Principles of General Chemistry
3rd Edition
ISBN: 9780073402697
Author: SILBERBERG, Martin S.
Publisher: McGraw-Hill College
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Question
Chapter 5, Problem 5.1P
(a)
Interpretation Introduction
Interpretation:
The difference between sample of gas and sample of liquid should be determined when the sample is transferred from one small container to a larger one.
Concept Introduction:
The characteristics of gases and liquids are:
- Liquid has definite volume but indefinite shape whereas the gas has indefinite volume and shape.
- Liquid has more density in comparison to gas but less than solid.
- Liquid has small compressibility in comparison to gas but larger than solid.
- Liquid has small thermal expansion in comparison to gas (moderate) but larger than solid.
(a)
Expert Solution
Answer to Problem 5.1P
The volume of gas increases whereas the volume of liquid will not change when the gas is transferred from one small container to large container.
Explanation of Solution
The volume of gas changed with pressure whereas the volume of liquid is not changed with the pressure. When the gas is transferred from one small container to large container then the pressure decreases and the volume of the gas increases whereas there is no effect in the volume of liquid.
(b)
Interpretation Introduction
Interpretation:
The difference between sample of gas and sample of liquid should be determined when the sample is heated in an expandable container, but there is no change of state takes place.
Concept Introduction:
The characteristics of gases and liquids are:
- Liquid has definite volume but indefinite shape whereas the gas has indefinite volume and shape.
- Liquid has more density in comparison to gas but less than solid.
- Liquid has small compressibility in comparison to gas but larger than solid.
- Liquid has small thermal expansion in comparison to gas (moderate) but larger than solid.
(b)
Expert Solution
Answer to Problem 5.1P
The volume of gas increases whereas the volume of liquid will not change when the gas is heated in an expandable container but no change in state takes place.
Explanation of Solution
When a gas is heated, its volume will increases 50 to 100 times greater than the liquid at constant pressure. Therefore, when the gas is heated in an expandable container,the volume of the gas increases whereas the volume will not change significantly.
(c)
Interpretation Introduction
Interpretation:
The difference between sample of gas and sample of liquid should be determined when the sample is placed in a cylinder having piston, and force is applied externally.
Concept Introduction:
The characteristics of gases and liquids are:
- Liquid has definite volume but indefinite shape whereas the gas has indefinite volume and shape.
- Liquid has more density in comparison to gas but less than solid.
- Liquid has small compressibility in comparison to gas but larger than solid.
- Liquid has small thermal expansion in comparison to gas (moderate) but larger than solid.
(c)
Expert Solution
Answer to Problem 5.1P
The volume of gas increases whereas the volume of liquid will not change when the sample is placed in a cylinder having piston, and force is applied externally.
Explanation of Solution
The volume of gas changed with pressure whereas the volume of liquid is not changed with the pressure. When the gas is placed in a cylinder having piston and the force is applied externally then the pressure increases and the volume of the gas decrease whereas there is no effect in the volume of liquid.
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Chapter 5 Solutions
Principles of General Chemistry
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