Organic And Biological Chemistry
7th Edition
ISBN: 9781305081079
Author: STOKER, H. Stephen (howard Stephen)
Publisher: Cengage Learning,
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Textbook Question
Chapter 1, Problem 1.30EP
Explain why two different straight-chain
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d) Determine the formal charge on the nitrogen atom in each of the structures.
NH3
NH2
N
C
бобкат
: N
N
H
H
Н
H2N-OH
A
B
C
D
E
F
G
Lewis Structure, Hybridization & Molecular Geometry
a) Draw the Lewis Structure of the molecules; Label the hybridization of each carbon atom;
Predict the approximate molecular geometry around each carbon atom.
CH3CHO
CH3CN
b) Draw the Lewis Structure of Nitromethane; Predict the approximate molecular geometry
around the nitrogen atom.
CH3NO2
c) Draw the Lewis Structure; Label the hybridization of the boron atom; Predict the
approximate molecular geometry.
BF3
BF4
a. The structure of the bicarbonate (hydrogen carbonate) ion, HCO3-, HCO3 " is
best described as a hybrid of several contributing resonance forms, two of which
are shown here.
HO
:0:
HO
+
:Ö:
Bicarbonate is crucial for the control of body pH (for example, blood pH
7.4). A more self-indulgent use is in baking soda, where it serves as a
source of CO2 CO2 gas, which gives bread and pastry their fluffy
constituency.
(i) Draw at least one additional resonance form.
=
(ii) Using curved "electron-pushing" arrows, show how these Lewis structures may
be interconverted by movement of electron pairs. (iii) Determine which form or
forms will be the major contributor(s) to the real structure of bicarbonate,
explaining your answer on the basis of the criteria in Section 1-5.
Chapter 1 Solutions
Organic And Biological Chemistry
Ch. 1.1 - Prob. 1QQCh. 1.1 - Prob. 2QQCh. 1.2 - Which of the following statements about the...Ch. 1.2 - Prob. 2QQCh. 1.3 - Prob. 1QQCh. 1.3 - Prob. 2QQCh. 1.4 - Prob. 1QQCh. 1.4 - Prob. 2QQCh. 1.4 - Prob. 3QQCh. 1.5 - Prob. 1QQ
Ch. 1.5 - Prob. 2QQCh. 1.5 - Prob. 3QQCh. 1.6 - Prob. 1QQCh. 1.6 - Prob. 2QQCh. 1.6 - Prob. 3QQCh. 1.6 - Prob. 4QQCh. 1.7 - Prob. 1QQCh. 1.7 - Prob. 2QQCh. 1.8 - Prob. 1QQCh. 1.8 - Prob. 2QQCh. 1.8 - Prob. 3QQCh. 1.8 - Prob. 4QQCh. 1.8 - Prob. 5QQCh. 1.8 - Prob. 6QQCh. 1.8 - Prob. 7QQCh. 1.9 - Prob. 1QQCh. 1.9 - Prob. 2QQCh. 1.10 - Prob. 1QQCh. 1.10 - Prob. 2QQCh. 1.11 - Prob. 1QQCh. 1.11 - Prob. 2QQCh. 1.11 - Prob. 3QQCh. 1.12 - Prob. 1QQCh. 1.12 - Prob. 2QQCh. 1.12 - Prob. 3QQCh. 1.13 - Prob. 1QQCh. 1.13 - Prob. 2QQCh. 1.13 - Prob. 3QQCh. 1.14 - Prob. 1QQCh. 1.14 - Prob. 2QQCh. 1.14 - Prob. 3QQCh. 1.15 - Prob. 1QQCh. 1.15 - Prob. 2QQCh. 1.16 - Prob. 1QQCh. 1.16 - Prob. 2QQCh. 1.16 - Prob. 3QQCh. 1.17 - Prob. 1QQCh. 1.17 - Prob. 2QQCh. 1.17 - Prob. 3QQCh. 1.17 - Prob. 4QQCh. 1.18 - Prob. 1QQCh. 1.18 - Prob. 2QQCh. 1.18 - Prob. 3QQCh. 1.18 - Prob. 4QQCh. 1 - Prob. 1.1EPCh. 1 - Prob. 1.2EPCh. 1 - Prob. 1.3EPCh. 1 - Prob. 1.4EPCh. 1 - Indicate whether each of the following situations...Ch. 1 - Indicate whether each of the following situations...Ch. 1 - Prob. 1.7EPCh. 1 - Prob. 1.8EPCh. 1 - What is the difference between a saturated...Ch. 1 - What structural feature is present in an...Ch. 1 - Prob. 1.11EPCh. 1 - Prob. 1.12EPCh. 1 - Prob. 1.13EPCh. 1 - Prob. 1.14EPCh. 1 - Prob. 1.15EPCh. 1 - Prob. 1.16EPCh. 1 - Convert the expanded structural formulas in...Ch. 1 - Prob. 1.18EPCh. 1 - Prob. 1.19EPCh. 1 - Prob. 1.20EPCh. 1 - Prob. 1.21EPCh. 1 - Prob. 1.22EPCh. 1 - Prob. 1.23EPCh. 1 - Prob. 1.24EPCh. 1 - Prob. 1.25EPCh. 1 - Prob. 1.26EPCh. 1 - Indicate whether each of the following would be...Ch. 1 - Indicate whether each of the following would be...Ch. 1 - Prob. 1.29EPCh. 1 - Explain why two different straight-chain alkanes...Ch. 1 - With the help of Table 12-1, indicate how many...Ch. 1 - Prob. 1.32EPCh. 1 - How many of the numerous eight-carbon alkane...Ch. 1 - How many of the numerous seven-carbon alkane...Ch. 1 - For each of the following pairs of structures,...Ch. 1 - For each of the following pairs of structures,...Ch. 1 - Convert each of the following linear condensed...Ch. 1 - Prob. 1.38EPCh. 1 - Prob. 1.39EPCh. 1 - Prob. 1.40EPCh. 1 - Prob. 1.41EPCh. 1 - Prob. 1.42EPCh. 1 - Prob. 1.43EPCh. 1 - Prob. 1.44EPCh. 1 - Prob. 1.45EPCh. 1 - Prob. 1.46EPCh. 1 - Prob. 1.47EPCh. 1 - Prob. 1.48EPCh. 1 - Prob. 1.49EPCh. 1 - Prob. 1.50EPCh. 1 - Prob. 1.51EPCh. 1 - Prob. 1.52EPCh. 1 - Draw a condensed structural formula for each of...Ch. 1 - Draw a condensed structural formula for each of...Ch. 1 - Prob. 1.55EPCh. 1 - For each of the alkanes in Problem 12-54,...Ch. 1 - Explain why the name given for each of the...Ch. 1 - Prob. 1.58EPCh. 1 - Indicate whether or not the two alkanes in each of...Ch. 1 - Prob. 1.60EPCh. 1 - How many of the 18 C8 alkane constitutional...Ch. 1 - How many of the nine C7 alkane constitutional...Ch. 1 - Prob. 1.63EPCh. 1 - Prob. 1.64EPCh. 1 - Prob. 1.65EPCh. 1 - Prob. 1.66EPCh. 1 - Do the line-angle structural formulas in each of...Ch. 1 - Do the line-angle structural formulas in each of...Ch. 1 - Convert each of the condensed structural formulas...Ch. 1 - Convert each of the condensed structural formulas...Ch. 1 - Assign an IUPAC name to each of the compounds in...Ch. 1 - Prob. 1.72EPCh. 1 - Prob. 1.73EPCh. 1 - Prob. 1.74EPCh. 1 - For each of the alkane structures in Problem...Ch. 1 - For each of the alkane structures in Problem...Ch. 1 - Prob. 1.77EPCh. 1 - Prob. 1.78EPCh. 1 - Prob. 1.79EPCh. 1 - Prob. 1.80EPCh. 1 - Prob. 1.81EPCh. 1 - Prob. 1.82EPCh. 1 - Draw condensed structural formulas for the...Ch. 1 - Draw condensed structural formulas for the...Ch. 1 - To which carbon atoms in a hexane molecule can...Ch. 1 - Prob. 1.86EPCh. 1 - Prob. 1.87EPCh. 1 - Prob. 1.88EPCh. 1 - Give an acceptable alternate name for each of the...Ch. 1 - Prob. 1.90EPCh. 1 - Prob. 1.91EPCh. 1 - Prob. 1.92EPCh. 1 - Prob. 1.93EPCh. 1 - Prob. 1.94EPCh. 1 - What is the molecular formula for each of the...Ch. 1 - Prob. 1.96EPCh. 1 - Prob. 1.97EPCh. 1 - Prob. 1.98EPCh. 1 - Prob. 1.99EPCh. 1 - How many secondary carbon atoms are present in...Ch. 1 - Assign an IUPAC name to each of the following...Ch. 1 - Assign an IUPAC name to each of the following...Ch. 1 - Prob. 1.103EPCh. 1 - Prob. 1.104EPCh. 1 - Prob. 1.105EPCh. 1 - Prob. 1.106EPCh. 1 - What is the molecular formula for each of the...Ch. 1 - Prob. 1.108EPCh. 1 - Prob. 1.109EPCh. 1 - Prob. 1.110EPCh. 1 - Prob. 1.111EPCh. 1 - Prob. 1.112EPCh. 1 - Determine whether cistrans isomerism is possible...Ch. 1 - Prob. 1.114EPCh. 1 - Prob. 1.115EPCh. 1 - Prob. 1.116EPCh. 1 - Prob. 1.117EPCh. 1 - Indicate whether the members of each of the...Ch. 1 - Prob. 1.119EPCh. 1 - Prob. 1.120EPCh. 1 - Prob. 1.121EPCh. 1 - Prob. 1.122EPCh. 1 - Prob. 1.123EPCh. 1 - Which member in each of the following pairs of...Ch. 1 - Prob. 1.125EPCh. 1 - Prob. 1.126EPCh. 1 - Answer the following questions about the...Ch. 1 - Prob. 1.128EPCh. 1 - Prob. 1.129EPCh. 1 - Prob. 1.130EPCh. 1 - Write molecular formulas for all the possible...Ch. 1 - Write molecular formulas for all the possible...Ch. 1 - Prob. 1.133EPCh. 1 - Prob. 1.134EPCh. 1 - Prob. 1.135EPCh. 1 - Assign an IUPAC name to each of the following...Ch. 1 - Prob. 1.137EPCh. 1 - Prob. 1.138EPCh. 1 - Prob. 1.139EPCh. 1 - Prob. 1.140EPCh. 1 - Prob. 1.141EPCh. 1 - Prob. 1.142EPCh. 1 - Prob. 1.143EPCh. 1 - Prob. 1.144EPCh. 1 - Prob. 1.145EPCh. 1 - Prob. 1.146EPCh. 1 - Give the IUPAC names for the eight isomeric...Ch. 1 - Prob. 1.148EP
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