Concept explainers
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(a)
Interpretation:
The formula for chemical products that are obtained when the given alkane undergoes complete combustion has to be given.
Concept Introduction:
Alkanes are not completely inert. Two important reactions that alkanes undergo are combustion and halogenation.
Combustion reaction is the one where reaction occurs between substance and oxygen which proceeds with evolution of light and heat. The product obtained when an alkane undergoes combustion is carbon dioxide and water. Due to the heat produced when alkanes are made to undergo combustion with oxygen, it is used as fuel.
Halogenation is a
Halogenation reaction of alkane is an example of substitution reaction. This is a reaction where a part of reacting molecule replaces an atom or group of atoms in hydrocarbon or hydrocarbon derivative.
Cycloalkanes are also similar to those of alkanes. Cycloalkanes also undergo combustion and halogenation reaction.
(b)
Interpretation:
The formula for chemical products that are obtained when the given alkane undergoes complete combustion has to be given.
Concept Introduction:
Alkanes are linear chain saturated hydrocarbons. The reactivity of alkanes are very less. They can be heated for a very long time in strong acids and bases without any reaction. Even strong reducing and strong oxidizing agents have less effect on alkanes.
Alkanes are not completely inert. Two important reactions that alkanes undergo are combustion and halogenation.
Combustion reaction is the one where reaction occurs between substance and oxygen which proceeds with evolution of light and heat. The product obtained when an alkane undergoes combustion is carbon dioxide and water. Due to the heat produced when alkanes are made to undergo combustion with oxygen, it is used as fuel.
Halogenation is a chemical reaction between a substance and halogen. The product of halogenation reaction is that one or more halogens are incorporated into molecules of the substance. Halogenation of hydrocarbon gives hydrocarbon derivatives as product where halogen atoms are substituted instead of hydrogen atoms.
Halogenation reaction of alkane is an example of substitution reaction. This is a reaction where a part of reacting molecule replaces an atom or group of atoms in hydrocarbon or hydrocarbon derivative.
Cycloalkanes are also similar to those of alkanes. Cycloalkanes also undergo combustion and halogenation reaction.
(c)
Interpretation:
The formula for chemical products that are obtained when the given alkane undergoes complete combustion has to be given.
Concept Introduction:
Alkanes are linear chain saturated hydrocarbons. The reactivity of alkanes are very less. They can be heated for a very long time in strong acids and bases without any reaction. Even strong reducing and strong oxidizing agents have less effect on alkanes.
Alkanes are not completely inert. Two important reactions that alkanes undergo are combustion and halogenation.
Combustion reaction is the one where reaction occurs between substance and oxygen which proceeds with evolution of light and heat. The product obtained when an alkane undergoes combustion is carbon dioxide and water. Due to the heat produced when alkanes are made to undergo combustion with oxygen, it is used as fuel.
Halogenation is a chemical reaction between a substance and halogen. The product of halogenation reaction is that one or more halogens are incorporated into molecules of the substance. Halogenation of hydrocarbon gives hydrocarbon derivatives as product where halogen atoms are substituted instead of hydrogen atoms.
Halogenation reaction of alkane is an example of substitution reaction. This is a reaction where a part of reacting molecule replaces an atom or group of atoms in hydrocarbon or hydrocarbon derivative.
Cycloalkanes are also similar to those of alkanes. Cycloalkanes also undergo combustion and halogenation reaction.
(d)
Interpretation:
The formula for chemical products that are obtained when the given alkane undergoes complete combustion has to be given.
Concept Introduction:
Alkanes are linear chain saturated hydrocarbons. The reactivity of alkanes are very less. They can be heated for a very long time in strong acids and bases without any reaction. Even strong reducing and strong oxidizing agents have less effect on alkanes.
Alkanes are not completely inert. Two important reactions that alkanes undergo are combustion and halogenation.
Combustion reaction is the one where reaction occurs between substance and oxygen which proceeds with evolution of light and heat. The product obtained when an alkane undergoes combustion is carbon dioxide and water. Due to the heat produced when alkanes are made to undergo combustion with oxygen, it is used as fuel.
Halogenation is a chemical reaction between a substance and halogen. The product of halogenation reaction is that one or more halogens are incorporated into molecules of the substance. Halogenation of hydrocarbon gives hydrocarbon derivatives as product where halogen atoms are substituted instead of hydrogen atoms.
Halogenation reaction of alkane is an example of substitution reaction. This is a reaction where a part of reacting molecule replaces an atom or group of atoms in hydrocarbon or hydrocarbon derivative.
Cycloalkanes are also similar to those of alkanes. Cycloalkanes also undergo combustion and halogenation reaction.
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Chapter 1 Solutions
Organic And Biological Chemistry
- Alcohols are very useful starting materials for the production of many different compounds. The following conversions, starting with 1-butanol, can be carried out in two or more steps. Show the steps (reactants/catalysts) you would follow to carry out the conversions, drawing the formula for the organic product in each step. For each step, a major product must be produced. (See Exercise 62.) (Hint: In the presence of H+, an alcohol is converted into an alkene and water. This is the exact reverse of the reaction of adding water to an alkene to form an alcohol.) a. 1-butanol butane b. 1-butanol 2-butanonearrow_forwardHow does the structure of a cycloalkane differ from that of a straight-chain or branched-chain alkane?arrow_forwardList four common fuels used by our society, and draw structural formulas for the corresponding hydrocarbons that compose them.arrow_forward
- Is the general formula of a cycloalkanes the same as the general formula of an alkane, CnH2n+2? Draw any structural diagram to illustrate your answer.arrow_forward. With very reactive agents, such as the halogen elements, alkanes undergo reactions, whereby a new atom rep laces one or more hydrogen atoms of the alkane.arrow_forward4.2 What is an alkane?arrow_forward
- What property is characteristic of chlorinated hydrocarbons? a. chemical stability b. high flammability c. high chemical reactivityarrow_forwardSummarize the nomenclature rules for alkanes, alkenes, alkynes, and aromatic compounds. Correct the following false statements regarding nomenclature of hydrocarbons. a. The root name for a hydrocarbon is based on the shortest continuous chain of carbon atoms. b. The suffix used to name all hydrocarbons is -ane. c. Substituent groups are numbered so as to give the largest numbers possible. d. No number is required to indicate the positions of double or triple bonds in alkenes and alkynes. e. Substituent groups get the lowest number possible in alkenes and alkynes. f. The ortho- term in aromatic hydrocarbons indicates the presence of two substituent groups bonded to carbon- 1 and carbon-3 in benzene.arrow_forwardWhat is a hydrocarbon? What is the difference between a saturated hydrocarbon and an unsaturated hydrocarbon? Distinguish between normal and branched hydrocarbons. What is an alkane? What is a cyclic alkane? What are the two general formulas for alkanes? What is the hybridization of carbon atoms in alkanes? What are the bond angles in alkanes? Why are cyclopropane and cyclobutane so reactive? The normal (unbranched) hydrocarbons are often referred to as straight-chain hydrocarbons. What does this name refer to? Does it mean that the carbon atoms in a straight-chain hydrocarbon really have a linear arrangement? Explain. In the shorthand notation for cyclic alkanes, the hydrogens are usually omitted. How do you determine the number of hydrogens bonded to each carbon in a ring structure?arrow_forward
- What is meant by the term “unsaturated hydrocarbon”? What structural feature characterizes unsaturated hydrocarbons?arrow_forwardDistinguish between isomerism and resonance. Distinguish between structural and geometric isomerism. When writing the various structural isomers, the most difficult task is identifying which are different isomers and which are identical to a previously written structurethat is, which are compounds that differ only by the rotation of a carbon single bond. How do you distinguish between structural isomers and those that are identical? Alkenes and cycloalkanes are structural isomers of each other. Give an example of each using C4H8. Another common feature of alkenes and cycloalkanes is that both have restricted rotation about one or more bonds in the compound, so both can exhibit cis- trans isomerism. What is required for an alkene or cycloalkane to exhibit cis-trans isomerism? Explain the difference between cis and trans isomers. Alcohols and ethers are structural isomers of each other, as are aldehydes and ketones. Give an example of each to illustrate. Which functional group in Table 21-4 can be structural isomers of carboxylic acids? What is optical isomerism? What do you look for to determine whether an organic compound exhibits optical isomerism? 1-Bromo-1-chloroethane is optically active whereas 1-bromo-2-chloroethane is not optically active. Explain.arrow_forward
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