pls help asap 13. For each of the following iron-based objects, explain which strategy you think would be the most effectiveand cost efficient for reducing corrosion. Justify your explanation. If another metal is required, identifythe metal involved and explain how you would choose the right metal for the job.a. A large suspension bridgeb. A set of cutleryc. A luxury car that will be driven in winter conditions

Here's an analysis of the most effective and cost-efficient corrosion reduction strategies for the…

Answered: 13. For each of the following…

Chemistry: An Atoms First Approach

2nd Edition

ISBN:9781305079243

Author:Steven S. Zumdahl, Susan A. Zumdahl

Publisher:Steven S. Zumdahl, Susan A. Zumdahl

Chapter17: Electrochemistry

Section: Chapter Questions

Problem 122AE

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Electrochemical Cells II Consider this cell running under standard conditions: Ni(s)Ni2(aq)Cu+(aq)Cu(s) a Is this cell a voltaic or an electrolytic cell? How do you know? b Does current flow in this cell spontaneously? c What is the maximum cell potential for this cell? d Say the cell is connected to a voltmeter. Describe what you might see for an initial voltage and what voltage changes, if any, you would observe as time went by. e What is the free energy of this cell when it is first constructed? f Does the free energy of the cell change over time as the cell runs? If so, how does it change?
Using data from Table 18.1, place the following in order of increasing strength as reducing agents (all under standard conditions). Cu+,F,H,H2O,I2,K
A magnesium bar with a mass of 6.0 kg is attached to a buried iron pipe to serve as a sacrificial anode. An average current of 0.020 A flows between the bar and the pipe. (a) What reaction takes place at the surface of the magnesium bar? (b) What reaction takes place at the surface of the iron pipe? (C) In which direction do electrons flow between the two surfaces? (d) How many years would it take for the entire magnesium bar to be consumed?
Using values from the table of standard reduction potentials, calculate the cell potentials of the following cells. (a) Fe(s)|Fe2+(aq)Hg2+(aq)|Hg(l) (b) Pt(s)|Fe2+(aq),Fe3+(aq)MnO4(aq),H+(aq),Mn2+(aq)|Pt(s) (c) Pt(s)|Cl2(g)|Cl-(aq)Au+(aq)|Au(s)
An aqueous solution of an unknown salt of gold is electrolyzed by a current of 2.75 amps for 3.39 hours. The electroplating is carried out with an efficiency of 93.0%, resulting in a deposit of 21.221 g of gold. a How many faradays are required to deposit the gold? b What is the charge on the gold ions (based on your calculations)?
Gold is produced electrochemically from an aqueous solution of Au(CN)2 containing an excess of CN. Gold metal and oxygen gas are produced at the electrodes. What amount (moles) of O2 will be produced during the production of 1.00 mole of gold?
Aluminum (E Al 3+/Al=2.07V) is more easily oxidized than iron (E Fe 3+/Fe=2.07V), and yet when both are exposed to the environment, untreated aluminum has very good corrosion resistance while the corrosion resistance of untreated iron is poor. Explain this observation.
Determine the overall reaction and its standard cell potential at 25 C for these reactions. Is the reaction spontaneous at standard conditions? Assume the standard reduction for Br2(l) is the same as for Br2(aq).. Pt(s)|H2(g)|H+(aq)Br2(aq),Br(aq)|Pt(s)
The following two half-reactions arc involved in a voltaic cell. At standard conditions, what species is produced at each electrode? Ag++eAgE=0.80VNi2++2eNiE=0.25V
For the cell: Cr|Cr3+Co2+|Co E° is 0.46 V. The same cell was prepared in the laboratory at standard conditions. The voltage obtained was 0.40 V. A possible explanation for the difference is (a) the surface area of the chromium electrode was smaller than the cobalt electrode. (b) the mass of the chromium electrode was larger than the mass of the cobalt electrode. (c) the concentration of Cr(NO3)2 solution used was less than 1.0 M. (d) the concentration of Cr(NO3)2 solution used was less than 1.0 M. (e) the volume of Cr(NO3)2 solution used was larger than the volume of Cr(NO3)2 solution used.
Consider the following galvanic cell at 25C: Pt|Cr2+(0.30M),Cr3+(2.0M)||Co2+(0.20M)|Co The overall reaction and equilibrium constant value are 2Cr2+(aq)+Co2+(aq)2Cr3+(aq)+Co(s)K=2.79107 Calculate the cell potential, for this galvanic cell and G for the cell reaction at these conditions.
Substances A2, B2, and C2 can all act as oxidizing agents. In solution, A2 is green, B2 is yellow, and C2 is red. In the reactions in which they participate, they are reduced to A, B, and C ions, all of which are colorless. When a solution of C2 is mixed with one containing B ions, the color changes from red to yellow. Which species is oxidized? __________ Which is reduced? __________ When a solution of C2 is mixed with one containing A ions, the color remains red. Is C2 a better oxidizing agent than A2? __________ Is C2 a better oxidizing agent than B2? __________ Arrange A2, B2, and C2 in order of increasing strength as an oxidizing agent. ___________________ _______________ ______________ weakest oxidizing agentstrongest oxidizing agent

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