General Chemistry: Atoms First
2nd Edition
ISBN: 9780321809261
Author: John E. McMurry, Robert C. Fay
Publisher: Prentice Hall
expand_more
expand_more
format_list_bulleted
Question
Chapter 12, Problem 12.123CHP
Interpretation Introduction
Interpretation:
The decay constant of
Concept introduction:
Half-life time: It is the time required for the reactant (substrate) concentration reduces to one-half of its initial concentration.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
Estimate the decay of carbon (Precalculus 1)
Fluorine-18 is a radioactive isotope that decays by positron emission to form oxygen-18 with a half-life of
109.7 min. (A positron is a particle with the mass of an electron and a single unit of positive charge; the equation is
SIF 0+e.) Physicians use 18F to study the brain by injecting a quantity of fluoro-substituted glucose into
the blood of a patient. The glucose accumulates in the regions where the brain is active and needs nourishment.
(a) What is the rate constant for the decomposition of fluorine-18?
(b) If a sample of glucose containing radioactive fluorine-18 is injected into the blood, what percent of the
radioactivity will remain after 5.59 h?
(c) How long does it take for 99.99% of the 18F to decay?
A chemical exposure occurs by ingestion. The dose is absorbed very quickly into the bloodstream, so that the concentration of the chemical in the bloodstream jumps almost immediately to its highest level, Concentration (Co) 13.7mg/mL. The concentration of the chemical then decays exponentially. The decay constant for the drug is 0.4055 per hour. What will the blood concentration be after 4 hours?
Chapter 12 Solutions
General Chemistry: Atoms First
Ch. 12.1 - The oxidation of iodide ion by arsenic acid,...Ch. 12.1 - Prob. 12.2PCh. 12.2 - Consider the last two reactions in Table 12.2....Ch. 12.3 - The oxidation of iodide ion by hydrogen peroxide...Ch. 12.3 - Prob. 12.5PCh. 12.3 - Prob. 12.6CPCh. 12.4 - Prob. 12.7PCh. 12.4 - Prob. 12.8PCh. 12.5 - Prob. 12.9PCh. 12.5 - Prob. 12.10CP
Ch. 12.6 - Prob. 12.11PCh. 12.6 - Prob. 12.12PCh. 12.6 - Prob. 12.13PCh. 12.6 - Prob. 12.14PCh. 12.7 - Prob. 12.15PCh. 12.9 - Prob. 12.16CPCh. 12.10 - Prob. 12.17PCh. 12.11 - Prob. 12.18PCh. 12.12 - Prob. 12.19PCh. 12.13 - Prob. 12.20PCh. 12.13 - Prob. 12.21PCh. 12.14 - Prob. 12.22CPCh. 12.15 - Prob. 12.23PCh. 12 - The following reaction is first order in A (red...Ch. 12 - Consider the first-order decomposition of A...Ch. 12 - Prob. 12.26CPCh. 12 - The following pictures represent the progress of...Ch. 12 - Prob. 12.28CPCh. 12 - Prob. 12.29CPCh. 12 - The relative rates of the reaction A + B AB in...Ch. 12 - Prob. 12.31CPCh. 12 - Prob. 12.32CPCh. 12 - Prob. 12.33CPCh. 12 - Prob. 12.34SPCh. 12 - Prob. 12.35SPCh. 12 - Prob. 12.36SPCh. 12 - Prob. 12.37SPCh. 12 - Prob. 12.38SPCh. 12 - Prob. 12.39SPCh. 12 - Prob. 12.40SPCh. 12 - The oxidation of 2-butanone (CH3COC2H5) by the...Ch. 12 - Prob. 12.42SPCh. 12 - The reaction 2 NO(g) + 2 H2(g) N2(g) + 2 H2O(g)...Ch. 12 - Bromomethane is converted to methanol in an...Ch. 12 - The oxidation of Br by BRO3, in acidic solution is...Ch. 12 - Prob. 12.46SPCh. 12 - Prob. 12.47SPCh. 12 - Prob. 12.48SPCh. 12 - Prob. 12.49SPCh. 12 - The initial rates listed in the following table...Ch. 12 - Prob. 12.51SPCh. 12 - Prob. 12.52SPCh. 12 - The rearrangement of methyl isonitrile (CH3NC) to...Ch. 12 - Prob. 12.54SPCh. 12 - What is the half-life (in hours) of the reaction...Ch. 12 - Prob. 12.56SPCh. 12 - Prob. 12.57SPCh. 12 - Prob. 12.58SPCh. 12 - What is the half-life (in days) of the reaction in...Ch. 12 - Prob. 12.60SPCh. 12 - Prob. 12.61SPCh. 12 - Prob. 12.62SPCh. 12 - Prob. 12.63SPCh. 12 - Prob. 12.64SPCh. 12 - Prob. 12.65SPCh. 12 - Prob. 12.66SPCh. 12 - Prob. 12.67SPCh. 12 - Prob. 12.68SPCh. 12 - Prob. 12.69SPCh. 12 - Prob. 12.70SPCh. 12 - Prob. 12.71SPCh. 12 - Prob. 12.72SPCh. 12 - Prob. 12.73SPCh. 12 - Prob. 12.74SPCh. 12 - Prob. 12.75SPCh. 12 - Prob. 12.76SPCh. 12 - Prob. 12.77SPCh. 12 - Prob. 12.78SPCh. 12 - Prob. 12.79SPCh. 12 - Rate constants for the reaction NO2(g) + CO(g) ...Ch. 12 - Prob. 12.81SPCh. 12 - Prob. 12.82SPCh. 12 - Prob. 12.83SPCh. 12 - Prob. 12.84SPCh. 12 - Prob. 12.85SPCh. 12 - Prob. 12.86SPCh. 12 - Prob. 12.87SPCh. 12 - Prob. 12.88SPCh. 12 - Prob. 12.89SPCh. 12 - Prob. 12.90SPCh. 12 - Prob. 12.91SPCh. 12 - Prob. 12.92SPCh. 12 - Prob. 12.93SPCh. 12 - The reaction 2 NO2(g) + F2(g) 2 NO2F(g) has a...Ch. 12 - Prob. 12.95SPCh. 12 - Prob. 12.96SPCh. 12 - Prob. 12.97SPCh. 12 - Prob. 12.98SPCh. 12 - Prob. 12.99SPCh. 12 - Prob. 12.100SPCh. 12 - Sulfur dioxide is oxidized to sulfur trioxide in...Ch. 12 - Consider the following mechanism for the...Ch. 12 - Prob. 12.103SPCh. 12 - Prob. 12.104CHPCh. 12 - Prob. 12.105CHPCh. 12 - Prob. 12.106CHPCh. 12 - Consider three reactions with different values of...Ch. 12 - Prob. 12.108CHPCh. 12 - Prob. 12.109CHPCh. 12 - Prob. 12.110CHPCh. 12 - When the temperature of a gas is raised by 10 C,...Ch. 12 - Prob. 12.112CHPCh. 12 - Prob. 12.113CHPCh. 12 - Prob. 12.114CHPCh. 12 - Prob. 12.115CHPCh. 12 - Prob. 12.116CHPCh. 12 - Prob. 12.117CHPCh. 12 - Prob. 12.118CHPCh. 12 - Consider the following concentrationtime data for...Ch. 12 - Prob. 12.120CHPCh. 12 - Prob. 12.121CHPCh. 12 - Prob. 12.122CHPCh. 12 - Prob. 12.123CHPCh. 12 - Assume that you are studying the first-order...Ch. 12 - Prob. 12.125CHPCh. 12 - Prob. 12.126CHPCh. 12 - Prob. 12.127CHPCh. 12 - Prob. 12.128CHPCh. 12 - Use the following initial rate data to determine...Ch. 12 - Prob. 12.130CHPCh. 12 - The following experimental data were obtained in a...Ch. 12 - Prob. 12.132CHPCh. 12 - Prob. 12.133CHPCh. 12 - Prob. 12.134CHPCh. 12 - Prob. 12.135CHPCh. 12 - Polytetrafluoroethylene (Teflon) decomposes when...Ch. 12 - Values of Ea = 6.3 kJ/mol and A = 6.0 108 M1 s1...Ch. 12 - Prob. 12.138MPCh. 12 - The rate constant for the decomposition of gaseous...Ch. 12 - Prob. 12.140MPCh. 12 - Prob. 12.141MPCh. 12 - Prob. 12.142MPCh. 12 - Prob. 12.143MP
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- The radioactive isotope 64Cu is used in the form of copper(II) acetate to study Wilsons disease. The isotope has a half-life of 12.70 hours. What fraction of radioactive copper(II) acetate remains after 64 hours?arrow_forwardFluorine-18 is a radioactive isotope that decays by positron emission to form oxygen-18 with a half-life of 109.7 min. (A positron is a particle with the mass of an electron and a single unit of positive charge; the equation is F918O188+e+10 Physicians use 18F to study the brain by injecting a quantity of ?uoro-substituted glucose into the blood of a patient. The glucose accumulates in the regions where the brain is active and needs nourishment. (a) What is the rate constant for [lie decomposition of ?uorine-18? (b) If a sample of glucose containing radioactive fluorine-18 is injected into the blood, what percent of the radioactivity will remain after 5.59 h? (c) How long does it take for 99.99% of the 18F to decay?arrow_forward7-43 (Chemical Connections 7A and 7B) Why is a high fever dangerous? Why is a low body temperature dangerous?arrow_forward
- Technetium-99 is often used for assessing heart, liver, and lung damage because certain technetium compounds are absorbed by damaged tissues. It has a half-life of 6.0 h. Calculate the rate constant for the decay of T4399c.arrow_forwardScientists can determine the age of ancient objects by the method of radiocarbon dating. The bombardment of the upper atmosphere by cosmic rays converts nitrogen to a radioactive isotope of carbon, 14C, with a half-life of about 5,730 years. Vegetation absorbs carbon dioxide through the atmosphere, and animal life assimilates 14C through food chains. When a plant or animal dies, it stops replacing its carbon, and the amount of 14C present begins to decrease through radioactive decay. Therefore, the level of radioactivity must also decay exponentially. Dinosaur fossils are too old to be reliably dated using carbon-14. Suppose we had a 66 million year old dinosaur fossil. What percent of the living dinosaur's 14C would be remaining today? (Round your answer to five decimal places.) 0.0000007537 X % Suppose the minimum detectable amount is 0.2%. What is the maximum age (in years) of a fossil that we could date using 14C? (Round your answer to the nearest year.) yrarrow_forwardScientists can determine the age of ancient objects by the method of radiocarbon dating. The bombardment of the upper atmosphere by cosmic rays converts nitrogen to a radioactive isotope of carbon, 14C, with a half-life of about 5,730 years. Vegetation absorbs carbon dioxide through the atmosphere, and animal life assimilates 14C through food chains. When a plant or animal dies, it stops replacing its carbon, and the amount of 14C present begins to decrease through radioactive decay. Therefore, the level of radioactivity must also decay exponentially. a) Dinosaur fossils are too old to be reliably dated using carbon-14. Suppose we had a 67 million year old dinosaur fossil. What percent of the living dinosaur's 14C would be remaining today? (Round your answer to five decimal places.) b) Suppose the minimum detectable amount is 0.7%. What is the maximum age (in years) of a fossil that we could date using 14C? (Round your answer to the nearest year.)arrow_forward
- The radioactive isotope carbon-14 is present in small quantities in all life forms, and it is constantly replenished until the organism dies, after which it decays to stable carbon-12 at a rate proportional to the amount of carbon-14 present, with a half-life of 5550 years. Suppose C(t) is the amount of carbon-14 present at time t. (a) Find the value of the constant k in the differential equation C′=−kC. k= ? (b) In 1988 three teams of scientists found that the Shroud of Turin, which was reputed to be the burial cloth of Jesus, contained about 91 percent of the amount of carbon-14 contained in freshly made cloth of the same material[1]. How was old the Shroud of Turin in 1988, according to these data? Age = ? years [1]: The New York Times, October 18, 1988.arrow_forwardScientists can determine the age of ancient objects by the method of radiocarbon dating. The bombardment of the upper atmosphere by cosmic rays converts nitrogen to radioactive isotope of carbon, 14C, with a half-life of about 5730 years. Vegetation absorbs carbon dioxide through the atmosphere and animal life assimilates 14C through food chains. When a plant or animal dies, it stops replacing its carbon and the amount of ¹4C begins to decrease through radioactive decay. Therefore the level of radioactivity must also decay exponentially. A parchment fragment was discovered that had about 74% as much 14C radioactivity as does plant material on earth today. Estimate the age of the parchment. (Round your answer to the nearest whole number.) yr Need Help? Watch It Additional Materials eBookarrow_forwardTritium,3 1 H , an isotope of hydrogen has a half-life of 12.33 years. Its decay constant in years-1 isarrow_forward
- A certain signal molecule S in muscle tissue is degraded by two different biochemical pathways: when only Path 1 is active, the half-life of S is 4.8 s. When only Path 2 is active, the half-life of S is 80.6 s. Calculate the half-life of S when both pathways are active. Rounded your answer to 2 significant digits. Пs S x10 X 5arrow_forward12. The half-life for the decay of the Uranlum (U)Isotope to the Lead (Pb)2 Isotope Is 4.5 x 10 years. Mass spectrometer data for a basaltic lava sample Indicates that the sample contalns 96%6 (U) and 4% (Pb)zz How old Is the basalt? N-N,e** a. 4.5 x 10 years b. 4.02 x 10 years c. 2.65 x 10 years d. 6.84 x 10 yearsarrow_forwardThe technique known as potassiumargon dating is used to date volcanicrock and ash, and thus establish dates for nearby fossils, like this 1.8-millionyear- old hominid skull. The potassium isotope 40K decays with a 1.28-billionyear half-life and is naturally present at very low levels. The most common decay mode is beta-minus decay into the stable isotope 40Ca, but 10.9% of decays result in the stable isotope 40Ar. The high temperatures in volcanoes drive argon out of solidifying rock and ash, so there is no argon in newly formed material. After formation, argon produced in the decay of 40K is trapped, so 40Ar builds up steadily over time. Accurate dating ispossible by measuring the ratio of the number of atoms of 40Ar and 40K. 1.8 million years after its formation,a. What fraction of the 40K initially present in a sample has decayed?b. What is the 40Ar/40K ratio of the sample?arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Chemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage LearningChemistry for Engineering StudentsChemistryISBN:9781285199023Author:Lawrence S. Brown, Tom HolmePublisher:Cengage LearningChemistry for Engineering StudentsChemistryISBN:9781337398909Author:Lawrence S. Brown, Tom HolmePublisher:Cengage Learning
- Chemistry by OpenStax (2015-05-04)ChemistryISBN:9781938168390Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark BlaserPublisher:OpenStaxChemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning
Chemistry for Engineering Students
Chemistry
ISBN:9781285199023
Author:Lawrence S. Brown, Tom Holme
Publisher:Cengage Learning
Chemistry for Engineering Students
Chemistry
ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Cengage Learning
Chemistry by OpenStax (2015-05-04)
Chemistry
ISBN:9781938168390
Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:OpenStax
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Kinetics: Initial Rates and Integrated Rate Laws; Author: Professor Dave Explains;https://www.youtube.com/watch?v=wYqQCojggyM;License: Standard YouTube License, CC-BY