
General Chemistry: Atoms First
2nd Edition
ISBN: 9780321809261
Author: John E. McMurry, Robert C. Fay
Publisher: Prentice Hall
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Chapter 12, Problem 12.84SP
Interpretation Introduction
Interpretation:
For the given decomposition reaction of hydrogen iodide, the potential energy diagram has to be given with appropriate labels.
Concept introduction:
Activation energy
The minimum amount of energy required to start a given
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b) Certain cyclic compounds are known to be conformationally similar to carbohydrates, although they are not
themselves carbohydrates. One example is Compound C shown below, which could be imagined as adopting
four possible conformations. In reality, however, only one of these is particularly stable. Circle the conformation
you expect to be the most stable, and provide an explanation to justify your choice. For your explanation to be
both convincing and correct, it must contain not only words, but also "cartoon" orbital drawings contrasting the
four structures.
Compound C
Possible conformations (circle one):
Дет
Lab Data
The distance entered is out of the expected range.
Check your calculations and conversion factors.
Verify your distance. Will the gas cloud be closer to the cotton ball with HCI or NH3?
Did you report your data to the correct number of significant figures?
- X
Experimental Set-up
HCI-NH3
NH3-HCI
Longer Tube
Time elapsed (min)
5 (exact)
5 (exact)
Distance between cotton balls (cm)
24.30
24.40
Distance to cloud (cm)
9.70
14.16
Distance traveled by HCI (cm)
9.70
9.80
Distance traveled by NH3 (cm)
14.60
14.50
Diffusion rate of HCI (cm/hr)
116
118
Diffusion rate of NH3 (cm/hr)
175.2
175.2
How to measure distance and calculate rate
For the titration of a divalent metal ion (M2+) with EDTA, the stoichiometry of the reaction is typically:
1:1 (one mole of EDTA per mole of metal ion)
2:1 (two moles of EDTA per mole of metal ion)
1:2 (one mole of EDTA per two moles of metal ion)
None of the above
Chapter 12 Solutions
General Chemistry: Atoms First
Ch. 12.1 - The oxidation of iodide ion by arsenic acid,...Ch. 12.1 - Prob. 12.2PCh. 12.2 - Consider the last two reactions in Table 12.2....Ch. 12.3 - The oxidation of iodide ion by hydrogen peroxide...Ch. 12.3 - Prob. 12.5PCh. 12.3 - Prob. 12.6CPCh. 12.4 - Prob. 12.7PCh. 12.4 - Prob. 12.8PCh. 12.5 - Prob. 12.9PCh. 12.5 - Prob. 12.10CP
Ch. 12.6 - Prob. 12.11PCh. 12.6 - Prob. 12.12PCh. 12.6 - Prob. 12.13PCh. 12.6 - Prob. 12.14PCh. 12.7 - Prob. 12.15PCh. 12.9 - Prob. 12.16CPCh. 12.10 - Prob. 12.17PCh. 12.11 - Prob. 12.18PCh. 12.12 - Prob. 12.19PCh. 12.13 - Prob. 12.20PCh. 12.13 - Prob. 12.21PCh. 12.14 - Prob. 12.22CPCh. 12.15 - Prob. 12.23PCh. 12 - The following reaction is first order in A (red...Ch. 12 - Consider the first-order decomposition of A...Ch. 12 - Prob. 12.26CPCh. 12 - The following pictures represent the progress of...Ch. 12 - Prob. 12.28CPCh. 12 - Prob. 12.29CPCh. 12 - The relative rates of the reaction A + B AB in...Ch. 12 - Prob. 12.31CPCh. 12 - Prob. 12.32CPCh. 12 - Prob. 12.33CPCh. 12 - Prob. 12.34SPCh. 12 - Prob. 12.35SPCh. 12 - Prob. 12.36SPCh. 12 - Prob. 12.37SPCh. 12 - Prob. 12.38SPCh. 12 - Prob. 12.39SPCh. 12 - Prob. 12.40SPCh. 12 - The oxidation of 2-butanone (CH3COC2H5) by the...Ch. 12 - Prob. 12.42SPCh. 12 - The reaction 2 NO(g) + 2 H2(g) N2(g) + 2 H2O(g)...Ch. 12 - Bromomethane is converted to methanol in an...Ch. 12 - The oxidation of Br by BRO3, in acidic solution is...Ch. 12 - Prob. 12.46SPCh. 12 - Prob. 12.47SPCh. 12 - Prob. 12.48SPCh. 12 - Prob. 12.49SPCh. 12 - The initial rates listed in the following table...Ch. 12 - Prob. 12.51SPCh. 12 - Prob. 12.52SPCh. 12 - The rearrangement of methyl isonitrile (CH3NC) to...Ch. 12 - Prob. 12.54SPCh. 12 - What is the half-life (in hours) of the reaction...Ch. 12 - Prob. 12.56SPCh. 12 - Prob. 12.57SPCh. 12 - Prob. 12.58SPCh. 12 - What is the half-life (in days) of the reaction in...Ch. 12 - Prob. 12.60SPCh. 12 - Prob. 12.61SPCh. 12 - Prob. 12.62SPCh. 12 - Prob. 12.63SPCh. 12 - Prob. 12.64SPCh. 12 - Prob. 12.65SPCh. 12 - Prob. 12.66SPCh. 12 - Prob. 12.67SPCh. 12 - Prob. 12.68SPCh. 12 - Prob. 12.69SPCh. 12 - Prob. 12.70SPCh. 12 - Prob. 12.71SPCh. 12 - Prob. 12.72SPCh. 12 - Prob. 12.73SPCh. 12 - Prob. 12.74SPCh. 12 - Prob. 12.75SPCh. 12 - Prob. 12.76SPCh. 12 - Prob. 12.77SPCh. 12 - Prob. 12.78SPCh. 12 - Prob. 12.79SPCh. 12 - Rate constants for the reaction NO2(g) + CO(g) ...Ch. 12 - Prob. 12.81SPCh. 12 - Prob. 12.82SPCh. 12 - Prob. 12.83SPCh. 12 - Prob. 12.84SPCh. 12 - Prob. 12.85SPCh. 12 - Prob. 12.86SPCh. 12 - Prob. 12.87SPCh. 12 - Prob. 12.88SPCh. 12 - Prob. 12.89SPCh. 12 - Prob. 12.90SPCh. 12 - Prob. 12.91SPCh. 12 - Prob. 12.92SPCh. 12 - Prob. 12.93SPCh. 12 - The reaction 2 NO2(g) + F2(g) 2 NO2F(g) has a...Ch. 12 - Prob. 12.95SPCh. 12 - Prob. 12.96SPCh. 12 - Prob. 12.97SPCh. 12 - Prob. 12.98SPCh. 12 - Prob. 12.99SPCh. 12 - Prob. 12.100SPCh. 12 - Sulfur dioxide is oxidized to sulfur trioxide in...Ch. 12 - Consider the following mechanism for the...Ch. 12 - Prob. 12.103SPCh. 12 - Prob. 12.104CHPCh. 12 - Prob. 12.105CHPCh. 12 - Prob. 12.106CHPCh. 12 - Consider three reactions with different values of...Ch. 12 - Prob. 12.108CHPCh. 12 - Prob. 12.109CHPCh. 12 - Prob. 12.110CHPCh. 12 - When the temperature of a gas is raised by 10 C,...Ch. 12 - Prob. 12.112CHPCh. 12 - Prob. 12.113CHPCh. 12 - Prob. 12.114CHPCh. 12 - Prob. 12.115CHPCh. 12 - Prob. 12.116CHPCh. 12 - Prob. 12.117CHPCh. 12 - Prob. 12.118CHPCh. 12 - Consider the following concentrationtime data for...Ch. 12 - Prob. 12.120CHPCh. 12 - Prob. 12.121CHPCh. 12 - Prob. 12.122CHPCh. 12 - Prob. 12.123CHPCh. 12 - Assume that you are studying the first-order...Ch. 12 - Prob. 12.125CHPCh. 12 - Prob. 12.126CHPCh. 12 - Prob. 12.127CHPCh. 12 - Prob. 12.128CHPCh. 12 - Use the following initial rate data to determine...Ch. 12 - Prob. 12.130CHPCh. 12 - The following experimental data were obtained in a...Ch. 12 - Prob. 12.132CHPCh. 12 - Prob. 12.133CHPCh. 12 - Prob. 12.134CHPCh. 12 - Prob. 12.135CHPCh. 12 - Polytetrafluoroethylene (Teflon) decomposes when...Ch. 12 - Values of Ea = 6.3 kJ/mol and A = 6.0 108 M1 s1...Ch. 12 - Prob. 12.138MPCh. 12 - The rate constant for the decomposition of gaseous...Ch. 12 - Prob. 12.140MPCh. 12 - Prob. 12.141MPCh. 12 - Prob. 12.142MPCh. 12 - Prob. 12.143MP
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