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Concept explainers
Interpretation:
The Lewis acid and Lewis base in compound
Concept Introduction:
Reduction: If electrons are gained to a species during a
Oxidation: If electrons are moved from a species during a chemical reaction. The species whose electrons are removed is said to be oxidized.
Lewis acid: The chemical species which accepts pair of electrons are termed as Lewis acid.
Lewis base: The chemical species which donates pair of electrons are termed as Lewis base.
Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.
Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound.
Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.
Bidentate ligand is ligands which donate two pair of electrons to form bond with metal.
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Chapter 20 Solutions
General Chemistry: Atoms First
- Using data in Appendix 1, estimate the temperature at which Fe2O3 can be reduced to iron, using hydrogen gas as a reducing agent (assume H2O(g) is the other product).arrow_forward(c) Suggest how the following boron species could be prepared, showing any intermediates. -B(OH)2 B(OH)2arrow_forwardDichromate, Cr2O7 2– , and permanganate, MnO4 – , are both common oxidising agents. When mixed, would acidified dichromate oxidise Mn2+ or would acidified permanganate oxidise Cr3+? Explain what you think would happen and write a chemical equation to show this.arrow_forward
- Complete and balance the following:(a) As(s) 1 excess O2(g)→(b) Bi(s) 1 excess F2(g) →(c) Ca3As2(s) 1 H2O(l) →arrow_forwardWrite the acidic equilibrium equation for HIO2.arrow_forwardExplain how the diphosphate ion, [O3P−O−PO3]4−, can function as a water softener that prevents the precipitation of Fe2+ as an insoluble iron salt.arrow_forward
- (a) Deduce the number of 3d electrons in the following ions Fe3+ , Cu2+. (b) Why do transition metals forms alloys. (c) Write any two characteristics of interstitial compounds.arrow_forwardDraw appropriate energy diagrams and determine all possible numbers of unpaired electrons in compounds of the following ions within an octahedral crystal field: (a) Mn2 +, (b) Co3 +, (c) Ni2 +, (d) Fe3 +arrow_forwardConsider the series of reactions to synthesize the alum (KAl(SO4 )2 · xH2O(s)) from the introduction. (a) Assuming an excess of the other reagents, from one mole of aluminum Al (s), how many moles of alum will be produced? (b) Assuming an excess of the other reagents, from one mole of potassium hydroxide KOH, how many moles of alum will be produced? (c) Assuming an excess of the other reagents, from one mole of sulfuric acid H2SO4 , how many moles of alum will be produced? (d) If you start the synthesis with 1.00 g of Al, 40.0 mL of 1.50 M KOH, and 20.0 mL of 9.00 M H2SO4 , which of the three will be the limiting reagent? (e) Assuming that the product is anhydrous (that there are no waters of hydration), calculate the theoretical yield of alum, in grams, based on the amounts of reagents in part (d). 3. Consider the nickel salt: (NH4 )2Ni(SO4 )2 ·y H2O (Ammonium Nickel Sulfate Hydrate), where y is the number of coordinated waters. (a) Assuming that the product is anhydrous (y = 0),…arrow_forward
- The pH of a 0.2 M solution of CuSO4 is 4.0. Write chemical equations to explain why a solution of this salt is neither basic [from the reaction of SO42-(aq) with water] nor neutral, but acidic.arrow_forward[Fe(H2O)6]2+, calculate the bond orderarrow_forwardWhat is the acidic equilibrium equation for HC₂H₃O₂?arrow_forward
- Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningChemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage Learning
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning
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