
General Chemistry: Atoms First
2nd Edition
ISBN: 9780321809261
Author: John E. McMurry, Robert C. Fay
Publisher: Prentice Hall
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Question
Chapter 20, Problem 20.130CHP
Interpretation Introduction
Interpretation:
The structure of all possible diastereoisomers of an octahedral complex with the formula
Concept introduction:
Stereoisomer: The same molecular formula but different with the arrangements of atoms around the metal ion. The Ligands are arranged differently in coordination compounds.
Diasteroisomers:
Stereoisomers which are not mirror images of each other can be termed as diastereoisomers.
It differs in physical properties such as melting point, solubility and refractive index.
Enantiomer:
It can have one carbon with four different substituents and have a non-superimposable mirror image.
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You are trying to decide if there is a single reagent you can add that will make the following synthesis possible without any other major side products:
xi
1. ☑
2. H₂O
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i
Draw the missing reagent X you think will make this synthesis work in the drawing area below.
If there is no reagent that will make your desired product in good yield or without complications, just check the box under the drawing area and leave it blank.
Click and drag to start drawing a
structure.
There is no reagent that will make this synthesis work without complications.
: ☐
S
☐
Predict the major products of this organic reaction:
H
OH
1. LiAlH4
2. H₂O
?
Note: be sure you use dash and wedge bonds when necessary, for example to distinguish between major products with different stereochemistry.
Click and drag to start drawing a
structure.
G
C
टे
For each reaction below, decide if the first stable organic product that forms in solution will create a new C-C bond, and check the appropriate box.
Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below.
Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first
stable product you expect to form in solution.
NH2
CI
MgCl
?
Will the first product that forms in this reaction
create a new CC bond?
Yes
No
MgBr
?
Will the first product that forms in this reaction
create a new CC bond?
Yes
No
G
टे
Chapter 20 Solutions
General Chemistry: Atoms First
Ch. 20.1 - Write the electron configuration of the metal in...Ch. 20.1 - Prob. 20.2CPCh. 20.3 - Prob. 20.3CPCh. 20.4 - Prob. 20.4PCh. 20.4 - Prob. 20.5PCh. 20.5 - Prob. 20.6PCh. 20.5 - Prob. 20.7PCh. 20.6 - Prob. 20.8PCh. 20.7 - Name each of the following: (a) [Cu(NH3)4]SO4, a...Ch. 20.7 - Prob. 20.10P
Ch. 20.8 - Prob. 20.11PCh. 20.8 - Prob. 20.12CPCh. 20.9 - Prob. 20.13PCh. 20.9 - Prob. 20.14CPCh. 20.9 - Prob. 20.15PCh. 20.10 - Prob. 20.16PCh. 20.11 - Prob. 20.17PCh. 20.12 - Prob. 20.18PCh. 20.12 - Prob. 20.19PCh. 20.12 - Prob. 20.20PCh. 20.12 - Prob. 20.21PCh. 20 - Prob. 20.22CPCh. 20 - Prob. 20.23CPCh. 20 - Prob. 20.24CPCh. 20 - Prob. 20.25CPCh. 20 - What is the systematic name for each of the...Ch. 20 - Prob. 20.27CPCh. 20 - Prob. 20.28CPCh. 20 - Prob. 20.29CPCh. 20 - Predict the crystal field energy-level diagram for...Ch. 20 - Prob. 20.31CPCh. 20 - Use the periodic table to give the electron...Ch. 20 - Prob. 20.33SPCh. 20 - Prob. 20.34SPCh. 20 - Prob. 20.35SPCh. 20 - Prob. 20.36SPCh. 20 - Prob. 20.37SPCh. 20 - Prob. 20.38SPCh. 20 - Prob. 20.39SPCh. 20 - What is the lanthanide contraction, and why does...Ch. 20 - The atomic radii of zirconium and hafnium are...Ch. 20 - Calculate the sum of the first two ionization...Ch. 20 - Prob. 20.43SPCh. 20 - Prob. 20.44SPCh. 20 - Prob. 20.45SPCh. 20 - Prob. 20.46SPCh. 20 - Prob. 20.47SPCh. 20 - Prob. 20.48SPCh. 20 - Prob. 20.49SPCh. 20 - Prob. 20.50SPCh. 20 - Prob. 20.51SPCh. 20 - Prob. 20.52SPCh. 20 - Prob. 20.53SPCh. 20 - Prob. 20.54SPCh. 20 - Prob. 20.55SPCh. 20 - Write a balanced equation for the industrial...Ch. 20 - Prob. 20.57SPCh. 20 - Prob. 20.58SPCh. 20 - Prob. 20.59SPCh. 20 - Prob. 20.60SPCh. 20 - Prob. 20.61SPCh. 20 - Prob. 20.62SPCh. 20 - Prob. 20.63SPCh. 20 - Prob. 20.64SPCh. 20 - Prob. 20.65SPCh. 20 - Prob. 20.66SPCh. 20 - Prob. 20.67SPCh. 20 - Prob. 20.68SPCh. 20 - Prob. 20.69SPCh. 20 - Prob. 20.70SPCh. 20 - Prob. 20.71SPCh. 20 - Prob. 20.72SPCh. 20 - Prob. 20.73SPCh. 20 - What is the formula of a complex that has each of...Ch. 20 - What is the formula, including the charge, for...Ch. 20 - Prob. 20.76SPCh. 20 - Prob. 20.77SPCh. 20 - Prob. 20.78SPCh. 20 - Prob. 20.79SPCh. 20 - Prob. 20.80SPCh. 20 - Prob. 20.81SPCh. 20 - What is the systematic name for each of the...Ch. 20 - Prob. 20.83SPCh. 20 - Prob. 20.84SPCh. 20 - Prob. 20.85SPCh. 20 - Prob. 20.86SPCh. 20 - Prob. 20.87SPCh. 20 - Prob. 20.88SPCh. 20 - Tell how many diastereoisomers are possible for...Ch. 20 - Which of the following complexes are chiral? (a)...Ch. 20 - Prob. 20.91SPCh. 20 - Prob. 20.92SPCh. 20 - Prob. 20.93SPCh. 20 - Prob. 20.94SPCh. 20 - Prob. 20.95SPCh. 20 - Prob. 20.96SPCh. 20 - Prob. 20.97SPCh. 20 - Prob. 20.98SPCh. 20 - Prob. 20.99SPCh. 20 - Prob. 20.100SPCh. 20 - Prob. 20.101SPCh. 20 - Prob. 20.102SPCh. 20 - Prob. 20.103SPCh. 20 - Prob. 20.104SPCh. 20 - Prob. 20.105SPCh. 20 - For each of the following complexes, draw a...Ch. 20 - Prob. 20.107SPCh. 20 - Prob. 20.108SPCh. 20 - Prob. 20.109SPCh. 20 - Prob. 20.110SPCh. 20 - Prob. 20.111SPCh. 20 - Prob. 20.112SPCh. 20 - Prob. 20.113SPCh. 20 - Prob. 20.114CHPCh. 20 - Prob. 20.115CHPCh. 20 - Prob. 20.116CHPCh. 20 - Prob. 20.117CHPCh. 20 - Prob. 20.118CHPCh. 20 - Prob. 20.119CHPCh. 20 - Prob. 20.120CHPCh. 20 - Prob. 20.121CHPCh. 20 - Prob. 20.122CHPCh. 20 - Prob. 20.123CHPCh. 20 - Prob. 20.124CHPCh. 20 - Draw a crystal field energy-level diagram, and...Ch. 20 - Prob. 20.126CHPCh. 20 - Prob. 20.127CHPCh. 20 - Prob. 20.128CHPCh. 20 - Prob. 20.129CHPCh. 20 - Prob. 20.130CHPCh. 20 - Look at the colors of the isomeric complexes in...Ch. 20 - The amount of paramagnetism for a first-series...Ch. 20 - Prob. 20.133CHPCh. 20 - Prob. 20.134CHPCh. 20 - Prob. 20.135CHPCh. 20 - For each of the following, (i) give the systematic...Ch. 20 - Prob. 20.137CHPCh. 20 - Prob. 20.138CHPCh. 20 - Prob. 20.139MPCh. 20 - Formation constants for the ammonia and...Ch. 20 - Prob. 20.141MPCh. 20 - Prob. 20.143MPCh. 20 - An alternative to cyanide leaching of gold ores is...
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