The two possible isomers for given complex [ C o ( N H 3 ) 3 ( N O 2 ) 3 ] should be drawn Concept Introduction: Isomerism: Two chemical compounds are said to be isomers if they have same number and kind of atoms but different only in their orientation that is structural arrangements. There are different types of isomerism in which geometric is of one type where the rotation around the atom is restricted like in cis-trans configuration. This is also refereed as cis-trans isomerism. Structural isomers: Have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal). Stereoisomers: differ in their spatial arrangement of atoms.

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Chapter 20, Problem 20.134CHP

(a)

Interpretation Introduction

Interpretation:

The two possible isomers for given complex [Co(NH3)3(NO2)3] should be drawn

Concept Introduction:

Isomerism: Two chemical compounds are said to be isomers if they have same number and kind of atoms but different only in their orientation that is structural arrangements.

There are different types of isomerism in which geometric is of one type where the rotation around the atom is restricted like in cis-trans configuration. This is also refereed as cis-trans isomerism.

Structural isomers: Have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

(b)

Interpretation Introduction

Interpretation:

The two possible isomers for given complex [Co(NH3)3(NO2)3] should be drawn

Concept Introduction:

Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound.

Stereoisomer: The same molecular formula but different with the arrangements of atoms around the metal ion. The Ligands are arranged differently in coordination compounds.

Geometric isomers: stereoisomers that cannot be interconverted without breaking the chemical bonds.

Optical isomers: Optical isomers are non-superimposable mirror images.

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