IUPAC name for the given alkane has to be written. Concept Introduction: Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word. Prefix represents the substituent present in the molecule and its position in the root name. Suffix denotes the presence of functional group if any in the molecule. It can be an alkene , alkyne , alcohol, carboxylic acid , alcohol etc. Root word represents the longest continuous carbon skeleton of the organic molecule. To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

Question

3. SYNTHESIS. Propose a sequence of synthetic steps (FGI) that convert the starting material (SM) into the Target molecule. For each FGI in your proposed synthesis, specify the reagents / conditions, and draw the product(s) of that FGI. DO NOT INCLUDE the FGI mxn in the answer you submit. If an FGI requires two reagent sets, specify the order in which the reagent sets are added, e.g., i) Hg(OAc)2 / H₂O; ii) NaBH4/MeOH. Indicate the stereochemistry (if any) of the products of each FGI. FGI 1. Me Starting Material Source of all carbons in the Target molecule (can use multiple copies) Me Me Target molecule + enantiomer

Answer 1

Question

Chapter 1, Problem 1.51EP

(a)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

(b)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

(c)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

(d)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

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3. SYNTHESIS. Propose a sequence of synthetic steps (FGI) that convert the starting material (SM) into the Target molecule. For each FGI in your proposed synthesis, specify the reagents / conditions, and draw the product(s) of that FGI. DO NOT INCLUDE the FGI mxn in the answer you submit. If an FGI requires two reagent sets, specify the order in which the reagent sets are added, e.g., i) Hg(OAc)2 / H₂O; ii) NaBH4/MeOH. Indicate the stereochemistry (if any) of the products of each FGI. FGI 1. Me Starting Material Source of all carbons in the Target molecule (can use multiple copies) Me Me Target molecule + enantiomer

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Answer 2

Question

Chapter 1, Problem 1.51EP

(a)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

(b)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

(c)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

(d)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

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Answer 3

Question

Chapter 1, Problem 1.51EP

(a)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

(b)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

(c)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

(d)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

Expert Solution & Answer

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Answer 4

Question

Chapter 1, Problem 1.51EP

(a)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

(b)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

(c)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

(d)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

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Answer 5

Chapter 1, Problem 1.51EP

(a)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

(b)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

(c)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

(d)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

Answer 6

Chapter 1, Problem 1.51EP

(a)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

Answer 7

Chapter 1, Problem 1.51EP

(a)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

Answer 8

(b)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

Answer 9

(b)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

Answer 10

(c)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

Answer 11

(c)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

Answer 12

(d)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

Answer 13

(d)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

Answer 14

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Answer 25

Ch. 1.1 - Prob. 1QQ Ch. 1.1 - Prob. 2QQ Ch. 1.2 - Which of the following statements about the...Ch. 1.2 - Prob. 2QQ Ch. 1.3 - Prob. 1QQ Ch. 1.3 - Prob. 2QQ Ch. 1.4 - Prob. 1QQ Ch. 1.4 - Prob. 2QQ Ch. 1.4 - Prob. 3QQ Ch. 1.5 - Prob. 1QQ

Solution Summary: The author explains that any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry).

Chapter 1 Solutions