Principles of General Chemistry
3rd Edition
ISBN: 9780073402697
Author: SILBERBERG, Martin S.
Publisher: McGraw-Hill College
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Chapter 5, Problem 5.67P
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Does SF6 (boiling point = 16°C at 1 atm) behave more ideally at 1508C or at 208C? Explain.
Neon and HF have approximately the same molecular masses.(a) Explain why the boiling points of Neon and HF differ.(b) Compare the change in the boiling points of Ne, Ar, Kr, and Xe with the change of the boiling points of HF, HCl, HBr, and HI, and explain the difference between the changes with increasing atomic or molecular mass.
Neon and HF have approximately the same molecular mass.
(a) Explain why the boiling point of Neon and HF differ.
(b) Compare the change in the boiling points of Ne, Ar, Kr, and Xe with the change of the boiling points of HF, HCl, HBr, and HI, and explain the difference between the changes with increasing atomic or molecular mass.
Chapter 5 Solutions
Principles of General Chemistry
Ch. 5 - Prob. 5.1PCh. 5 - Prob. 5.2PCh. 5 - Prob. 5.3PCh. 5 - Prob. 5.4PCh. 5 - Prob. 5.5PCh. 5 - Prob. 5.6PCh. 5 - Prob. 5.7PCh. 5 - Prob. 5.8PCh. 5 - The gravitational force exerted by Earth on an...Ch. 5 - Prob. 5.10P
Ch. 5 - Prob. 5.11PCh. 5 - Prob. 5.12PCh. 5 - Each of the following processes caused the gas...Ch. 5 - What is the effect of the following on the volume...Ch. 5 - What is the effect of the following on the volume...Ch. 5 - Prob. 5.16PCh. 5 - Prob. 5.17PCh. 5 - Prob. 5.18PCh. 5 - Prob. 5.19PCh. 5 - Prob. 5.20PCh. 5 - If 1.4710-3mol of argon occupies a 75.0-mL...Ch. 5 - Prob. 5.22PCh. 5 - A 75.0-g sample of dinitrogen monoxide is confined...Ch. 5 - Prob. 5.24PCh. 5 - Prob. 5.25PCh. 5 - Prob. 5.26PCh. 5 - Prob. 5.27PCh. 5 - Prob. 5.28PCh. 5 - Prob. 5.29PCh. 5 - Prob. 5.30PCh. 5 - Prob. 5.31PCh. 5 - Prob. 5.32PCh. 5 - The density of a noble gas is 2.71g/L at 3.00 atm...Ch. 5 - Prob. 5.34PCh. 5 - When an evacuated 63.8-mL glass bulb is tilled...Ch. 5 - After 0.600 L of Ar at 1.20 atm and 227oC is mixed...Ch. 5 - A 355-mL container holds 0.146 g of Ne and an...Ch. 5 - How many grams of phosphorus react with 35.5 L of...Ch. 5 - Prob. 5.39PCh. 5 - Prob. 5.40PCh. 5 - Prob. 5.41PCh. 5 - Prob. 5.42PCh. 5 - How many liters of hydrogen gas are collected over...Ch. 5 - Prob. 5.44PCh. 5 - Prob. 5.45PCh. 5 - Prob. 5.46PCh. 5 - Prob. 5.47PCh. 5 - Prob. 5.48PCh. 5 - Prob. 5.49PCh. 5 - Prob. 5.50PCh. 5 - Prob. 5.51PCh. 5 - Prob. 5.52PCh. 5 - Prob. 5.53PCh. 5 - Prob. 5.54PCh. 5 - Prob. 5.55PCh. 5 - Prob. 5.56PCh. 5 - Prob. 5.57PCh. 5 - The graph below shows the distribution of...Ch. 5 - Prob. 5.59PCh. 5 - Prob. 5.60PCh. 5 - White phosphorus melts and then vaporizes at high...Ch. 5 - Helium (He) is the lightest noble gas component of...Ch. 5 - Prob. 5.63PCh. 5 - Prob. 5.64PCh. 5 - Prob. 5.65PCh. 5 - Prob. 5.66PCh. 5 - Does SF6(boilingpoint=16oCat1atm) behave more...Ch. 5 - Hemoglobin is the protein that transports O2...Ch. 5 - A baker uses sodium hydrogen carbonate (baking...Ch. 5 - Prob. 5.70PCh. 5 - Prob. 5.71PCh. 5 - Prob. 5.72PCh. 5 - Prob. 5.73PCh. 5 - Prob. 5.74PCh. 5 - Prob. 5.75PCh. 5 - Prob. 5.76PCh. 5 - Prob. 5.77PCh. 5 - Prob. 5.78PCh. 5 - Aluminum chloride is easily vaporized above 180C....Ch. 5 - An atmospheric chemist studying the pollutant SO2...Ch. 5 - The thermal decomposition of ethylene occurs...Ch. 5 - Prob. 5.82PCh. 5 - Analysis of a newly discovered gaseous...Ch. 5 - Prob. 5.84PCh. 5 - Prob. 5.85PCh. 5 - Containers A, B, and C are attached by closed...Ch. 5 - Prob. 5.87PCh. 5 - Prob. 5.88PCh. 5 - Prob. 5.89PCh. 5 - Prob. 5.90PCh. 5 - Prob. 5.91PCh. 5 - Prob. 5.92PCh. 5 - To study a key fuel-cell reaction, a chemical...Ch. 5 - Prob. 5.94PCh. 5 - Prob. 5.95PCh. 5 - Prob. 5.96PCh. 5 - Prob. 5.97PCh. 5 - Prob. 5.98PCh. 5 - Prob. 5.99PCh. 5 - In A, the picture shows a cylinder with 0.1 mol of...Ch. 5 - Prob. 5.101PCh. 5 - Prob. 5.102PCh. 5 - According to government standards, the 8h...Ch. 5 - One way to prevent emission of the pollutant NO...Ch. 5 - Prob. 5.105PCh. 5 - Prob. 5.106PCh. 5 - Prob. 5.107PCh. 5 - Prob. 5.108P
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- 5-106 The normal boiling point of hexane, C6H14, is 69°C, and that of pentane, C5H12, is 36°C. Predict which of these compounds has a higher vapor pressure at 20°C.arrow_forwardThe normal boiling point of SO2 is 263.1 K and that of NH3 is 239.7 K. At −40 °C, would you predict that ammonia has a vapor pressure greater than, less than, or equal to that of sulfur dioxide? Explain.arrow_forwardFor each of the following pairs, choose the member with the lower boiling point. Explain your reason in each case. (a) NaCl or PCl3 (b) NH3 or AsH3 (c) C3H7OH or C2H5OCH3 (d) HI(g) or HCl(g)arrow_forward
- Which would you expect to have the higher fusion enthalpy, N2 or I2? Explain your choice.arrow_forwardCarbon tetrachloride, CCl4, has a vapor pressure of 213 torr at 40.C and 836 torr at 80.C. What is the normal boiling point of CCl4?arrow_forward5-86 Using the phase diagram of water (Figure 5-20), describe the process by which you can sublime 1 g of ice at-10°C and at 1 atm pressure to water vapor at the same temperature.arrow_forward
- Chloroform, CHCl3, has a normal boiling point of 61C. Its vapor pressure at 43C is 0.526 atm. What is the concentration (in g/L) of CHCl3 when it saturates the air at 27C?arrow_forwardExplain why liquids assume the shape of any container into which they are poured, whereas solids are rigid and retain their shape.arrow_forwardHow many grams of water at 0C will be melted by the condensation of 1 g of steam at 100C?arrow_forward
- In each of the following groups of substances, pick the one that has the given property. Justify your answer. a. highest boiling point: HBr, Kr, or Cl2 b. highest freezing point: H2O, NaCl, or HF c. lowest vapor pressure at 25C: Cl2, Br2, or I2 d. lowest freezing point: N2, CO, or CO2 e. lowest boiling point: CH4, CH3CH3, or CH3CH2CH3 f. highest boiling point: HF, HCl, or HBr g.arrow_forwardWhy do the boiling points of the noble gases increase in the order HeNeArKrXe?arrow_forwardThe AHvap of xenon is 12.57 kJ · mol¬' and its ASvan is 76.15 J · mol¬1 . K-l. What it the boiling point of xenon? Th = °Carrow_forward
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