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(a)
Interpretation: To draw the structural formula for oxaloacetic acid.
Concept introduction: There are a number of
Polyfunctional carboxylate ions act as a substrate in the metabolic pathways and can be divided into two parts depending upon the parent
Oxaloacetic acid is an unsaturated derivative of succinic acid. The structure of succinic acid is:
(b)
Interpretation: To draw the structural formula for oxaloacetate ion.
Concept introduction: There are a number of metabolic reaction that occur in the human body for completion of functions. During these metabolic reactions, the various metabolic intermediates are formed for the short time to complete the reactions. Polyfunctional carboxylate ions are also the metabolic intermediate formed during metabolic pathways.
Polyfunctional carboxylate ions act as a substrate in the metabolic pathways and can be divided into two parts depending upon the parent carboxylic acid. The first class consists of malate, oxaloacetate and fumarate ion which are derivative of succinic acid.
(c)
Interpretation: To draw the structural formula for citric acid.
Concept introduction: There are a number of metabolic reaction that occur in the human body for completion of functions. During these metabolic reactions, the various metabolic intermediates are formed for the short time to complete the reactions. Polyfunctional carboxylate ions are also the metabolic intermediate formed during metabolic pathways.
Polyfunctional carboxylate ions act as a substrate in the metabolic pathways and can be divided into two parts depending upon the parent carboxylic acid. The second class consists of
Citric acid is an unsaturated derivative of glutaric acid. The structure of glutaric acid is:
(d)
Interpretation: To draw the structural formula for citrate ion.
Concept introduction: There are a number of metabolic reaction that occur in the human body for completion of functions. During these metabolic reactions, the various metabolic intermediates are formed for the short time to complete the reactions. Polyfunctional carboxylate ions are also the metabolic intermediate formed during metabolic pathways.
Polyfunctional carboxylate ions act as a substrate in the metabolic pathways and can be divided into two parts depending upon the parent carboxylic acid. The second class consists of
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Chapter 23 Solutions
General, Organic, and Biological Chemistry
- Complete the following esterification reaction by drawing the structural formula of the product formed. HOH HO i catalyst catalyst OH HO (product has rum flavor) (product has orange flavor)arrow_forwardThe statements in the tables below are about two different chemical equilibria. The symbols have their usual meaning, for example AG stands for the standard Gibbs free energy of reaction and K stands for the equilibrium constant. In each table, there may be one statement that is faise because it contradicts the other three statements. If you find a false statement, check the box next to t Otherwise, check the "no false statements" box under the table. statement false? AG"1 no false statements: statement false? AG-0 0 InK-0 0 K-1 0 AH-TAS no false statements 2arrow_forwardComplete the following esterification reactions by drawing the line formulas of the carboxylic acid and alcohol required to form the ester shown. catalyst catalyst catalyst apricot fragrancearrow_forward
- Show the saponification products of the following ester: You don't need to draw in the Na+ cation. catalyst, A catalyst, A catalyst, Aarrow_forwardWhat would happen if the carboxylic acid and alcohol groups were on the same molecule? In essence, the molecule reacts with itself. Draw the structure of the products formed in this manner using the reactants below. If two functional groups interact with one another on the same molecule, this is called an “intramolecular" (within one) rather than "intermolecular" (between two or more) attack. OH OH catalyst OH HO catalyst catalyst HO OHarrow_forwardQ3: Write in the starting alkyl bromide used to form the following products. Include any reactants, reagents, and solvents over the reaction arrow. If more than one step is required, denote separate steps by using 1), 2), 3), etc. H OH racemic OH OH 5 racemicarrow_forward
- Draw the Lewis structure of the SO3-O(CH3)2 complex shown in the bottom right of slide 2in lecture 3-3 (“Me” means a CH3 group) – include all valence electron pairs and formal charges.From this structure, should the complex be a stable molecule? Explain.arrow_forwardPredict all organic product(s), including stereoisomers when applicable.arrow_forwardQ5: Propose a reasonable synthesis for the following decalin derivative. using only decalin and alkanes of 3 or fewer carbons. Decalin H3C HO க CH3arrow_forward
- 2Helparrow_forwardplease add appropriate arrows, and tell me clearly where to add arrows, or draw itarrow_forwardWhat I Have Learned Directions: Given the following reaction and the stress applied in each reaction, answer the question below. A. H2(g) + Cl2(g) 2 HCl(g) Stress applied: Decreasing the pressure 1. What is the Keq expression? 2. What will be the effect in the number of moles of HCl(g)? 3. What will be the Equilibrium Shift or the reaction? B. Fe3O4(s) + 4 H2(g) + heat 53 Fe(s) + 4 H₂O(g) Stress applied: Increasing the temperature 1. What is the Keq expression?. 2. What will be the effect in the volume of water vapor collected? 3. What will be the Equilibrium Shift or the reaction? C. 4 NH3(g) + 5 O2(g) 4 NO(g) + 6 H2O(g) + heat Stress applied: Increasing the volume of the container 1. What is the Keq expression?. 2. What will be the effect in the amount of H₂O? 3. What will be the Equilibrium Shift or the reaction?arrow_forward
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