Macmillan Learning Draw the acyl chloride that would give the ketone shown using the Friedel-Crafts acylation reaction. Select Draw Templates More с H о Cl 2Q Erase AICI₂
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- Among the choices shown, which reagents would lead to 3-pentanone from bromoethane? Al 1 Li Cul 2) C13CH2OTS | BI1 NECNn DMSO 2) CH3CH2M;Br 3)H2O C)CH13CH2-CO CI D CH3CH2-CO OCH2CI13The key step in a reported laboratory synthesis of sativene, a hydrocarbon isolated from the mold Helminthosporium sativum, involves the following base treatment of a keto tosylate. What kind of reaction is occurring? How would you complete the synthesis?Draw the products for the following substitution reactions:
- If benzamide (PhCONH₂) undergoes a Hofmann rearrangement, what is the major product? O acetophenone O aniline O benzyl azide O cyclohexylamine benzylamineWhich of the following structures and IUPAC names are incorrectly matched? * oe (A) Methyleyclohexanoate (В) `NH2 Br 4-Bromo-3-chlorohexanamide 2-Ethoxypentane (D) HOOC HOOC 3,5-Nonanedioic acid В A DQ2 what is the enamine that will be formed from the below N O H₂O*
- Draw mechanism using pyradine as a base in the intial step Draw the mechanism using pydradine as a general base Draw the mechanism using pyradine as a nucleophilic catalyst Draw the mechanism using nucleophilic catalysis and using acetate as a general base H3C ROH ་ ་ CH3 N H3C -RWhich reagents will give the following synthesis reaction?Orsellinic acid, a common constituent of lichens, is synthesized from the condensation of acetyl thioester and malonyl thioester. If a lichen is grown on a medium containing acetate that was radioactively labeled with 14C at the carbonyl carbon, which carbons will be labeled in orsellinic acid?
- Ketoprofen, like ibuprofen, is an anti-inflammatory analgesic. How can ketoprofen be synthesized from the given starting material?One step in the synthesis of periplanone B, the chapter-opening molecule, involved anionic oxy-Cope rearrangement of the following unsaturated alcohol. Draw the product that results after protonation of the intermediate enolate.Propose a synthesis of the topical anesthetic cyclomethycaine from 4-hydroxybenzoic acid, 2-methylpiperidine, and any other necessary reagents. HN' + HO. НО Cyclomethycaine 4-Hydroxybenzoic acid 2-Methylpiperidine