCh. 12 - Prob. 12.74SPCh. 12 - Prob. 12.75SPCh. 12 - Prob. 12.76SPCh. 12 - Prob. 12.77SPCh. 12 - Prob. 12.78SPCh. 12 - Prob. 12.79SPCh. 12 - Rate constants for the reaction NO2(g) + CO(g) ...Ch. 12 - Prob. 12.81SPCh. 12 - Prob. 12.82SPCh. 12 - Prob. 12.83SPCh. 12 - Prob. 12.84SPCh. 12 - Prob. 12.85SPCh. 12 - Prob. 12.86SPCh. 12 - Prob. 12.87SPCh. 12 - Prob. 12.88SPCh. 12 - Prob. 12.89SPCh. 12 - Prob. 12.90SPCh. 12 - Prob. 12.91SPCh. 12 - Prob. 12.92SPCh. 12 - Prob. 12.93SPCh. 12 - The reaction 2 NO2(g) + F2(g) 2 NO2F(g) has a...Ch. 12 - Prob. 12.95SPCh. 12 - Prob. 12.96SPCh. 12 - Prob. 12.97SPCh. 12 - Prob. 12.98SPCh. 12 - Prob. 12.99SPCh. 12 - Prob. 12.100SPCh. 12 - Sulfur dioxide is oxidized to sulfur trioxide in...Ch. 12 - Consider the following mechanism for the...Ch. 12 - Prob. 12.103SPCh. 12 - Prob. 12.104CHPCh. 12 - Prob. 12.105CHPCh. 12 - Prob. 12.106CHPCh. 12 - Consider three reactions with different values of...Ch. 12 - Prob. 12.108CHPCh. 12 - Prob. 12.109CHPCh. 12 - Prob. 12.110CHPCh. 12 - When the temperature of a gas is raised by 10 C,...Ch. 12 - Prob. 12.112CHPCh. 12 - Prob. 12.113CHPCh. 12 - Prob. 12.114CHPCh. 12 - Prob. 12.115CHPCh. 12 - Prob. 12.116CHPCh. 12 - Prob. 12.117CHPCh. 12 - Prob. 12.118CHPCh. 12 - Consider the following concentrationtime data for...Ch. 12 - Prob. 12.120CHPCh. 12 - Prob. 12.121CHPCh. 12 - Prob. 12.122CHPCh. 12 - Prob. 12.123CHPCh. 12 - Assume that you are studying the first-order...Ch. 12 - Prob. 12.125CHPCh. 12 - Prob. 12.126CHPCh. 12 - Prob. 12.127CHPCh. 12 - Prob. 12.128CHPCh. 12 - Use the following initial rate data to determine...Ch. 12 - Prob. 12.130CHPCh. 12 - The following experimental data were obtained in a...Ch. 12 - Prob. 12.132CHPCh. 12 - Prob. 12.133CHPCh. 12 - Prob. 12.134CHPCh. 12 - Prob. 12.135CHPCh. 12 - Polytetrafluoroethylene (Teflon) decomposes when...Ch. 12 - Values of Ea = 6.3 kJ/mol and A = 6.0 108 M1 s1...Ch. 12 - Prob. 12.138MPCh. 12 - The rate constant for the decomposition of gaseous...Ch. 12 - Prob. 12.140MPCh. 12 - Prob. 12.141MPCh. 12 - Prob. 12.142MPCh. 12 - Prob. 12.143MP
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