Principles of General Chemistry
3rd Edition
ISBN: 9780073402697
Author: SILBERBERG, Martin S.
Publisher: McGraw-Hill College
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Textbook Question
Chapter 5, Problem 5.23P
A 75.0-g sample of dinitrogen monoxide is confined in a 3.1-L vessel. What is the pressure (in atm) at 115°C?
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NMR spectrum of ethyl acetate has signals whose chemical shifts are indicated below. Which hydrogen or set of hydrogens corresponds to the signal at
4.1 ppm? Select the single best answer.
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ethyl acetate
H NMR: 1.3 ppm, 2.0 ppm, 4.1 ppm
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How many signals do you expect in the H NMR spectrum for this molecule?
Br Br
Write the answer below.
Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H
atoms that would contribute to the same signal as the H already highlighted red
Note for advanced students: In this question, any multiplet is counted as one signal.
1
Number of signals in the 'H NMR spectrum.
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to
the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
Check
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute
to the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
O
✓
No additional Hs to color in top
molecule
ง
No additional Hs to color in bottom…
in the kinetics experiment, what were the values calculated? Select all that apply.a) equilibrium constantb) pHc) order of reactiond) rate contstant
Chapter 5 Solutions
Principles of General Chemistry
Ch. 5 - Prob. 5.1PCh. 5 - Prob. 5.2PCh. 5 - Prob. 5.3PCh. 5 - Prob. 5.4PCh. 5 - Prob. 5.5PCh. 5 - Prob. 5.6PCh. 5 - Prob. 5.7PCh. 5 - Prob. 5.8PCh. 5 - The gravitational force exerted by Earth on an...Ch. 5 - Prob. 5.10P
Ch. 5 - Prob. 5.11PCh. 5 - Prob. 5.12PCh. 5 - Each of the following processes caused the gas...Ch. 5 - What is the effect of the following on the volume...Ch. 5 - What is the effect of the following on the volume...Ch. 5 - Prob. 5.16PCh. 5 - Prob. 5.17PCh. 5 - Prob. 5.18PCh. 5 - Prob. 5.19PCh. 5 - Prob. 5.20PCh. 5 - If 1.4710-3mol of argon occupies a 75.0-mL...Ch. 5 - Prob. 5.22PCh. 5 - A 75.0-g sample of dinitrogen monoxide is confined...Ch. 5 - Prob. 5.24PCh. 5 - Prob. 5.25PCh. 5 - Prob. 5.26PCh. 5 - Prob. 5.27PCh. 5 - Prob. 5.28PCh. 5 - Prob. 5.29PCh. 5 - Prob. 5.30PCh. 5 - Prob. 5.31PCh. 5 - Prob. 5.32PCh. 5 - The density of a noble gas is 2.71g/L at 3.00 atm...Ch. 5 - Prob. 5.34PCh. 5 - When an evacuated 63.8-mL glass bulb is tilled...Ch. 5 - After 0.600 L of Ar at 1.20 atm and 227oC is mixed...Ch. 5 - A 355-mL container holds 0.146 g of Ne and an...Ch. 5 - How many grams of phosphorus react with 35.5 L of...Ch. 5 - Prob. 5.39PCh. 5 - Prob. 5.40PCh. 5 - Prob. 5.41PCh. 5 - Prob. 5.42PCh. 5 - How many liters of hydrogen gas are collected over...Ch. 5 - Prob. 5.44PCh. 5 - Prob. 5.45PCh. 5 - Prob. 5.46PCh. 5 - Prob. 5.47PCh. 5 - Prob. 5.48PCh. 5 - Prob. 5.49PCh. 5 - Prob. 5.50PCh. 5 - Prob. 5.51PCh. 5 - Prob. 5.52PCh. 5 - Prob. 5.53PCh. 5 - Prob. 5.54PCh. 5 - Prob. 5.55PCh. 5 - Prob. 5.56PCh. 5 - Prob. 5.57PCh. 5 - The graph below shows the distribution of...Ch. 5 - Prob. 5.59PCh. 5 - Prob. 5.60PCh. 5 - White phosphorus melts and then vaporizes at high...Ch. 5 - Helium (He) is the lightest noble gas component of...Ch. 5 - Prob. 5.63PCh. 5 - Prob. 5.64PCh. 5 - Prob. 5.65PCh. 5 - Prob. 5.66PCh. 5 - Does SF6(boilingpoint=16oCat1atm) behave more...Ch. 5 - Hemoglobin is the protein that transports O2...Ch. 5 - A baker uses sodium hydrogen carbonate (baking...Ch. 5 - Prob. 5.70PCh. 5 - Prob. 5.71PCh. 5 - Prob. 5.72PCh. 5 - Prob. 5.73PCh. 5 - Prob. 5.74PCh. 5 - Prob. 5.75PCh. 5 - Prob. 5.76PCh. 5 - Prob. 5.77PCh. 5 - Prob. 5.78PCh. 5 - Aluminum chloride is easily vaporized above 180C....Ch. 5 - An atmospheric chemist studying the pollutant SO2...Ch. 5 - The thermal decomposition of ethylene occurs...Ch. 5 - Prob. 5.82PCh. 5 - Analysis of a newly discovered gaseous...Ch. 5 - Prob. 5.84PCh. 5 - Prob. 5.85PCh. 5 - Containers A, B, and C are attached by closed...Ch. 5 - Prob. 5.87PCh. 5 - Prob. 5.88PCh. 5 - Prob. 5.89PCh. 5 - Prob. 5.90PCh. 5 - Prob. 5.91PCh. 5 - Prob. 5.92PCh. 5 - To study a key fuel-cell reaction, a chemical...Ch. 5 - Prob. 5.94PCh. 5 - Prob. 5.95PCh. 5 - Prob. 5.96PCh. 5 - Prob. 5.97PCh. 5 - Prob. 5.98PCh. 5 - Prob. 5.99PCh. 5 - In A, the picture shows a cylinder with 0.1 mol of...Ch. 5 - Prob. 5.101PCh. 5 - Prob. 5.102PCh. 5 - According to government standards, the 8h...Ch. 5 - One way to prevent emission of the pollutant NO...Ch. 5 - Prob. 5.105PCh. 5 - Prob. 5.106PCh. 5 - Prob. 5.107PCh. 5 - Prob. 5.108P
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- true or false, given that a 20.00 mL sample of NaOH took 24.15 mL of 0.141 M HCI to reach the endpoint in a titration, the concentration of the NaOH is 1.17 M.arrow_forwardin the bromothymol blue experiment, pKa was measured. A closely related compound has a Ka of 2.10 x 10-5. What is the pKa?a) 7.1b) 4.7c) 2.0arrow_forwardcalculate the equilibrium concentration of H2 given that K= 0.017 at a constant temperature for this reaction. The inital concentration of HBr is 0.050 M.2HBr(g) ↔ H2(g) + Br2(g)a) 4.48 x 10-2 M b) 5.17 x 10-3 Mc) 1.03 x 10-2 Md) 1.70 x 10-2 Marrow_forward
- true or falsegiven these two equilibria with their equilibrium constants:H2(g) + CI2(l) ↔ 2HCI(g) K= 0.006 CI2(l) ↔ CI2(g) K= 0.30The equilibrium contstant for the following reaction is 1.8H2(g) + CI2 ↔ 2HCI(g)arrow_forwardI2(g) + CI2(g) ↔ 2ICIK for this reaction is 81.9. Find the equilibrium concentration of I2 if the inital concentration of I2 and CI2 are 0.010 Marrow_forwardtrue or false,the equilibrium constant for this reaction is 0.50.PCI5(g) ↔ PCI3(g) + CI2(g)Based on the above, the equilibrium constant for the following reaction is 0.25.2PCI5(g) ↔. 2PCI3(g) + 2CI2(g)arrow_forward
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