To identify the compound among ATP and phosphoenolpyruvate that releases more energy upon hydrolysis. Concept introduction: High-energy compounds are those compounds that release a large amount of energy upon hydrolysis. These compounds consist of highly strained bonds which are responsible for the release of a high amount of energy. The compounds containing a phosphate group are examples of high energy compound. Free energy on hydrolysis is considered as a parameter for determining the strain in the bonds. Greater the strain in the bond more will be the negative value of free energy on hydrolysis and vice-versa.

Question

Photochemical smog is formed in part by the action of light on nitrogen dioxide. The wavelength of radiation absorbed by NO2 in this reaction is 197 nm.(a) Draw the Lewis structure of NO2 and sketch its π molecular orbitals.(b) When 1.56 mJ of energy is absorbed by 3.0 L of air at 20 °C and 0.91 atm, all the NO2 molecules in this sample dissociate by the reaction shown. Assume that each absorbed photon leads to the dissociation (into NO and O) of one NO2 molecule. What is the proportion, in parts per million, of NO2 molecules in this sample? Assume that the sample behaves ideally.

Answer 1

Question

Chapter 23, Problem 23.55EP

(a)

Interpretation Introduction

Interpretation: To identify the compound among ATP and phosphoenolpyruvate that releases more energy upon hydrolysis.

Concept introduction: High-energy compounds are those compounds that release a large amount of energy upon hydrolysis. These compounds consist of highly strained bonds which are responsible for the release of a high amount of energy. The compounds containing a phosphate group are examples of high energy compound.

Free energy on hydrolysis is considered as a parameter for determining the strain in the bonds. Greater the strain in the bond more will be the negative value of free energy on hydrolysis and vice-versa.

(b)

Interpretation Introduction

Interpretation: To identify the compound among creatine phosphate and ADP that releases more energy upon hydrolysis.

Concept introduction: High-energy compounds are those compounds that release a large amount of energy upon hydrolysis. These compounds consist of highly strained bonds which are responsible for the release of a high amount of energy. The compounds containing a phosphate group are examples of high energy compound.

Free energy on hydrolysis is considered as a parameter for determining the strain in the bonds. Greater the strain in the bond more will be the negative value of free energy on hydrolysis and vice-versa.

(c)

Interpretation Introduction

Interpretation: To identify the compound among glucose 1-phosphate and 1,3-bisphosphoglycerate that releases more energy upon hydrolysis.

Concept introduction: High-energy compounds are those compounds that release a large amount of energy upon hydrolysis. These compounds consist of highly strained bonds which are responsible for the release of a high amount of energy. The compounds containing a phosphate group are examples of high energy compound.

Free energy on hydrolysis is considered as a parameter for determining the strain in the bonds. Greater the strain in the bond more will be the negative value of free energy on hydrolysis and vice-versa.

(d)

Interpretation Introduction

Interpretation: To identify the compound among AMP and glycerol 3-phosphate that releases more energy upon hydrolysis.

Concept introduction: High-energy compounds are those compounds that release a large amount of energy upon hydrolysis. These compounds consist of highly strained bonds which are responsible for the release of a high amount of energy. The compounds containing a phosphate group are examples of high energy compound.

Free energy on hydrolysis is considered as a parameter for determining the strain in the bonds. Greater the strain in the bond more will be the negative value of free energy on hydrolysis and vice-versa.

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Photochemical smog is formed in part by the action of light on nitrogen dioxide. The wavelength of radiation absorbed by NO2 in this reaction is 197 nm.(a) Draw the Lewis structure of NO2 and sketch its π molecular orbitals.(b) When 1.56 mJ of energy is absorbed by 3.0 L of air at 20 °C and 0.91 atm, all the NO2 molecules in this sample dissociate by the reaction shown. Assume that each absorbed photon leads to the dissociation (into NO and O) of one NO2 molecule. What is the proportion, in parts per million, of NO2 molecules in this sample? Assume that the sample behaves ideally.

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An expression for the root mean square velocity, vrms, of a gas was derived. Using Maxwell’s velocity distribution, one can also calculate the mean velocity and the most probable velocity (mp) of a collection of molecules. The equations used for these two quantities are vmean=(8RT/πM)1/2 and vmp=(2RT/M)1/2 These values have a fixed relationship to each other.(a) Arrange these three quantities in order of increasing magnitude.(b) Show that the relative magnitudes are independent of the molar mass of the gas.(c) Use the smallest velocity as a reference for establishing the order of magnitude and determine the relationship between the larger and smaller values.

Answer 2

Question

Chapter 23, Problem 23.55EP

(a)

Interpretation Introduction

Interpretation: To identify the compound among ATP and phosphoenolpyruvate that releases more energy upon hydrolysis.

Concept introduction: High-energy compounds are those compounds that release a large amount of energy upon hydrolysis. These compounds consist of highly strained bonds which are responsible for the release of a high amount of energy. The compounds containing a phosphate group are examples of high energy compound.

Free energy on hydrolysis is considered as a parameter for determining the strain in the bonds. Greater the strain in the bond more will be the negative value of free energy on hydrolysis and vice-versa.

(b)

Interpretation Introduction

Interpretation: To identify the compound among creatine phosphate and ADP that releases more energy upon hydrolysis.

Concept introduction: High-energy compounds are those compounds that release a large amount of energy upon hydrolysis. These compounds consist of highly strained bonds which are responsible for the release of a high amount of energy. The compounds containing a phosphate group are examples of high energy compound.

Free energy on hydrolysis is considered as a parameter for determining the strain in the bonds. Greater the strain in the bond more will be the negative value of free energy on hydrolysis and vice-versa.

(c)

Interpretation Introduction

Interpretation: To identify the compound among glucose 1-phosphate and 1,3-bisphosphoglycerate that releases more energy upon hydrolysis.

Concept introduction: High-energy compounds are those compounds that release a large amount of energy upon hydrolysis. These compounds consist of highly strained bonds which are responsible for the release of a high amount of energy. The compounds containing a phosphate group are examples of high energy compound.

Free energy on hydrolysis is considered as a parameter for determining the strain in the bonds. Greater the strain in the bond more will be the negative value of free energy on hydrolysis and vice-versa.

(d)

Interpretation Introduction

Interpretation: To identify the compound among AMP and glycerol 3-phosphate that releases more energy upon hydrolysis.

Concept introduction: High-energy compounds are those compounds that release a large amount of energy upon hydrolysis. These compounds consist of highly strained bonds which are responsible for the release of a high amount of energy. The compounds containing a phosphate group are examples of high energy compound.

Free energy on hydrolysis is considered as a parameter for determining the strain in the bonds. Greater the strain in the bond more will be the negative value of free energy on hydrolysis and vice-versa.

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Answer 3

Question

Chapter 23, Problem 23.55EP

(a)

Interpretation Introduction

Interpretation: To identify the compound among ATP and phosphoenolpyruvate that releases more energy upon hydrolysis.

Concept introduction: High-energy compounds are those compounds that release a large amount of energy upon hydrolysis. These compounds consist of highly strained bonds which are responsible for the release of a high amount of energy. The compounds containing a phosphate group are examples of high energy compound.

Free energy on hydrolysis is considered as a parameter for determining the strain in the bonds. Greater the strain in the bond more will be the negative value of free energy on hydrolysis and vice-versa.

(b)

Interpretation Introduction

Interpretation: To identify the compound among creatine phosphate and ADP that releases more energy upon hydrolysis.

Concept introduction: High-energy compounds are those compounds that release a large amount of energy upon hydrolysis. These compounds consist of highly strained bonds which are responsible for the release of a high amount of energy. The compounds containing a phosphate group are examples of high energy compound.

Free energy on hydrolysis is considered as a parameter for determining the strain in the bonds. Greater the strain in the bond more will be the negative value of free energy on hydrolysis and vice-versa.

(c)

Interpretation Introduction

Interpretation: To identify the compound among glucose 1-phosphate and 1,3-bisphosphoglycerate that releases more energy upon hydrolysis.

Concept introduction: High-energy compounds are those compounds that release a large amount of energy upon hydrolysis. These compounds consist of highly strained bonds which are responsible for the release of a high amount of energy. The compounds containing a phosphate group are examples of high energy compound.

Free energy on hydrolysis is considered as a parameter for determining the strain in the bonds. Greater the strain in the bond more will be the negative value of free energy on hydrolysis and vice-versa.

(d)

Interpretation Introduction

Interpretation: To identify the compound among AMP and glycerol 3-phosphate that releases more energy upon hydrolysis.

Concept introduction: High-energy compounds are those compounds that release a large amount of energy upon hydrolysis. These compounds consist of highly strained bonds which are responsible for the release of a high amount of energy. The compounds containing a phosphate group are examples of high energy compound.

Free energy on hydrolysis is considered as a parameter for determining the strain in the bonds. Greater the strain in the bond more will be the negative value of free energy on hydrolysis and vice-versa.

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Answer 4

Question

Chapter 23, Problem 23.55EP

(a)

Interpretation Introduction

Interpretation: To identify the compound among ATP and phosphoenolpyruvate that releases more energy upon hydrolysis.

Concept introduction: High-energy compounds are those compounds that release a large amount of energy upon hydrolysis. These compounds consist of highly strained bonds which are responsible for the release of a high amount of energy. The compounds containing a phosphate group are examples of high energy compound.

Free energy on hydrolysis is considered as a parameter for determining the strain in the bonds. Greater the strain in the bond more will be the negative value of free energy on hydrolysis and vice-versa.

(b)

Interpretation Introduction

Interpretation: To identify the compound among creatine phosphate and ADP that releases more energy upon hydrolysis.

Concept introduction: High-energy compounds are those compounds that release a large amount of energy upon hydrolysis. These compounds consist of highly strained bonds which are responsible for the release of a high amount of energy. The compounds containing a phosphate group are examples of high energy compound.

Free energy on hydrolysis is considered as a parameter for determining the strain in the bonds. Greater the strain in the bond more will be the negative value of free energy on hydrolysis and vice-versa.

(c)

Interpretation Introduction

Interpretation: To identify the compound among glucose 1-phosphate and 1,3-bisphosphoglycerate that releases more energy upon hydrolysis.

Concept introduction: High-energy compounds are those compounds that release a large amount of energy upon hydrolysis. These compounds consist of highly strained bonds which are responsible for the release of a high amount of energy. The compounds containing a phosphate group are examples of high energy compound.

Free energy on hydrolysis is considered as a parameter for determining the strain in the bonds. Greater the strain in the bond more will be the negative value of free energy on hydrolysis and vice-versa.

(d)

Interpretation Introduction

Interpretation: To identify the compound among AMP and glycerol 3-phosphate that releases more energy upon hydrolysis.

Concept introduction: High-energy compounds are those compounds that release a large amount of energy upon hydrolysis. These compounds consist of highly strained bonds which are responsible for the release of a high amount of energy. The compounds containing a phosphate group are examples of high energy compound.

Free energy on hydrolysis is considered as a parameter for determining the strain in the bonds. Greater the strain in the bond more will be the negative value of free energy on hydrolysis and vice-versa.

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Answer 5

Chapter 23, Problem 23.55EP

(a)

Interpretation Introduction

Interpretation: To identify the compound among ATP and phosphoenolpyruvate that releases more energy upon hydrolysis.

Concept introduction: High-energy compounds are those compounds that release a large amount of energy upon hydrolysis. These compounds consist of highly strained bonds which are responsible for the release of a high amount of energy. The compounds containing a phosphate group are examples of high energy compound.

Free energy on hydrolysis is considered as a parameter for determining the strain in the bonds. Greater the strain in the bond more will be the negative value of free energy on hydrolysis and vice-versa.

(b)

Interpretation Introduction

Interpretation: To identify the compound among creatine phosphate and ADP that releases more energy upon hydrolysis.

Concept introduction: High-energy compounds are those compounds that release a large amount of energy upon hydrolysis. These compounds consist of highly strained bonds which are responsible for the release of a high amount of energy. The compounds containing a phosphate group are examples of high energy compound.

Free energy on hydrolysis is considered as a parameter for determining the strain in the bonds. Greater the strain in the bond more will be the negative value of free energy on hydrolysis and vice-versa.

(c)

Interpretation Introduction

Interpretation: To identify the compound among glucose 1-phosphate and 1,3-bisphosphoglycerate that releases more energy upon hydrolysis.

Concept introduction: High-energy compounds are those compounds that release a large amount of energy upon hydrolysis. These compounds consist of highly strained bonds which are responsible for the release of a high amount of energy. The compounds containing a phosphate group are examples of high energy compound.

Free energy on hydrolysis is considered as a parameter for determining the strain in the bonds. Greater the strain in the bond more will be the negative value of free energy on hydrolysis and vice-versa.

(d)

Interpretation Introduction

Interpretation: To identify the compound among AMP and glycerol 3-phosphate that releases more energy upon hydrolysis.

Concept introduction: High-energy compounds are those compounds that release a large amount of energy upon hydrolysis. These compounds consist of highly strained bonds which are responsible for the release of a high amount of energy. The compounds containing a phosphate group are examples of high energy compound.

Free energy on hydrolysis is considered as a parameter for determining the strain in the bonds. Greater the strain in the bond more will be the negative value of free energy on hydrolysis and vice-versa.

Answer 6

Chapter 23, Problem 23.55EP

(a)

Interpretation Introduction

Interpretation: To identify the compound among ATP and phosphoenolpyruvate that releases more energy upon hydrolysis.

Concept introduction: High-energy compounds are those compounds that release a large amount of energy upon hydrolysis. These compounds consist of highly strained bonds which are responsible for the release of a high amount of energy. The compounds containing a phosphate group are examples of high energy compound.

Free energy on hydrolysis is considered as a parameter for determining the strain in the bonds. Greater the strain in the bond more will be the negative value of free energy on hydrolysis and vice-versa.

Answer 7

Chapter 23, Problem 23.55EP

(a)

Interpretation Introduction

Interpretation: To identify the compound among ATP and phosphoenolpyruvate that releases more energy upon hydrolysis.

Concept introduction: High-energy compounds are those compounds that release a large amount of energy upon hydrolysis. These compounds consist of highly strained bonds which are responsible for the release of a high amount of energy. The compounds containing a phosphate group are examples of high energy compound.

Free energy on hydrolysis is considered as a parameter for determining the strain in the bonds. Greater the strain in the bond more will be the negative value of free energy on hydrolysis and vice-versa.

Answer 8

(b)

Interpretation Introduction

Interpretation: To identify the compound among creatine phosphate and ADP that releases more energy upon hydrolysis.

Concept introduction: High-energy compounds are those compounds that release a large amount of energy upon hydrolysis. These compounds consist of highly strained bonds which are responsible for the release of a high amount of energy. The compounds containing a phosphate group are examples of high energy compound.

Free energy on hydrolysis is considered as a parameter for determining the strain in the bonds. Greater the strain in the bond more will be the negative value of free energy on hydrolysis and vice-versa.

Answer 9

(b)

Interpretation Introduction

Interpretation: To identify the compound among creatine phosphate and ADP that releases more energy upon hydrolysis.

Concept introduction: High-energy compounds are those compounds that release a large amount of energy upon hydrolysis. These compounds consist of highly strained bonds which are responsible for the release of a high amount of energy. The compounds containing a phosphate group are examples of high energy compound.

Free energy on hydrolysis is considered as a parameter for determining the strain in the bonds. Greater the strain in the bond more will be the negative value of free energy on hydrolysis and vice-versa.

Answer 10

(c)

Interpretation Introduction

Interpretation: To identify the compound among glucose 1-phosphate and 1,3-bisphosphoglycerate that releases more energy upon hydrolysis.

Concept introduction: High-energy compounds are those compounds that release a large amount of energy upon hydrolysis. These compounds consist of highly strained bonds which are responsible for the release of a high amount of energy. The compounds containing a phosphate group are examples of high energy compound.

Free energy on hydrolysis is considered as a parameter for determining the strain in the bonds. Greater the strain in the bond more will be the negative value of free energy on hydrolysis and vice-versa.

Answer 11

(c)

Interpretation Introduction

Interpretation: To identify the compound among glucose 1-phosphate and 1,3-bisphosphoglycerate that releases more energy upon hydrolysis.

Concept introduction: High-energy compounds are those compounds that release a large amount of energy upon hydrolysis. These compounds consist of highly strained bonds which are responsible for the release of a high amount of energy. The compounds containing a phosphate group are examples of high energy compound.

Free energy on hydrolysis is considered as a parameter for determining the strain in the bonds. Greater the strain in the bond more will be the negative value of free energy on hydrolysis and vice-versa.

Answer 12

(d)

Interpretation Introduction

Interpretation: To identify the compound among AMP and glycerol 3-phosphate that releases more energy upon hydrolysis.

Concept introduction: High-energy compounds are those compounds that release a large amount of energy upon hydrolysis. These compounds consist of highly strained bonds which are responsible for the release of a high amount of energy. The compounds containing a phosphate group are examples of high energy compound.

Free energy on hydrolysis is considered as a parameter for determining the strain in the bonds. Greater the strain in the bond more will be the negative value of free energy on hydrolysis and vice-versa.

Answer 13

(d)

Interpretation Introduction

Interpretation: To identify the compound among AMP and glycerol 3-phosphate that releases more energy upon hydrolysis.

Concept introduction: High-energy compounds are those compounds that release a large amount of energy upon hydrolysis. These compounds consist of highly strained bonds which are responsible for the release of a high amount of energy. The compounds containing a phosphate group are examples of high energy compound.

Free energy on hydrolysis is considered as a parameter for determining the strain in the bonds. Greater the strain in the bond more will be the negative value of free energy on hydrolysis and vice-versa.

Answer 14

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Ch. 23.1 - Prob. 1QQ Ch. 23.1 - Prob. 2QQ Ch. 23.2 - Which of the following is not found within the...Ch. 23.2 - Which of the following is not an organelle? a....Ch. 23.2 - Prob. 3QQ Ch. 23.2 - Prob. 4QQ Ch. 23.3 - Which of the following statements concerning...Ch. 23.3 - Prob. 2QQ Ch. 23.3 - Which of the following statements concerning...Ch. 23.3 - Which of the following statements concerning...

Solution Summary: The author identifies the compound among ATP and phosphoenolpyruvate that releases more energy upon hydrolysis.

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