The balanced equation for the given overall reaction has to be given. Concept introduction: In a balanced equation the number of atoms of each element as a reactant is equal to the number of atoms of that element as a product. Coefficient is a number placed before a formula in a chemical equation. A balanced equation should be obeying the law of conservation of mass. Law of conservation of mass states that, the number of atoms remains constant throughout the reaction, simply it can be stated as follows, “during a chemical reaction atoms are neither be created nor be destroyed”.

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Answer 1

Question

Chapter 12, Problem 12.97SP

(a)

Interpretation Introduction

Interpretation:

The balanced equation for the given overall reaction has to be given.

Concept introduction:

In a balanced equation the number of atoms of each element as a reactant is equal to the number of atoms of that element as a product.

Coefficient is a number placed before a formula in a chemical equation.

A balanced equation should be obeying the law of conservation of mass. Law of conservation of mass states that, the number of atoms remains constant throughout the reaction, simply it can be stated as follows, “during a chemical reaction atoms are neither be created nor be destroyed”.

(b)

Interpretation Introduction

Interpretation:

The intermediates in the given reaction have to be identified.

Concept introduction:

Intermediate: Intermediate is a short lived molecule of a particular reaction which is formed from reactant molecules and then reacts further to form products. These molecule entities are not found in the overall reaction.

(c)

Interpretation Introduction

Interpretation:

Given mechanism is whether is consistent or not with the experimental rate law has to be shown.

Concept introduction:

Rate of reaction: The rate of a reaction is defined by the change in concentration of substrate (reactant) or target (product) with change in time.

Rate = Concentration change (in reactant or product)Time change

The rate law for the slowest step in a reaction mechanism (rate determining step) is the rate law for overall reaction.

Rate law: It is an equation that related to the dependence of the reaction rate on the concentration of each substrate (reactants).

Rate constant: Rate constant is an expression used to relate the rate of a reaction to the concentration of reactants participating in the reaction.

(d)

Interpretation Introduction

Interpretation:

The rate constant k has to be related to the rate constants of the elementary reactions.

Concept introduction:

Rate of reaction: The rate of a reaction is defined by the change in concentration of substrate (reactant) or target (product) with change in time.

Rate = Concentration change (in reactant or product)Time change

Rate law: It is an equation that related to the dependence of the reaction rate on the concentration of each substrate (reactants).

Rate constant: Rate constant is an expression used to relate the rate of a reaction to the concentration of reactants participating in the reaction.

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For each reaction below, decide if the first stable organic product that forms in solution will create a new C - C bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. NH2 tu ? ? OH Will the first product that forms in this reaction create a new CC bond? Yes No Will the first product that forms in this reaction create a new CC bond? Yes No C $ ©

As the lead product manager at OrganometALEKS Industries, you are trying to decide if the following reaction will make a molecule with a new C-C bond as its major product: 1. MgCl ? 2. H₂O* If this reaction will work, draw the major organic product or products you would expect in the drawing area below. If there's more than one major product, you can draw them in any arrangement you like. Be sure you use wedge and dash bonds if necessary, for example to distinguish between major products with different stereochemistry. If the major products of this reaction won't have a new CC bond, just check the box under the drawing area and leave it blank. Click and drag to start drawing a structure. This reaction will not make a product with a new CC bond. G m

Including activity coefficients, find [Hg22+] in saturated Hg2Br2 in 0.00100 M NH4 Ksp Hg2Br2 = 5.6×10-23.

Answer 2

Question

Chapter 12, Problem 12.97SP

(a)

Interpretation Introduction

Interpretation:

The balanced equation for the given overall reaction has to be given.

Concept introduction:

In a balanced equation the number of atoms of each element as a reactant is equal to the number of atoms of that element as a product.

Coefficient is a number placed before a formula in a chemical equation.

A balanced equation should be obeying the law of conservation of mass. Law of conservation of mass states that, the number of atoms remains constant throughout the reaction, simply it can be stated as follows, “during a chemical reaction atoms are neither be created nor be destroyed”.

(b)

Interpretation Introduction

Interpretation:

The intermediates in the given reaction have to be identified.

Concept introduction:

Intermediate: Intermediate is a short lived molecule of a particular reaction which is formed from reactant molecules and then reacts further to form products. These molecule entities are not found in the overall reaction.

(c)

Interpretation Introduction

Interpretation:

Given mechanism is whether is consistent or not with the experimental rate law has to be shown.

Concept introduction:

Rate of reaction: The rate of a reaction is defined by the change in concentration of substrate (reactant) or target (product) with change in time.

Rate = Concentration change (in reactant or product)Time change

The rate law for the slowest step in a reaction mechanism (rate determining step) is the rate law for overall reaction.

Rate law: It is an equation that related to the dependence of the reaction rate on the concentration of each substrate (reactants).

Rate constant: Rate constant is an expression used to relate the rate of a reaction to the concentration of reactants participating in the reaction.

(d)

Interpretation Introduction

Interpretation:

The rate constant k has to be related to the rate constants of the elementary reactions.

Concept introduction:

Rate of reaction: The rate of a reaction is defined by the change in concentration of substrate (reactant) or target (product) with change in time.

Rate = Concentration change (in reactant or product)Time change

Rate law: It is an equation that related to the dependence of the reaction rate on the concentration of each substrate (reactants).

Rate constant: Rate constant is an expression used to relate the rate of a reaction to the concentration of reactants participating in the reaction.

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Answer 3

Question

Chapter 12, Problem 12.97SP

(a)

Interpretation Introduction

Interpretation:

The balanced equation for the given overall reaction has to be given.

Concept introduction:

In a balanced equation the number of atoms of each element as a reactant is equal to the number of atoms of that element as a product.

Coefficient is a number placed before a formula in a chemical equation.

A balanced equation should be obeying the law of conservation of mass. Law of conservation of mass states that, the number of atoms remains constant throughout the reaction, simply it can be stated as follows, “during a chemical reaction atoms are neither be created nor be destroyed”.

(b)

Interpretation Introduction

Interpretation:

The intermediates in the given reaction have to be identified.

Concept introduction:

Intermediate: Intermediate is a short lived molecule of a particular reaction which is formed from reactant molecules and then reacts further to form products. These molecule entities are not found in the overall reaction.

(c)

Interpretation Introduction

Interpretation:

Given mechanism is whether is consistent or not with the experimental rate law has to be shown.

Concept introduction:

Rate of reaction: The rate of a reaction is defined by the change in concentration of substrate (reactant) or target (product) with change in time.

Rate = Concentration change (in reactant or product)Time change

The rate law for the slowest step in a reaction mechanism (rate determining step) is the rate law for overall reaction.

Rate law: It is an equation that related to the dependence of the reaction rate on the concentration of each substrate (reactants).

Rate constant: Rate constant is an expression used to relate the rate of a reaction to the concentration of reactants participating in the reaction.

(d)

Interpretation Introduction

Interpretation:

The rate constant k has to be related to the rate constants of the elementary reactions.

Concept introduction:

Rate of reaction: The rate of a reaction is defined by the change in concentration of substrate (reactant) or target (product) with change in time.

Rate = Concentration change (in reactant or product)Time change

Rate law: It is an equation that related to the dependence of the reaction rate on the concentration of each substrate (reactants).

Rate constant: Rate constant is an expression used to relate the rate of a reaction to the concentration of reactants participating in the reaction.

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Answer 4

Question

Chapter 12, Problem 12.97SP

(a)

Interpretation Introduction

Interpretation:

The balanced equation for the given overall reaction has to be given.

Concept introduction:

In a balanced equation the number of atoms of each element as a reactant is equal to the number of atoms of that element as a product.

Coefficient is a number placed before a formula in a chemical equation.

A balanced equation should be obeying the law of conservation of mass. Law of conservation of mass states that, the number of atoms remains constant throughout the reaction, simply it can be stated as follows, “during a chemical reaction atoms are neither be created nor be destroyed”.

(b)

Interpretation Introduction

Interpretation:

The intermediates in the given reaction have to be identified.

Concept introduction:

Intermediate: Intermediate is a short lived molecule of a particular reaction which is formed from reactant molecules and then reacts further to form products. These molecule entities are not found in the overall reaction.

(c)

Interpretation Introduction

Interpretation:

Given mechanism is whether is consistent or not with the experimental rate law has to be shown.

Concept introduction:

Rate of reaction: The rate of a reaction is defined by the change in concentration of substrate (reactant) or target (product) with change in time.

Rate = Concentration change (in reactant or product)Time change

The rate law for the slowest step in a reaction mechanism (rate determining step) is the rate law for overall reaction.

Rate law: It is an equation that related to the dependence of the reaction rate on the concentration of each substrate (reactants).

Rate constant: Rate constant is an expression used to relate the rate of a reaction to the concentration of reactants participating in the reaction.

(d)

Interpretation Introduction

Interpretation:

The rate constant k has to be related to the rate constants of the elementary reactions.

Concept introduction:

Rate of reaction: The rate of a reaction is defined by the change in concentration of substrate (reactant) or target (product) with change in time.

Rate = Concentration change (in reactant or product)Time change

Rate law: It is an equation that related to the dependence of the reaction rate on the concentration of each substrate (reactants).

Rate constant: Rate constant is an expression used to relate the rate of a reaction to the concentration of reactants participating in the reaction.

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Answer 5

Chapter 12, Problem 12.97SP

(a)

Interpretation Introduction

Interpretation:

The balanced equation for the given overall reaction has to be given.

Concept introduction:

In a balanced equation the number of atoms of each element as a reactant is equal to the number of atoms of that element as a product.

Coefficient is a number placed before a formula in a chemical equation.

A balanced equation should be obeying the law of conservation of mass. Law of conservation of mass states that, the number of atoms remains constant throughout the reaction, simply it can be stated as follows, “during a chemical reaction atoms are neither be created nor be destroyed”.

(b)

Interpretation Introduction

Interpretation:

The intermediates in the given reaction have to be identified.

Concept introduction:

Intermediate: Intermediate is a short lived molecule of a particular reaction which is formed from reactant molecules and then reacts further to form products. These molecule entities are not found in the overall reaction.

(c)

Interpretation Introduction

Interpretation:

Given mechanism is whether is consistent or not with the experimental rate law has to be shown.

Concept introduction:

Rate of reaction: The rate of a reaction is defined by the change in concentration of substrate (reactant) or target (product) with change in time.

Rate = Concentration change (in reactant or product)Time change

The rate law for the slowest step in a reaction mechanism (rate determining step) is the rate law for overall reaction.

Rate law: It is an equation that related to the dependence of the reaction rate on the concentration of each substrate (reactants).

Rate constant: Rate constant is an expression used to relate the rate of a reaction to the concentration of reactants participating in the reaction.

(d)

Interpretation Introduction

Interpretation:

The rate constant k has to be related to the rate constants of the elementary reactions.

Concept introduction:

Rate of reaction: The rate of a reaction is defined by the change in concentration of substrate (reactant) or target (product) with change in time.

Rate = Concentration change (in reactant or product)Time change

Rate law: It is an equation that related to the dependence of the reaction rate on the concentration of each substrate (reactants).

Rate constant: Rate constant is an expression used to relate the rate of a reaction to the concentration of reactants participating in the reaction.

Answer 6

Chapter 12, Problem 12.97SP

(a)

Interpretation Introduction

Interpretation:

The balanced equation for the given overall reaction has to be given.

Concept introduction:

In a balanced equation the number of atoms of each element as a reactant is equal to the number of atoms of that element as a product.

Coefficient is a number placed before a formula in a chemical equation.

A balanced equation should be obeying the law of conservation of mass. Law of conservation of mass states that, the number of atoms remains constant throughout the reaction, simply it can be stated as follows, “during a chemical reaction atoms are neither be created nor be destroyed”.

Answer 7

Chapter 12, Problem 12.97SP

(a)

Interpretation Introduction

Interpretation:

The balanced equation for the given overall reaction has to be given.

Concept introduction:

In a balanced equation the number of atoms of each element as a reactant is equal to the number of atoms of that element as a product.

Coefficient is a number placed before a formula in a chemical equation.

A balanced equation should be obeying the law of conservation of mass. Law of conservation of mass states that, the number of atoms remains constant throughout the reaction, simply it can be stated as follows, “during a chemical reaction atoms are neither be created nor be destroyed”.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The intermediates in the given reaction have to be identified.

Concept introduction:

Intermediate: Intermediate is a short lived molecule of a particular reaction which is formed from reactant molecules and then reacts further to form products. These molecule entities are not found in the overall reaction.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The intermediates in the given reaction have to be identified.

Concept introduction:

Intermediate: Intermediate is a short lived molecule of a particular reaction which is formed from reactant molecules and then reacts further to form products. These molecule entities are not found in the overall reaction.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Given mechanism is whether is consistent or not with the experimental rate law has to be shown.

Concept introduction:

Rate of reaction: The rate of a reaction is defined by the change in concentration of substrate (reactant) or target (product) with change in time.

Rate = Concentration change (in reactant or product)Time change

The rate law for the slowest step in a reaction mechanism (rate determining step) is the rate law for overall reaction.

Rate law: It is an equation that related to the dependence of the reaction rate on the concentration of each substrate (reactants).

Rate constant: Rate constant is an expression used to relate the rate of a reaction to the concentration of reactants participating in the reaction.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Given mechanism is whether is consistent or not with the experimental rate law has to be shown.

Concept introduction:

Rate of reaction: The rate of a reaction is defined by the change in concentration of substrate (reactant) or target (product) with change in time.

Rate = Concentration change (in reactant or product)Time change

The rate law for the slowest step in a reaction mechanism (rate determining step) is the rate law for overall reaction.

Rate law: It is an equation that related to the dependence of the reaction rate on the concentration of each substrate (reactants).

Rate constant: Rate constant is an expression used to relate the rate of a reaction to the concentration of reactants participating in the reaction.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The rate constant k has to be related to the rate constants of the elementary reactions.

Concept introduction:

Rate of reaction: The rate of a reaction is defined by the change in concentration of substrate (reactant) or target (product) with change in time.

Rate = Concentration change (in reactant or product)Time change

Rate law: It is an equation that related to the dependence of the reaction rate on the concentration of each substrate (reactants).

Rate constant: Rate constant is an expression used to relate the rate of a reaction to the concentration of reactants participating in the reaction.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The rate constant k has to be related to the rate constants of the elementary reactions.

Concept introduction:

Rate of reaction: The rate of a reaction is defined by the change in concentration of substrate (reactant) or target (product) with change in time.

Rate = Concentration change (in reactant or product)Time change

Rate law: It is an equation that related to the dependence of the reaction rate on the concentration of each substrate (reactants).

Rate constant: Rate constant is an expression used to relate the rate of a reaction to the concentration of reactants participating in the reaction.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 12.1 - The oxidation of iodide ion by arsenic acid,...Ch. 12.1 - Prob. 12.2P Ch. 12.2 - Consider the last two reactions in Table 12.2....Ch. 12.3 - The oxidation of iodide ion by hydrogen peroxide...Ch. 12.3 - Prob. 12.5P Ch. 12.3 - Prob. 12.6CP Ch. 12.4 - Prob. 12.7P Ch. 12.4 - Prob. 12.8P Ch. 12.5 - Prob. 12.9P Ch. 12.5 - Prob. 12.10CP

Solution Summary: The author explains that a balanced equation obeys the law of conservation of mass, which states that the number of atoms remains constant throughout the reaction.

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