Rank the compounds in each group below according to their reactivity toward electrophilic aromaticsubstitution (most reactive = 1; least reactive = 3). Place the number corresponding to the compounds'relative reactivity in the blank below the compound.a.CH₂FCH3Fb. At what position, and on what ring, is bromination of phenyl benzoate expected to occur? Explainyour answer.:0:C-Ophenyl benzoate6.Consider the reaction below to answer the following questions.ABCNO₂FeBr3+Br₂Da.The nucleophile in the reaction is:BODADESb. The Lewis acid catalyst in the reaction is:C.This reaction proceedsd. Draw the structure of product D.(faster or slower) than benzene.

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Answered: Rank the compounds in each group below…

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Identify products A and B from the given 1H NMR data.a. Treatment of CH2 = CHCOCH3 with one equivalent of HCl forms compound A. A exhibits the following absorptions in its 1H NMR spectrum: 2.2 (singlet, 3 H), 3.05 (triplet, 2 H), and 3.6 (triplet, 2 H) ppm. What is the structure of A?b. Treatment of acetone [(CH3)2C = O] with dilute aqueous base forms B. Compound B exhibits four singlets in its 1H NMR spectrum at 1.3 (6 H), 2.2 (3 H), 2.5 (2 H), and 3.8 (1 H) ppm. What is the structure of B?
Arrange these compounds in order of reactivity towards electrophilic aromaticsubstitution, with the most reactive compound listed first
Rank the following species from best nucleophile to poorest nucleophile in the given solvent: но. но, A B D Nucleophilic strength in butanol: > > Best Poorest A B C|D
Rank the compounds in each group below according to their reactivity toward electrophilie aromatic substitution (most reactive-1: least reactive 3) Place the number corresponding to the compounds' relative reactivity in the blank below the compound CH3 32. a- 1 2 3 b- 31 2 c- 132 d- 21 3 NHCCH3 соснз 33. d- 3 1 2 c-13 2 a- 123 b-213
Recognising how resonance contribtutes to the arrangement of charge around a ring helps to understand the reactivity of a substituted benzene. Consider the resonance contributors of ethoxybenzene 8-1 8-5-5 e According to resonance, is the ring: activated or deactivated to electrophilic substitution. And which site/s are the most susceptible to substitution? O a. deactivated - meta postions are most active O b. Deactivated - ortho and para positions are most active O c. Activated - ortho and para positions are most active O d. Activated - meta positions are most active
Galantamine, a natural product produced by the amaryllis family of flowering plants, has been used in the early treatment of Alzheimer's disease. In a synthesis of galantamine and related compounds (J. Org. Chem. 2015, 80, 1952-1956), compound 1 was converted into compound 2. Propose an efficient synthesis for the conversion of 1 to 2 A. NaOH MeO D. DMP or PCC G. HBr MeO B. H₂SO4, H₂O, HgSO4 E. Na2Cr₂O7, H₂SO4, H₂O H. 1) O3; 2) DMS H 2 The conversion of 1 to 2 can be performed with some reagent or combination of the reagents listed below. Give the necessary reagents in the correct order for each transformation, as a string of letters (without spaces or punctuation, such as "EBF"). If there is more than one correct solution, provide just one answer. C. 1) BH3-THF; 2) H₂O2, NaOH F.HBr, ROOR I. TsCl, py Meo I₁, N Me Galanthamine OH
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Galantamine, a natural product produced by the amaryllis family of flowering plants, has been used in the early treatment of Alzheimer's disease. In a synthesis of galantamine and related compounds (J. Org. Chem. 2015, 80, 1952-1956), compound 1 was converted into compound 2. Propose an efficient synthesis for the conversion of 1 to 2 A. NaOH MeO D. DMP or PCC G. HBr 1 MeO B. H₂SO4, H₂O, HgSO4 E. Na₂Cr₂O7, H₂SO4, H₂O H. 1) O3; 2) DMS H 2 x I. TsCl, py The conversion of 1 to 2 can be performed with some reagent or combination of the reagents listed below. Give the necessary reagents in the correct order for each transformation, as a string of letters (without spaces or punctuation, such as "EBF"). If there is more than one correct solution, provide just one answer. C. 1) BH3-THF; 2) H₂O2, NaOH F.HBr, ROOR = MeO Ill. N Me Galanthamine OH
Topic: Reactions of aromatic compoundsDraw a stepwise mechanism for the following reactions
In each reaction box, place the best reagent and conditions from the list below.
Rank the following carbonyl compounds in order of increasing reactivity in nucleophilic substitution reactions Please explain
II. Rank the following compounds in order of increasing reactivity toward nucleophilic acyl substitution or with CH3MgBr (pattern is the same with either one). A Least reactive B C CI D CH3 most reactive

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