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(a)
Interpretation: The given incomplete reaction should be completed and its balanced net ionic equation has to be determined.
Concept introduction:
Transition element is one which can form one or more stable ions with a partially occupied d-subshell. Most of the
Ionic equation is an equation in which ions are explicitly shown.
Spectator ions are the ion that appears unchanged on both sides of a reaction arrow.
Net ionic equation is the chemical equation for a reaction which lists only those species participating in the reaction.
To write the net ionic equation, steps mentioned below must be followed.
- 1. Write the balanced molecular equation
- 2. Write the ionic equation showing the strong electrolytes completely dissociated into cations and anions.
- 3. Cancel the spectator ions on both sides of the ionic equation.
- 4. Check that charges and number of atoms are balanced in the net ionic equation.
(b)
Interpretation: The given incomplete reaction should be completed and its balanced net ionic equation has to be determined.
Concept introduction:
Transition element is one which can form one or more stable ions with a partially occupied d-subshell. Most of the transition elements are metals and majority of elements exists in various oxidation states also.
Ionic equation is an equation in which ions are explicitly shown.
Spectator ions are the ion that appears unchanged on both sides of a reaction arrow.
Net ionic equation is the chemical equation for a reaction which lists only those species participating in the reaction.
To write the net ionic equation, steps mentioned below must be followed.
- 1. Write the balanced molecular equation
- 2. Write the ionic equation showing the strong electrolytes completely dissociated into cations and anions.
- 3. Cancel the spectator ions on both sides of the ionic equation.
- 4. Check that charges and number of atoms are balanced in the net ionic equation.
(c)
Interpretation: The given incomplete reaction should be completed and its balanced net ionic equation has to be determined.
Concept introduction:
Transition element is one which can form one or more stable ions with a partially occupied d-subshell. Most of the transition elements are metals and majority of elements exists in various oxidation states also.
Ionic equation is an equation in which ions are explicitly shown.
Spectator ions are the ion that appears unchanged on both sides of a reaction arrow.
Net ionic equation is the chemical equation for a reaction which lists only those species participating in the reaction.
To write the net ionic equation, steps mentioned below must be followed.
- 1. Write the balanced molecular equation
- 2. Write the ionic equation showing the strong electrolytes completely dissociated into cations and anions.
- 3. Cancel the spectator ions on both sides of the ionic equation.
- 4. Check that charges and number of atoms are balanced in the net ionic equation.
(d)
Interpretation: The given incomplete reaction should be completed and its balanced net ionic equation has to be determined.
Concept introduction:
Transition element is one which can form one or more stable ions with a partially occupied d-subshell. Most of the transition elements are metals and majority of elements exists in various oxidation states also.
Ionic equation is an equation in which ions are explicitly shown.
Spectator ions are the ion that appears unchanged on both sides of a reaction arrow.
Net ionic equation is the chemical equation for a reaction which lists only those species participating in the reaction.
To write the net ionic equation, steps mentioned below must be followed.
- 1. Write the balanced molecular equation
- 2. Write the ionic equation showing the strong electrolytes completely dissociated into cations and anions.
- 3. Cancel the spectator ions on both sides of the ionic equation.
- 4. Check that charges and number of atoms are balanced in the net ionic equation.
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Chapter 20 Solutions
General Chemistry: Atoms First
- When carbon dioxide dissolves in water it reacts to produce carbonic acid, H2CO3(aq), which can ionize in two steps. H2CO3(aq)HCO3(aq)+H+(aq)Kc1=4.2107HCO3(aq)CO32(aq)+H+(aq)Kc2=4.81011 Calculate the equilibrium constant for the reaction H2CO3(aq)CO32(aq)+2H+(aq)arrow_forwardPhosphate buffers are important in regulating the pH of intracellular fluids. If the concentration ratio of H2PO4/HPO42 in a sample of intracellular fluid is 1.1: 1, what is the pH of this sample of intracellular fluid? H2PO4(aq)HPO42(aq)+H+(aq)Ka=6.2108arrow_forwardIn the commercial preparation of aluminum, aluminum oxide, Al2O3, is electrolyzed at 1000C. (The mineral cryolite is added as a solvent.) Assume that the cathode reaction is Al3+3eAl How many coulombs of electricity are required to give 3.9 kg of aluminum?arrow_forward
- Write balanced net ionic equations for the following reactions in acid solution. (a) Liquid hydrazine reacts with an aqueous solution of sodium bromate. Nitrogen gas and bromide ions are formed. (b) Solid phosphorus (P4) reacts with an aqueous solution of nitrate to form nitrogen oxide gas and dihydrogen phosphate (H2PO4-) ions. (c) Aqueous solutions of potassium sulfite and potassium permanganate react. Sulfate and manganese(II) ions are formed.arrow_forwardAluminum is produced commercially by the electrolysis of Al2O3 in the presence of a molten salt. If a plant has a continuous capacity of 1.00 million A, what mass of aluminum can be produced in 2.00 h?arrow_forwardAnswer the following questions by referring to standard electrode potentials at 25C. a Will oxygen, O2, oxidize iron(II) ion in solution under standard conditions? b Will copper metal reduce 1.0 M Ni2(aq) to metallic nickel?arrow_forward
- One of the few industrial-scale processes that produce organic compounds electrochemically is used by the Monsanto Company to produce1,4-dicyanobutane. The reduction reaction is 2CH2CHCH+2H++2eNC(CH2)4CN The NC(CH2)4CN is then chemically reduced using hydrogen gas to H2N(CH2)6NH2, which is used in the production of nylon. What current must be used to produce 150.kg NC(CH2)4CN per hour?arrow_forwardThree reactions very important to the semiconductor industry are The reduction of silicon dioxide to crude silicon, SiO2(s) + 2 C(s) → Si(s) + 2 CO(g) ΔrH° = 689.9 kJ/mol The formation of silicon tetrachloride from crude silicon, Si(s) + 2 Cl2(g) → SiCl4(g) ΔrH° = −657.01 kJ/mol The reduction of silicon tetrachloride to pure silicon with magnesium, SiCl4(g) + 2 Mg(s) → 2 MgCl2(s) + Si(s) ΔrH° = −625.6 kJ/mol Calculate the overall enthalpy change when 1.00 mol sand, SiO2, changes into very pure silicon by this series of reactions.arrow_forwardSodium perchlorate, NaClO4, is produced by electrolysis of sodium chlorate, NaClO3. If a current of 2.50 103 A passes through an electrolytic cell, how many kilograms of sodium perchlorate are produced per hour?arrow_forward
- Which is the stronger acid, H2SO4 or H2SeO4? Why? You may wish to review the Chapter on acid-base equilibria.arrow_forwardThe molecular weight of sperm whale myoglobin is 17.8 kDa.17.8 kDa. The myoglobin content of sperm whale muscle is about 80 g · kg−1.80 g · kg−1. In contrast, the myoglobin content of some human muscles is about 8 g · kg−1.8 g · kg−1. Compare the amounts of O2O2 bound to myoglobin in human muscle and in sperm whale muscle. Assume that the myoglobin is saturated with O2,O2, and that the molecular weights of human and sperm whale myoglobin are the same. How much O2O2 is bound to myoglobin in human muscle? How much O2O2 is bound to myoglobin in whale muscle? The amount of oxygen dissolved in tissue water at 37°C37°C is about 3.5×10−5 M.3.5×10−5 M. What is the ratio of myoglobin‑bound oxygen to dissolved oxygen in the tissue water of sperm whale muscle?arrow_forwardis Fe2+(aq) + 2OH−(aq) → Fe(OH)2 (s) an oxidation reduction reactionarrow_forward
- Chemistry by OpenStax (2015-05-04)ChemistryISBN:9781938168390Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark BlaserPublisher:OpenStaxGeneral Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage LearningChemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage LearningChemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning
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