The structure of two isomeric compounds of Co ( NH 3 ) 3 ( NO 2 ) 3 has to be drawn. Concept Introduction : Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions. Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms. Structural isomers: molecules have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal). Stereoisomers: differ in their spatial arrangement of atoms. Stereoisomer: The same molecular formula but different with the arrangements of atoms around the metal ion. The Ligands are arranged differently in coordination compounds. Geometric isomers: stereoisomers that cannot be interconverted without breaking the chemical bonds.

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Answer 1

Question

Chapter 20, Problem 20.129CHP

a)

Interpretation Introduction

Interpretation:

The structure of two isomeric compounds of Co(NH3)3(NO2)3 has to be drawn.

Concept Introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: molecules have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

Stereoisomer: The same molecular formula but different with the arrangements of atoms around the metal ion. The Ligands are arranged differently in coordination compounds.

Geometric isomers: stereoisomers that cannot be interconverted without breaking the chemical bonds.

b)

Interpretation Introduction

Interpretation:

The chemical formula of the third compound has to be predicted.

Concept Introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

Stereoisomer: The same molecular formula but different with the arrangements of atoms around the metal ion. The Ligands are arranged differently in coordination compounds.

Geometric isomers: stereoisomers that cannot be interconverted without breaking the chemical bonds.

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Answer 2

Question

Chapter 20, Problem 20.129CHP

a)

Interpretation Introduction

Interpretation:

The structure of two isomeric compounds of Co(NH3)3(NO2)3 has to be drawn.

Concept Introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: molecules have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

Stereoisomer: The same molecular formula but different with the arrangements of atoms around the metal ion. The Ligands are arranged differently in coordination compounds.

Geometric isomers: stereoisomers that cannot be interconverted without breaking the chemical bonds.

b)

Interpretation Introduction

Interpretation:

The chemical formula of the third compound has to be predicted.

Concept Introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

Stereoisomer: The same molecular formula but different with the arrangements of atoms around the metal ion. The Ligands are arranged differently in coordination compounds.

Geometric isomers: stereoisomers that cannot be interconverted without breaking the chemical bonds.

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Answer 3

Question

Chapter 20, Problem 20.129CHP

a)

Interpretation Introduction

Interpretation:

The structure of two isomeric compounds of Co(NH3)3(NO2)3 has to be drawn.

Concept Introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: molecules have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

Stereoisomer: The same molecular formula but different with the arrangements of atoms around the metal ion. The Ligands are arranged differently in coordination compounds.

Geometric isomers: stereoisomers that cannot be interconverted without breaking the chemical bonds.

b)

Interpretation Introduction

Interpretation:

The chemical formula of the third compound has to be predicted.

Concept Introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

Stereoisomer: The same molecular formula but different with the arrangements of atoms around the metal ion. The Ligands are arranged differently in coordination compounds.

Geometric isomers: stereoisomers that cannot be interconverted without breaking the chemical bonds.

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Answer 4

Question

Chapter 20, Problem 20.129CHP

a)

Interpretation Introduction

Interpretation:

The structure of two isomeric compounds of Co(NH3)3(NO2)3 has to be drawn.

Concept Introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: molecules have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

Stereoisomer: The same molecular formula but different with the arrangements of atoms around the metal ion. The Ligands are arranged differently in coordination compounds.

Geometric isomers: stereoisomers that cannot be interconverted without breaking the chemical bonds.

b)

Interpretation Introduction

Interpretation:

The chemical formula of the third compound has to be predicted.

Concept Introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

Stereoisomer: The same molecular formula but different with the arrangements of atoms around the metal ion. The Ligands are arranged differently in coordination compounds.

Geometric isomers: stereoisomers that cannot be interconverted without breaking the chemical bonds.

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Answer 5

Chapter 20, Problem 20.129CHP

a)

Interpretation Introduction

Interpretation:

The structure of two isomeric compounds of Co(NH3)3(NO2)3 has to be drawn.

Concept Introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: molecules have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

Stereoisomer: The same molecular formula but different with the arrangements of atoms around the metal ion. The Ligands are arranged differently in coordination compounds.

Geometric isomers: stereoisomers that cannot be interconverted without breaking the chemical bonds.

b)

Interpretation Introduction

Interpretation:

The chemical formula of the third compound has to be predicted.

Concept Introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

Stereoisomer: The same molecular formula but different with the arrangements of atoms around the metal ion. The Ligands are arranged differently in coordination compounds.

Geometric isomers: stereoisomers that cannot be interconverted without breaking the chemical bonds.

Answer 6

Chapter 20, Problem 20.129CHP

a)

Interpretation Introduction

Interpretation:

The structure of two isomeric compounds of Co(NH3)3(NO2)3 has to be drawn.

Concept Introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: molecules have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

Stereoisomer: The same molecular formula but different with the arrangements of atoms around the metal ion. The Ligands are arranged differently in coordination compounds.

Geometric isomers: stereoisomers that cannot be interconverted without breaking the chemical bonds.

Answer 7

Chapter 20, Problem 20.129CHP

a)

Interpretation Introduction

Interpretation:

The structure of two isomeric compounds of Co(NH3)3(NO2)3 has to be drawn.

Concept Introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: molecules have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

Stereoisomer: The same molecular formula but different with the arrangements of atoms around the metal ion. The Ligands are arranged differently in coordination compounds.

Geometric isomers: stereoisomers that cannot be interconverted without breaking the chemical bonds.

Answer 8

b)

Interpretation Introduction

Interpretation:

The chemical formula of the third compound has to be predicted.

Concept Introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

Stereoisomer: The same molecular formula but different with the arrangements of atoms around the metal ion. The Ligands are arranged differently in coordination compounds.

Geometric isomers: stereoisomers that cannot be interconverted without breaking the chemical bonds.

Answer 9

b)

Interpretation Introduction

Interpretation:

The chemical formula of the third compound has to be predicted.

Concept Introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

Stereoisomer: The same molecular formula but different with the arrangements of atoms around the metal ion. The Ligands are arranged differently in coordination compounds.

Geometric isomers: stereoisomers that cannot be interconverted without breaking the chemical bonds.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 20.1 - Write the electron configuration of the metal in...Ch. 20.1 - Prob. 20.2CP Ch. 20.3 - Prob. 20.3CP Ch. 20.4 - Prob. 20.4P Ch. 20.4 - Prob. 20.5P Ch. 20.5 - Prob. 20.6P Ch. 20.5 - Prob. 20.7P Ch. 20.6 - Prob. 20.8P Ch. 20.7 - Name each of the following: (a) [Cu(NH3)4]SO4, a...Ch. 20.7 - Prob. 20.10P

Solution Summary: The author explains that the structure of two isomeric compounds has to be drawn.

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