General Chemistry: Atoms First
General Chemistry: Atoms First
2nd Edition
ISBN: 9780321809261
Author: John E. McMurry, Robert C. Fay
Publisher: Prentice Hall
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Chapter 12, Problem 12.53SP

The rearrangement of methyl isonitrile (CH3NC) to acetonitrile (CH3CN) is a first-order reaction and has a rate constant of 5.11 × 10−5 s−1 at 472 K.

CH 3 N C CH 3 C N

Chapter 12, Problem 12.53SP, The rearrangement of methyl isonitrile (CH3NC) to acetonitrile (CH3CN) is a first-order reaction and

If the initial concentration of CH3NC is 0.0340 M:

  1. (a) What is the molarity of CH3NC after 2.00 h?
  2. (b) How many minutes does it take for the CH3NC concentration to drop to 0.0300 M?
  3. (c) How many minutes does it take for 20% of the CH3NC to react?
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A first order reaction is 46.0% complete at the end of 59.0 minutes. What is the value of k? What is the half-life for this reaction? HOW DO WE GET THERE? The integrated rate law will be used to determine the value of k. In [A] [A]。 = = -kt What is the value of [A] [A]。 when the reaction is 46.0% complete?
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Chapter 12 Solutions

General Chemistry: Atoms First

Ch. 12.6 - Prob. 12.11PCh. 12.6 - Prob. 12.12PCh. 12.6 - Prob. 12.13PCh. 12.6 - Prob. 12.14PCh. 12.7 - Prob. 12.15PCh. 12.9 - Prob. 12.16CPCh. 12.10 - Prob. 12.17PCh. 12.11 - Prob. 12.18PCh. 12.12 - Prob. 12.19PCh. 12.13 - Prob. 12.20PCh. 12.13 - Prob. 12.21PCh. 12.14 - Prob. 12.22CPCh. 12.15 - Prob. 12.23PCh. 12 - The following reaction is first order in A (red...Ch. 12 - Consider the first-order decomposition of A...Ch. 12 - Prob. 12.26CPCh. 12 - The following pictures represent the progress of...Ch. 12 - Prob. 12.28CPCh. 12 - Prob. 12.29CPCh. 12 - The relative rates of the reaction A + B AB in...Ch. 12 - Prob. 12.31CPCh. 12 - Prob. 12.32CPCh. 12 - Prob. 12.33CPCh. 12 - Prob. 12.34SPCh. 12 - Prob. 12.35SPCh. 12 - Prob. 12.36SPCh. 12 - Prob. 12.37SPCh. 12 - Prob. 12.38SPCh. 12 - Prob. 12.39SPCh. 12 - Prob. 12.40SPCh. 12 - The oxidation of 2-butanone (CH3COC2H5) by the...Ch. 12 - Prob. 12.42SPCh. 12 - The reaction 2 NO(g) + 2 H2(g) N2(g) + 2 H2O(g)...Ch. 12 - Bromomethane is converted to methanol in an...Ch. 12 - The oxidation of Br by BRO3, in acidic solution is...Ch. 12 - Prob. 12.46SPCh. 12 - Prob. 12.47SPCh. 12 - Prob. 12.48SPCh. 12 - Prob. 12.49SPCh. 12 - The initial rates listed in the following table...Ch. 12 - Prob. 12.51SPCh. 12 - Prob. 12.52SPCh. 12 - The rearrangement of methyl isonitrile (CH3NC) to...Ch. 12 - Prob. 12.54SPCh. 12 - What is the half-life (in hours) of the reaction...Ch. 12 - Prob. 12.56SPCh. 12 - Prob. 12.57SPCh. 12 - Prob. 12.58SPCh. 12 - What is the half-life (in days) of the reaction in...Ch. 12 - Prob. 12.60SPCh. 12 - Prob. 12.61SPCh. 12 - Prob. 12.62SPCh. 12 - Prob. 12.63SPCh. 12 - Prob. 12.64SPCh. 12 - Prob. 12.65SPCh. 12 - Prob. 12.66SPCh. 12 - Prob. 12.67SPCh. 12 - Prob. 12.68SPCh. 12 - Prob. 12.69SPCh. 12 - Prob. 12.70SPCh. 12 - Prob. 12.71SPCh. 12 - Prob. 12.72SPCh. 12 - Prob. 12.73SPCh. 12 - Prob. 12.74SPCh. 12 - Prob. 12.75SPCh. 12 - Prob. 12.76SPCh. 12 - Prob. 12.77SPCh. 12 - Prob. 12.78SPCh. 12 - Prob. 12.79SPCh. 12 - Rate constants for the reaction NO2(g) + CO(g) ...Ch. 12 - Prob. 12.81SPCh. 12 - Prob. 12.82SPCh. 12 - Prob. 12.83SPCh. 12 - Prob. 12.84SPCh. 12 - Prob. 12.85SPCh. 12 - Prob. 12.86SPCh. 12 - Prob. 12.87SPCh. 12 - Prob. 12.88SPCh. 12 - Prob. 12.89SPCh. 12 - Prob. 12.90SPCh. 12 - Prob. 12.91SPCh. 12 - Prob. 12.92SPCh. 12 - Prob. 12.93SPCh. 12 - The reaction 2 NO2(g) + F2(g) 2 NO2F(g) has a...Ch. 12 - Prob. 12.95SPCh. 12 - Prob. 12.96SPCh. 12 - Prob. 12.97SPCh. 12 - Prob. 12.98SPCh. 12 - Prob. 12.99SPCh. 12 - Prob. 12.100SPCh. 12 - Sulfur dioxide is oxidized to sulfur trioxide in...Ch. 12 - Consider the following mechanism for the...Ch. 12 - Prob. 12.103SPCh. 12 - Prob. 12.104CHPCh. 12 - Prob. 12.105CHPCh. 12 - Prob. 12.106CHPCh. 12 - Consider three reactions with different values of...Ch. 12 - Prob. 12.108CHPCh. 12 - Prob. 12.109CHPCh. 12 - Prob. 12.110CHPCh. 12 - When the temperature of a gas is raised by 10 C,...Ch. 12 - Prob. 12.112CHPCh. 12 - Prob. 12.113CHPCh. 12 - Prob. 12.114CHPCh. 12 - Prob. 12.115CHPCh. 12 - Prob. 12.116CHPCh. 12 - Prob. 12.117CHPCh. 12 - Prob. 12.118CHPCh. 12 - Consider the following concentrationtime data for...Ch. 12 - Prob. 12.120CHPCh. 12 - Prob. 12.121CHPCh. 12 - Prob. 12.122CHPCh. 12 - Prob. 12.123CHPCh. 12 - Assume that you are studying the first-order...Ch. 12 - Prob. 12.125CHPCh. 12 - Prob. 12.126CHPCh. 12 - Prob. 12.127CHPCh. 12 - Prob. 12.128CHPCh. 12 - Use the following initial rate data to determine...Ch. 12 - Prob. 12.130CHPCh. 12 - The following experimental data were obtained in a...Ch. 12 - Prob. 12.132CHPCh. 12 - Prob. 12.133CHPCh. 12 - Prob. 12.134CHPCh. 12 - Prob. 12.135CHPCh. 12 - Polytetrafluoroethylene (Teflon) decomposes when...Ch. 12 - Values of Ea = 6.3 kJ/mol and A = 6.0 108 M1 s1...Ch. 12 - Prob. 12.138MPCh. 12 - The rate constant for the decomposition of gaseous...Ch. 12 - Prob. 12.140MPCh. 12 - Prob. 12.141MPCh. 12 - Prob. 12.142MPCh. 12 - Prob. 12.143MP
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