Macmillan Learning Draw the acyl chloride that would give the ketone shown using the Friedel-Crafts acylation reaction. Select Draw Templates More с H о Cl 2Q Erase AICI₂
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- Among the choices shown, which reagents would lead to 3-pentanone from bromoethane? Al 1 Li Cul 2) C13CH2OTS | BI1 NECNn DMSO 2) CH3CH2M;Br 3)H2O C)CH13CH2-CO CI D CH3CH2-CO OCH2CI13Provide the Major product for the following reactionsThe key step in a reported laboratory synthesis of sativene, a hydrocarbon isolated from the mold Helminthosporium sativum, involves the following base treatment of a keto tosylate. What kind of reaction is occurring? How would you complete the synthesis?
- Draw the products for the following substitution reactions:Provide the reagents necessary to affect each transformationent Review: Which of the following contribute to the favorablilty of the following eliminatio CH₂00 000 TH Ph H CH₂OH + H + CIⓇ The pi bond formed in the product is more stable than the sigma bond broken in the reactant The unstable charge on the base lowers the activation energy of the reaction. Formation of three products from two reactants is entropically favorable The charge formed on the leaving group is more stable than the charge on the base.
- The ketone whose 1H NMR spectrum is shown here was obtained as the product of an acetoacetic ester synthesis. What alkyl halide was used in the synthesis?Draw the major product formed from the following elimination reactions.H₂C 0 NH₂ B₂, NaOH 98 H₂C OH When an a-hydroxy amide is treated with try in aqueous NaOH under Hofmann rearrangement conditions, loss of CO, occurs and a chain-shortened aldehyde is formed. The mechanhum involves the following steps: Base abstracts an acidic amide proton, yielding amide anion The amide anion reacts with bromine in an e-substitution reaction to give N-bromoamide 2. Abstraction of the remaining amide proton by base gives a resonance-stabilized bromoamide anion Rearangement occurs to yield isocyanate Water adds to the isocyanate to yield carbamic acid Elimination of CD, yields carbinolamine Following proton transfer, expubion of ammonia yields the final product aldehyde Write out the mechanism on a separate sheet of paper, and then draw the structures of carbamic acid 5 and isocyanate 4. H 400, ANH, You do not have to consider stereochemistry. You do not have to explicitly draw Hatoms De not include lone pairs in your answer. They will not be considered in the grading…
- 3A Complete the reactions below. H₂SO4/H₂O HgSO4 A NaBH4 EtOH B лH₂SO4 CPropose a synthesis of the topical anesthetic cyclomethycaine from 4-hydroxybenzoic acid, 2-methylpiperidine, and any other necessary reagents. HN' + HO. НО Cyclomethycaine 4-Hydroxybenzoic acid 2-MethylpiperidineFor the following Claisen reactions, draw the correct organic products. NaOEt, EtOH A OEt NaOEt, E1OH OEt NaOEt, EtOH E OEt OEt G OEt- NaOEt, E1OH OEt OEt NaOEt, ELOHI