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Concept explainers
(a)
Interpretation:
For the given set of ethylenediamine complexes, the chiral and achiral complexes are to be identified.
Concept Introduction:
Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.
Chirality:
Objects having non-superimposable mirror image relationship that is, it does not contain plane of symmetry are referred as chiral.
Symmetry operation (Plane of symmetry):
It is an operation that gives an object looking the same after it has been carried out.
(b)
Interpretation:
The enantiomer for chiral complex should be identified.
(c)
Interpretation:
From the given set of complexes if any of chiral complexes are enantiomers of one another should be identified.
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Chapter 20 Solutions
General Chemistry: Atoms First
- Four different octahedral chromium coordination compounds exist that all have the same oxidation state for chromium and have H2O and Cl as the ligands and counterions. When 1 mole of each of the four compounds is dissolved in water, how many moles of silver chloride will precipitate upon addition of excess AgNO3?arrow_forwardPlatinum(II) forms many complexes, among them those with the following ligands. Give the formula and charge of each complex. (a) two ammonia molecules and one oxalate ion (C2O42-) (b) two ammonia molecules, one thiocyanate ion (SCN-), and one bromide ion (c) one ethylenediamine molecule and two nitrite ionsarrow_forwardTrimethylphosphine, P(CH3)3, can act as a ligand by donating the lone pair of electrons on the phosphorus atom. If trimethylphosphine is added to a solution of nickel(Il) chloride in acetone, a blue compound that has a molecular mass of approximately 270 g and contains 21.5% Ni, 26.0% Cl, and 52.5% P(CH3)3 can be isolated. This blue compound does not have any isomeric forms. What are the geometry and molecular formula of the blue compound?arrow_forward
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