
General, Organic, and Biological Chemistry
7th Edition
ISBN: 9781285853918
Author: H. Stephen Stoker
Publisher: Cengage Learning
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Chapter 23.9, Problem 2QQ
Interpretation Introduction
Interpretation: To determine the number of proton transfer across the inner mitochondrial membrane that is effected by one NADH molecule in the electron transport chain.
Concept introduction: Oxidative phosphorylation is the biochemical process for the synthesis of ATP from ADP and
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Indicate the processes in the dismutation of Cu2O.
1. Consider these three reactions as the elementary steps in the mechanism for a chemical reaction.
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Potential Energy (kJ)
600
400
200
0
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-600-
-800
(i) Cl₂ (g) + Pt(s) → 2Cl (g) + Pt(s)
(ii) Cl (g)+ CO (g) + Pt (s) → CICO (g) + Pt (s)
Ea = 1550 kJ
Ea = 2240 kJ
(iii) Cl (g) + CICO (g) → Cl₂CO (g)
Ea
= 2350 kJ
AH=-950 kJ
ΔΗ = 575 ΚΙ
AH=-825 kJ
a. Draw the potential energy diagram for the reaction. Label the data points for clarity.
The potential energy of the reactants is 600 kJ
Reaction Progress
b. What is the overall chemical equation?
c. What is the overall change in enthalpy for the above chemical reaction?
d. What is the overall amount of activation energy for the above chemical reaction?
e. Which reaction intermediate would be considered a catalyst (if any) and why?
f. If you were to add 2700kJ of energy to the reaction (e.g. 2700 kl of heat or electricity), would
you be able to make the reaction reverse itself (i.e. have…
draw the enolate anion and the carbonyl that would be needed to make this product through an aldol addition reaction.
Chapter 23 Solutions
General, Organic, and Biological Chemistry
Ch. 23.1 - Prob. 1QQCh. 23.1 - Prob. 2QQCh. 23.2 - Which of the following is not found within the...Ch. 23.2 - Which of the following is not an organelle? a....Ch. 23.2 - Prob. 3QQCh. 23.2 - Prob. 4QQCh. 23.3 - Which of the following statements concerning...Ch. 23.3 - Prob. 2QQCh. 23.3 - Which of the following statements concerning...Ch. 23.3 - Which of the following statements concerning...
Ch. 23.3 - Which of the following statements concerning...Ch. 23.4 - Prob. 1QQCh. 23.4 - Prob. 2QQCh. 23.5 - Prob. 1QQCh. 23.5 - Prob. 2QQCh. 23.5 - Prob. 3QQCh. 23.6 - Which of the following occurs in the second stage...Ch. 23.6 - Which of the following stages in the biochemical...Ch. 23.6 - Prob. 3QQCh. 23.7 - Prob. 1QQCh. 23.7 - Prob. 2QQCh. 23.7 - Prob. 3QQCh. 23.7 - How many NADH and FADH2 molecules are produced,...Ch. 23.7 - Which of the following citric acid cycle...Ch. 23.7 - In which of the following listings of citric acid...Ch. 23.8 - Which of the following is a fuel for the electron...Ch. 23.8 - Prob. 2QQCh. 23.8 - What is the substrate that initially interacts...Ch. 23.8 - The number of fixed enzyme sites in the electron...Ch. 23.8 - In which of the following listings of electron...Ch. 23.8 - Prob. 6QQCh. 23.9 - How many of the four enzyme complexes in the...Ch. 23.9 - Prob. 2QQCh. 23.9 - Prob. 3QQCh. 23.10 - Prob. 1QQCh. 23.10 - Prob. 2QQCh. 23.11 - Prob. 1QQCh. 23.11 - Prob. 2QQCh. 23.11 - Prob. 3QQCh. 23.12 - Prob. 1QQCh. 23.12 - Prob. 2QQCh. 23 - Classify anabolism and catabolism as synthetic or...Ch. 23 - Classify anabolism and catabolism as...Ch. 23 - What is a metabolic pathway?Ch. 23 - Prob. 23.4EPCh. 23 - Classify each of the following processes as...Ch. 23 - Classify each of the following processes as...Ch. 23 - Prob. 23.7EPCh. 23 - Prob. 23.8EPCh. 23 - Prob. 23.9EPCh. 23 - Indicate whether each of the following statements...Ch. 23 - Prob. 23.11EPCh. 23 - Prob. 23.12EPCh. 23 - Prob. 23.13EPCh. 23 - Prob. 23.14EPCh. 23 - Specify, by name and by number present, the...Ch. 23 - Prob. 23.16EPCh. 23 - Prob. 23.17EPCh. 23 - Prob. 23.18EPCh. 23 - Prob. 23.19EPCh. 23 - Prob. 23.20EPCh. 23 - Prob. 23.21EPCh. 23 - Prob. 23.22EPCh. 23 - Write a generalized chemical equation, containing...Ch. 23 - Prob. 23.24EPCh. 23 - Prob. 23.25EPCh. 23 - Prob. 23.26EPCh. 23 - Draw each of the following types of block diagrams...Ch. 23 - Prob. 23.28EPCh. 23 - What is the name of the B vitamin present in each...Ch. 23 - Prob. 23.30EPCh. 23 - Prob. 23.31EPCh. 23 - Prob. 23.32EPCh. 23 - Prob. 23.33EPCh. 23 - Prob. 23.34EPCh. 23 - Prob. 23.35EPCh. 23 - Prob. 23.36EPCh. 23 - Prob. 23.37EPCh. 23 - Prob. 23.38EPCh. 23 - Prob. 23.39EPCh. 23 - Prob. 23.40EPCh. 23 - Prob. 23.41EPCh. 23 - Prob. 23.42EPCh. 23 - Prob. 23.43EPCh. 23 - Prob. 23.44EPCh. 23 - Prob. 23.45EPCh. 23 - Prob. 23.46EPCh. 23 - Prob. 23.47EPCh. 23 - Prob. 23.48EPCh. 23 - Prob. 23.49EPCh. 23 - Prob. 23.50EPCh. 23 - Prob. 23.51EPCh. 23 - Prob. 23.52EPCh. 23 - Prob. 23.53EPCh. 23 - Prob. 23.54EPCh. 23 - Prob. 23.55EPCh. 23 - Prob. 23.56EPCh. 23 - Prob. 23.57EPCh. 23 - Prob. 23.58EPCh. 23 - List, by name, the four general stages of the...Ch. 23 - Prob. 23.60EPCh. 23 - Prob. 23.61EPCh. 23 - Prob. 23.62EPCh. 23 - Prob. 23.63EPCh. 23 - Prob. 23.64EPCh. 23 - Prob. 23.65EPCh. 23 - Prob. 23.66EPCh. 23 - Prob. 23.67EPCh. 23 - Prob. 23.68EPCh. 23 - Prob. 23.69EPCh. 23 - Prob. 23.70EPCh. 23 - Prob. 23.71EPCh. 23 - Prob. 23.72EPCh. 23 - Prob. 23.73EPCh. 23 - Prob. 23.74EPCh. 23 - Prob. 23.75EPCh. 23 - Prob. 23.76EPCh. 23 - Prob. 23.77EPCh. 23 - Prob. 23.78EPCh. 23 - Prob. 23.79EPCh. 23 - Prob. 23.80EPCh. 23 - Prob. 23.81EPCh. 23 - Prob. 23.82EPCh. 23 - Prob. 23.83EPCh. 23 - Prob. 23.84EPCh. 23 - Prob. 23.85EPCh. 23 - Prob. 23.86EPCh. 23 - Prob. 23.87EPCh. 23 - Prob. 23.88EPCh. 23 - Indicate whether each of the following changes...Ch. 23 - Prob. 23.90EPCh. 23 - Prob. 23.91EPCh. 23 - Prob. 23.92EPCh. 23 - Which electron carrier shuttles electrons between...Ch. 23 - Prob. 23.94EPCh. 23 - Prob. 23.95EPCh. 23 - Prob. 23.96EPCh. 23 - Prob. 23.97EPCh. 23 - Prob. 23.98EPCh. 23 - Prob. 23.99EPCh. 23 - Prob. 23.100EPCh. 23 - Put the following substances in the correct order...Ch. 23 - Prob. 23.102EPCh. 23 - Prob. 23.103EPCh. 23 - Prob. 23.104EPCh. 23 - Prob. 23.105EPCh. 23 - Prob. 23.106EPCh. 23 - Prob. 23.107EPCh. 23 - Prob. 23.108EPCh. 23 - Prob. 23.109EPCh. 23 - Prob. 23.110EPCh. 23 - How many protons cross the inner mitochondrial...Ch. 23 - How many protons cross the inner mitochondrial...Ch. 23 - Prob. 23.113EPCh. 23 - Prob. 23.114EPCh. 23 - Prob. 23.115EPCh. 23 - Prob. 23.116EPCh. 23 - Prob. 23.117EPCh. 23 - Prob. 23.118EPCh. 23 - Prob. 23.119EPCh. 23 - Prob. 23.120EPCh. 23 - Prob. 23.121EPCh. 23 - Prob. 23.122EPCh. 23 - Prob. 23.123EPCh. 23 - Prob. 23.124EPCh. 23 - Prob. 23.125EPCh. 23 - Prob. 23.126EPCh. 23 - Prob. 23.127EPCh. 23 - Prob. 23.128EPCh. 23 - Indicate whether or not each of the following B...Ch. 23 - Prob. 23.130EPCh. 23 - Prob. 23.131EPCh. 23 - Prob. 23.132EP
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