General, Organic, and Biological Chemistry
7th Edition
ISBN: 9781285853918
Author: H. Stephen Stoker
Publisher: Cengage Learning
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Textbook Question
Chapter 23.8, Problem 4QQ
The number of fixed enzyme sites in the electron transport chain is
- a. three
- b. four
- c. five
- d. no correct response
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Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below.
Find the following:
(a) The no. of protons corresponding to each signal in the spectra
(6) Give the structure of the compound and assign the signals to each
proton in the compound.
a
70.2
Integration Values
C5H10O2
b
47.7
C
46.5
d
69.5
3.6 3.5
3.4 3.3 3.2 3.1 3.0
2.9 2.8
2.7
2.6 2.5
2.4 2.3 2.2 2.1 2.0
Chemical Shift (ppm)
1.9
1.8
1.7 1.6
1.5
1.4 1.3 1.2
1.1 1.0
0.9 0.8
Part 111. 1 H-NMR spectrum of a compound with integration values in red is given below.
Answer the following:
(a) write the signals in the 'H-NMR spectrum to the corresponding protons on the structure
of the molecule below.
(b) Identify the theoretical multiplicities for each proton in the compound. Also give the possible.
complex splitting patterns assuming J values are not similar.
там
Br
22
2
3
6
4 7.2 7.0 6.8 6.6 6.4 6.2 6.0 5.8 5.6 5.4 5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 3.4 3.2 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0
Chemical Shift (ppm)
ra.
Br
2
3
6
6
2.5
2.4
2.3
2.2
2.1
2.0
1.9
1.8
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1.0
0.9
0.8
Chemical Shift (ppm)
2
2
Br
7.3
7.2
7.1
7.0 6.9
6.7 6.6 6.5
6.4
6.3
6.2
6.1
6.0
Chemical Shift (ppm)
5.9
5.8 5.7
5.5 5.4 5.3 5.2
5.0 4.9
1600°
1538°C
1493°C
In the diagram, the letter L indicates
that it is a liquid. Indicate its
components in the upper region
where only L is indicated.
The
iron-iron carbide phase
diagram.
Temperature (°C)
1400
8
1394°C
y+L
1200
2.14
y, Austenite
10000
912°C
800a
0.76
0.022
600
400
(Fe)
a, Ferrite
Composition (at% C)
15
1147°C
a + Fe3C
2
3
Composition (wt% C)
L
2500
4.30
2000
y + Fe3C
727°C
1500
Cementite (Fe3C)
1000
4
5
6
6.70
Temperature (°F)
Chapter 23 Solutions
General, Organic, and Biological Chemistry
Ch. 23.1 - Prob. 1QQCh. 23.1 - Prob. 2QQCh. 23.2 - Which of the following is not found within the...Ch. 23.2 - Which of the following is not an organelle? a....Ch. 23.2 - Prob. 3QQCh. 23.2 - Prob. 4QQCh. 23.3 - Which of the following statements concerning...Ch. 23.3 - Prob. 2QQCh. 23.3 - Which of the following statements concerning...Ch. 23.3 - Which of the following statements concerning...
Ch. 23.3 - Which of the following statements concerning...Ch. 23.4 - Prob. 1QQCh. 23.4 - Prob. 2QQCh. 23.5 - Prob. 1QQCh. 23.5 - Prob. 2QQCh. 23.5 - Prob. 3QQCh. 23.6 - Which of the following occurs in the second stage...Ch. 23.6 - Which of the following stages in the biochemical...Ch. 23.6 - Prob. 3QQCh. 23.7 - Prob. 1QQCh. 23.7 - Prob. 2QQCh. 23.7 - Prob. 3QQCh. 23.7 - How many NADH and FADH2 molecules are produced,...Ch. 23.7 - Which of the following citric acid cycle...Ch. 23.7 - In which of the following listings of citric acid...Ch. 23.8 - Which of the following is a fuel for the electron...Ch. 23.8 - Prob. 2QQCh. 23.8 - What is the substrate that initially interacts...Ch. 23.8 - The number of fixed enzyme sites in the electron...Ch. 23.8 - In which of the following listings of electron...Ch. 23.8 - Prob. 6QQCh. 23.9 - How many of the four enzyme complexes in the...Ch. 23.9 - Prob. 2QQCh. 23.9 - Prob. 3QQCh. 23.10 - Prob. 1QQCh. 23.10 - Prob. 2QQCh. 23.11 - Prob. 1QQCh. 23.11 - Prob. 2QQCh. 23.11 - Prob. 3QQCh. 23.12 - Prob. 1QQCh. 23.12 - Prob. 2QQCh. 23 - Classify anabolism and catabolism as synthetic or...Ch. 23 - Classify anabolism and catabolism as...Ch. 23 - What is a metabolic pathway?Ch. 23 - Prob. 23.4EPCh. 23 - Classify each of the following processes as...Ch. 23 - Classify each of the following processes as...Ch. 23 - Prob. 23.7EPCh. 23 - Prob. 23.8EPCh. 23 - Prob. 23.9EPCh. 23 - Indicate whether each of the following statements...Ch. 23 - Prob. 23.11EPCh. 23 - Prob. 23.12EPCh. 23 - Prob. 23.13EPCh. 23 - Prob. 23.14EPCh. 23 - Specify, by name and by number present, the...Ch. 23 - Prob. 23.16EPCh. 23 - Prob. 23.17EPCh. 23 - Prob. 23.18EPCh. 23 - Prob. 23.19EPCh. 23 - Prob. 23.20EPCh. 23 - Prob. 23.21EPCh. 23 - Prob. 23.22EPCh. 23 - Write a generalized chemical equation, containing...Ch. 23 - Prob. 23.24EPCh. 23 - Prob. 23.25EPCh. 23 - Prob. 23.26EPCh. 23 - Draw each of the following types of block diagrams...Ch. 23 - Prob. 23.28EPCh. 23 - What is the name of the B vitamin present in each...Ch. 23 - Prob. 23.30EPCh. 23 - Prob. 23.31EPCh. 23 - Prob. 23.32EPCh. 23 - Prob. 23.33EPCh. 23 - Prob. 23.34EPCh. 23 - Prob. 23.35EPCh. 23 - Prob. 23.36EPCh. 23 - Prob. 23.37EPCh. 23 - Prob. 23.38EPCh. 23 - Prob. 23.39EPCh. 23 - Prob. 23.40EPCh. 23 - Prob. 23.41EPCh. 23 - Prob. 23.42EPCh. 23 - Prob. 23.43EPCh. 23 - Prob. 23.44EPCh. 23 - Prob. 23.45EPCh. 23 - Prob. 23.46EPCh. 23 - Prob. 23.47EPCh. 23 - Prob. 23.48EPCh. 23 - Prob. 23.49EPCh. 23 - Prob. 23.50EPCh. 23 - Prob. 23.51EPCh. 23 - Prob. 23.52EPCh. 23 - Prob. 23.53EPCh. 23 - Prob. 23.54EPCh. 23 - Prob. 23.55EPCh. 23 - Prob. 23.56EPCh. 23 - Prob. 23.57EPCh. 23 - Prob. 23.58EPCh. 23 - List, by name, the four general stages of the...Ch. 23 - Prob. 23.60EPCh. 23 - Prob. 23.61EPCh. 23 - Prob. 23.62EPCh. 23 - Prob. 23.63EPCh. 23 - Prob. 23.64EPCh. 23 - Prob. 23.65EPCh. 23 - Prob. 23.66EPCh. 23 - Prob. 23.67EPCh. 23 - Prob. 23.68EPCh. 23 - Prob. 23.69EPCh. 23 - Prob. 23.70EPCh. 23 - Prob. 23.71EPCh. 23 - Prob. 23.72EPCh. 23 - Prob. 23.73EPCh. 23 - Prob. 23.74EPCh. 23 - Prob. 23.75EPCh. 23 - Prob. 23.76EPCh. 23 - Prob. 23.77EPCh. 23 - Prob. 23.78EPCh. 23 - Prob. 23.79EPCh. 23 - Prob. 23.80EPCh. 23 - Prob. 23.81EPCh. 23 - Prob. 23.82EPCh. 23 - Prob. 23.83EPCh. 23 - Prob. 23.84EPCh. 23 - Prob. 23.85EPCh. 23 - Prob. 23.86EPCh. 23 - Prob. 23.87EPCh. 23 - Prob. 23.88EPCh. 23 - Indicate whether each of the following changes...Ch. 23 - Prob. 23.90EPCh. 23 - Prob. 23.91EPCh. 23 - Prob. 23.92EPCh. 23 - Which electron carrier shuttles electrons between...Ch. 23 - Prob. 23.94EPCh. 23 - Prob. 23.95EPCh. 23 - Prob. 23.96EPCh. 23 - Prob. 23.97EPCh. 23 - Prob. 23.98EPCh. 23 - Prob. 23.99EPCh. 23 - Prob. 23.100EPCh. 23 - Put the following substances in the correct order...Ch. 23 - Prob. 23.102EPCh. 23 - Prob. 23.103EPCh. 23 - Prob. 23.104EPCh. 23 - Prob. 23.105EPCh. 23 - Prob. 23.106EPCh. 23 - Prob. 23.107EPCh. 23 - Prob. 23.108EPCh. 23 - Prob. 23.109EPCh. 23 - Prob. 23.110EPCh. 23 - How many protons cross the inner mitochondrial...Ch. 23 - How many protons cross the inner mitochondrial...Ch. 23 - Prob. 23.113EPCh. 23 - Prob. 23.114EPCh. 23 - Prob. 23.115EPCh. 23 - Prob. 23.116EPCh. 23 - Prob. 23.117EPCh. 23 - Prob. 23.118EPCh. 23 - Prob. 23.119EPCh. 23 - Prob. 23.120EPCh. 23 - Prob. 23.121EPCh. 23 - Prob. 23.122EPCh. 23 - Prob. 23.123EPCh. 23 - Prob. 23.124EPCh. 23 - Prob. 23.125EPCh. 23 - Prob. 23.126EPCh. 23 - Prob. 23.127EPCh. 23 - Prob. 23.128EPCh. 23 - Indicate whether or not each of the following B...Ch. 23 - Prob. 23.130EPCh. 23 - Prob. 23.131EPCh. 23 - Prob. 23.132EP
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