Principles of General Chemistry
3rd Edition
ISBN: 9780073402697
Author: SILBERBERG, Martin S.
Publisher: McGraw-Hill College
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Chapter 5, Problem 5.67P
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Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an
organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the
compound. Find the structure. Show complete solutions.
Predicted 1H NMR Spectrum
4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1
f1 (ppm)
Predicted 13C NMR Spectrum
100
f1 (ppm)
30
220 210 200 190 180
170
160 150 140 130 120
110
90
80
70
-26
60
50
40
46
30
20
115
10
1.0 0.9 0.8
0
-10
Q: Arrange BCC and Fec
metals, in sequence from the
Fable (Dr. R's slides) and
Calculate Volume and Density.
Aa
BCC
V
52 5
SFCC
None
Chapter 5 Solutions
Principles of General Chemistry
Ch. 5 - Prob. 5.1PCh. 5 - Prob. 5.2PCh. 5 - Prob. 5.3PCh. 5 - Prob. 5.4PCh. 5 - Prob. 5.5PCh. 5 - Prob. 5.6PCh. 5 - Prob. 5.7PCh. 5 - Prob. 5.8PCh. 5 - The gravitational force exerted by Earth on an...Ch. 5 - Prob. 5.10P
Ch. 5 - Prob. 5.11PCh. 5 - Prob. 5.12PCh. 5 - Each of the following processes caused the gas...Ch. 5 - What is the effect of the following on the volume...Ch. 5 - What is the effect of the following on the volume...Ch. 5 - Prob. 5.16PCh. 5 - Prob. 5.17PCh. 5 - Prob. 5.18PCh. 5 - Prob. 5.19PCh. 5 - Prob. 5.20PCh. 5 - If 1.4710-3mol of argon occupies a 75.0-mL...Ch. 5 - Prob. 5.22PCh. 5 - A 75.0-g sample of dinitrogen monoxide is confined...Ch. 5 - Prob. 5.24PCh. 5 - Prob. 5.25PCh. 5 - Prob. 5.26PCh. 5 - Prob. 5.27PCh. 5 - Prob. 5.28PCh. 5 - Prob. 5.29PCh. 5 - Prob. 5.30PCh. 5 - Prob. 5.31PCh. 5 - Prob. 5.32PCh. 5 - The density of a noble gas is 2.71g/L at 3.00 atm...Ch. 5 - Prob. 5.34PCh. 5 - When an evacuated 63.8-mL glass bulb is tilled...Ch. 5 - After 0.600 L of Ar at 1.20 atm and 227oC is mixed...Ch. 5 - A 355-mL container holds 0.146 g of Ne and an...Ch. 5 - How many grams of phosphorus react with 35.5 L of...Ch. 5 - Prob. 5.39PCh. 5 - Prob. 5.40PCh. 5 - Prob. 5.41PCh. 5 - Prob. 5.42PCh. 5 - How many liters of hydrogen gas are collected over...Ch. 5 - Prob. 5.44PCh. 5 - Prob. 5.45PCh. 5 - Prob. 5.46PCh. 5 - Prob. 5.47PCh. 5 - Prob. 5.48PCh. 5 - Prob. 5.49PCh. 5 - Prob. 5.50PCh. 5 - Prob. 5.51PCh. 5 - Prob. 5.52PCh. 5 - Prob. 5.53PCh. 5 - Prob. 5.54PCh. 5 - Prob. 5.55PCh. 5 - Prob. 5.56PCh. 5 - Prob. 5.57PCh. 5 - The graph below shows the distribution of...Ch. 5 - Prob. 5.59PCh. 5 - Prob. 5.60PCh. 5 - White phosphorus melts and then vaporizes at high...Ch. 5 - Helium (He) is the lightest noble gas component of...Ch. 5 - Prob. 5.63PCh. 5 - Prob. 5.64PCh. 5 - Prob. 5.65PCh. 5 - Prob. 5.66PCh. 5 - Does SF6(boilingpoint=16oCat1atm) behave more...Ch. 5 - Hemoglobin is the protein that transports O2...Ch. 5 - A baker uses sodium hydrogen carbonate (baking...Ch. 5 - Prob. 5.70PCh. 5 - Prob. 5.71PCh. 5 - Prob. 5.72PCh. 5 - Prob. 5.73PCh. 5 - Prob. 5.74PCh. 5 - Prob. 5.75PCh. 5 - Prob. 5.76PCh. 5 - Prob. 5.77PCh. 5 - Prob. 5.78PCh. 5 - Aluminum chloride is easily vaporized above 180C....Ch. 5 - An atmospheric chemist studying the pollutant SO2...Ch. 5 - The thermal decomposition of ethylene occurs...Ch. 5 - Prob. 5.82PCh. 5 - Analysis of a newly discovered gaseous...Ch. 5 - Prob. 5.84PCh. 5 - Prob. 5.85PCh. 5 - Containers A, B, and C are attached by closed...Ch. 5 - Prob. 5.87PCh. 5 - Prob. 5.88PCh. 5 - Prob. 5.89PCh. 5 - Prob. 5.90PCh. 5 - Prob. 5.91PCh. 5 - Prob. 5.92PCh. 5 - To study a key fuel-cell reaction, a chemical...Ch. 5 - Prob. 5.94PCh. 5 - Prob. 5.95PCh. 5 - Prob. 5.96PCh. 5 - Prob. 5.97PCh. 5 - Prob. 5.98PCh. 5 - Prob. 5.99PCh. 5 - In A, the picture shows a cylinder with 0.1 mol of...Ch. 5 - Prob. 5.101PCh. 5 - Prob. 5.102PCh. 5 - According to government standards, the 8h...Ch. 5 - One way to prevent emission of the pollutant NO...Ch. 5 - Prob. 5.105PCh. 5 - Prob. 5.106PCh. 5 - Prob. 5.107PCh. 5 - Prob. 5.108P
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- The emission data in cps displayed in Table 1 is reported to two decimal places by the chemist. However, the instrument output is shown in Table 2. Table 2. Iron emission from ICP-AES Sample Blank Standard Emission, cps 579.503252562 9308340.13122 Unknown Sample 343.232365741 Did the chemist make the correct choice in how they choose to display the data up in Table 1? Choose the best explanation from the choices below. No. Since the instrument calculates 12 digits for all values, they should all be kept and not truncated. Doing so would eliminate significant information. No. Since the instrument calculates 5 decimal places for the standard, all of the values should be limited to the same number. The other decimal places are not significant for the blank and unknown sample. Yes. The way Saman made the standards was limited by the 250-mL volumetric flask. This glassware can report values to 2 decimal places, and this establishes our number of significant figures. Yes. Instrumental data…arrow_forwardSteps and explanation pleasearrow_forwardSteps and explanation to undertand concepts.arrow_forward
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