General Chemistry: Atoms First
General Chemistry: Atoms First
2nd Edition
ISBN: 9780321809261
Author: John E. McMurry, Robert C. Fay
Publisher: Prentice Hall
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Chapter 20.7, Problem 20.10P

(a)

Interpretation Introduction

Interpretation:

The formula of the given compound has to be written.

Concept Introduction:

IUPAC nomenclature of coordination compounds:

  • Just as in naming simple salts, if the compound is a salt, name the cation first and then the anion.  For example, K3[Fe(CN)6] is potassium hexacyanoferrate (III).
  • In naming a complex ion or a neutral complex, name the ligands first and then the metal.  The names of anionic ligands end in -o.  They are usually obtained by changing the anion endings -ide to -o and -ate to -ato.  Neutral ligands are specified by their usual names, except for H2O, NH3, and CO, which are called aqua, ammine, and carbonyl, respectively.  The name of a complex is one word, with no space between the various ligand names and no space between the names of the last ligand and the metal.
  • If the complex contains more than one ligand of a particular type, indicate the number with the appropriate Greek prefix: di-, tri-, tetra-, penta-, hexa-, and so forth.  The ligands are listed in alphabetical order, and the prefixes are ignored in determining the order. Thus, tetraaqua precedes dichloro in the name for [Cr(H2O)4Cl2]Cl: tetraaquadichlorochromium (III) chloride.
  • If the name of a ligand itself contains a Greek prefix-for example, ethylenediamine - put the ligand name in parentheses and use one of the following alternative prefixes to specify the number of ligands: bis- (2), tris- (3), tetrakis- (4), and so forth.  Thus, the name of [Co(en)3]Cl3 is tris(ethylenediamine)cobalt (III) chloride.
  • Use a Roman numeral in parentheses immediately following the name of the metal to indicate the metal’s oxidation state.
  • In naming the metal, use the ending -ate if the metal is in an anionic complex.  Thus, [Fe(CN)6]3- is the hexacyanoferrate (III) anion.

(b)

Interpretation Introduction

Interpretation:

The formula of the given compound has to be written.

Concept Introduction:

IUPAC nomenclature of coordination compounds:

  • Just as in naming simple salts, if the compound is a salt, name the cation first and then the anion.  For example, K3[Fe(CN)6] is potassium hexacyanoferrate (III).
  • In naming a complex ion or a neutral complex, name the ligands first and then the metal.  The names of anionic ligands end in -o.  They are usually obtained by changing the anion endings -ide to -o and -ate to -ato.  Neutral ligands are specified by their usual names, except for H2O, NH3, and CO, which are called aqua, ammine, and carbonyl, respectively.  The name of a complex is one word, with no space between the various ligand names and no space between the names of the last ligand and the metal.
  • If the complex contains more than one ligand of a particular type, indicate the number with the appropriate Greek prefix: di-, tri-, tetra-, penta-, hexa-, and so forth.  The ligands are listed in alphabetical order, and the prefixes are ignored in determining the order. Thus, tetraaqua precedes dichloro in the name for [Cr(H2O)4Cl2]Cl: tetraaquadichlorochromium (III) chloride.
  • If the name of a ligand itself contains a Greek prefix-for example, ethylenediamine - put the ligand name in parentheses and use one of the following alternative prefixes to specify the number of ligands: bis- (2), tris- (3), tetrakis- (4), and so forth.  Thus, the name of [Co(en)3]Cl3 is tris(ethylenediamine)cobalt (III) chloride.
  • Use a Roman numeral in parentheses immediately following the name of the metal to indicate the metal’s oxidation state.
  • In naming the metal, use the ending -ate if the metal is in an anionic complex.  Thus, [Fe(CN)6]3- is the hexacyanoferrate (III) anion.

(c)

Interpretation Introduction

Interpretation:

The formula of the given compound has to be written.

Concept Introduction:

IUPAC nomenclature of coordination compounds:

  • Just as in naming simple salts, if the compound is a salt, name the cation first and then the anion.  For example, K3[Fe(CN)6] is potassium hexacyanoferrate (III).
  • In naming a complex ion or a neutral complex, name the ligands first and then the metal.  The names of anionic ligands end in -o.  They are usually obtained by changing the anion endings -ide to -o and -ate to -ato.  Neutral ligands are specified by their usual names, except for H2O, NH3, and CO, which are called aqua, ammine, and carbonyl, respectively.  The name of a complex is one word, with no space between the various ligand names and no space between the names of the last ligand and the metal.
  • If the complex contains more than one ligand of a particular type, indicate the number with the appropriate Greek prefix: di-, tri-, tetra-, penta-, hexa-, and so forth.  The ligands are listed in alphabetical order, and the prefixes are ignored in determining the order. Thus, tetraaqua precedes dichloro in the name for [Cr(H2O)4Cl2]Cl: tetraaquadichlorochromium (III) chloride.
  • If the name of a ligand itself contains a Greek prefix-for example, ethylenediamine - put the ligand name in parentheses and use one of the following alternative prefixes to specify the number of ligands: bis- (2), tris- (3), tetrakis- (4), and so forth.  Thus, the name of [Co(en)3]Cl3 is tris(ethylenediamine)cobalt (III) chloride.
  • Use a Roman numeral in parentheses immediately following the name of the metal to indicate the metal’s oxidation state.
  • In naming the metal, use the ending -ate if the metal is in an anionic complex.  Thus, [Fe(CN)6]3- is the hexacyanoferrate (III) anion.

(d)

Interpretation Introduction

Interpretation:

The formula of the given compound has to be written.

Concept Introduction:

IUPAC nomenclature of coordination compounds:

  • Just as in naming simple salts, if the compound is a salt, name the cation first and then the anion.  For example, K3[Fe(CN)6] is potassium hexacyanoferrate (III).
  • In naming a complex ion or a neutral complex, name the ligands first and then the metal.  The names of anionic ligands end in -o.  They are usually obtained by changing the anion endings -ide to -o and -ate to -ato.  Neutral ligands are specified by their usual names, except for H2O, NH3, and CO, which are called aqua, ammine, and carbonyl, respectively.  The name of a complex is one word, with no space between the various ligand names and no space between the names of the last ligand and the metal.
  • If the complex contains more than one ligand of a particular type, indicate the number with the appropriate Greek prefix: di-, tri-, tetra-, penta-, hexa-, and so forth.  The ligands are listed in alphabetical order, and the prefixes are ignored in determining the order. Thus, tetraaqua precedes dichloro in the name for [Cr(H2O)4Cl2]Cl: tetraaquadichlorochromium (III) chloride.
  • If the name of a ligand itself contains a Greek prefix-for example, ethylenediamine - put the ligand name in parentheses and use one of the following alternative prefixes to specify the number of ligands: bis- (2), tris- (3), tetrakis- (4), and so forth.  Thus, the name of [Co(en)3]Cl3 is tris(ethylenediamine)cobalt (III) chloride.
  • Use a Roman numeral in parentheses immediately following the name of the metal to indicate the metal’s oxidation state.
  • In naming the metal, use the ending -ate if the metal is in an anionic complex.  Thus, [Fe(CN)6]3- is the hexacyanoferrate (III) anion.

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Chapter 20 Solutions

General Chemistry: Atoms First

Ch. 20.8 - Prob. 20.11PCh. 20.8 - Prob. 20.12CPCh. 20.9 - Prob. 20.13PCh. 20.9 - Prob. 20.14CPCh. 20.9 - Prob. 20.15PCh. 20.10 - Prob. 20.16PCh. 20.11 - Prob. 20.17PCh. 20.12 - Prob. 20.18PCh. 20.12 - Prob. 20.19PCh. 20.12 - Prob. 20.20PCh. 20.12 - Prob. 20.21PCh. 20 - Prob. 20.22CPCh. 20 - Prob. 20.23CPCh. 20 - Prob. 20.24CPCh. 20 - Prob. 20.25CPCh. 20 - What is the systematic name for each of the...Ch. 20 - Prob. 20.27CPCh. 20 - Prob. 20.28CPCh. 20 - Prob. 20.29CPCh. 20 - Predict the crystal field energy-level diagram for...Ch. 20 - Prob. 20.31CPCh. 20 - Use the periodic table to give the electron...Ch. 20 - Prob. 20.33SPCh. 20 - Prob. 20.34SPCh. 20 - Prob. 20.35SPCh. 20 - Prob. 20.36SPCh. 20 - Prob. 20.37SPCh. 20 - Prob. 20.38SPCh. 20 - Prob. 20.39SPCh. 20 - What is the lanthanide contraction, and why does...Ch. 20 - The atomic radii of zirconium and hafnium are...Ch. 20 - Calculate the sum of the first two ionization...Ch. 20 - Prob. 20.43SPCh. 20 - Prob. 20.44SPCh. 20 - Prob. 20.45SPCh. 20 - Prob. 20.46SPCh. 20 - Prob. 20.47SPCh. 20 - Prob. 20.48SPCh. 20 - Prob. 20.49SPCh. 20 - Prob. 20.50SPCh. 20 - Prob. 20.51SPCh. 20 - Prob. 20.52SPCh. 20 - Prob. 20.53SPCh. 20 - Prob. 20.54SPCh. 20 - Prob. 20.55SPCh. 20 - Write a balanced equation for the industrial...Ch. 20 - Prob. 20.57SPCh. 20 - Prob. 20.58SPCh. 20 - Prob. 20.59SPCh. 20 - Prob. 20.60SPCh. 20 - Prob. 20.61SPCh. 20 - Prob. 20.62SPCh. 20 - Prob. 20.63SPCh. 20 - Prob. 20.64SPCh. 20 - Prob. 20.65SPCh. 20 - Prob. 20.66SPCh. 20 - Prob. 20.67SPCh. 20 - Prob. 20.68SPCh. 20 - Prob. 20.69SPCh. 20 - Prob. 20.70SPCh. 20 - Prob. 20.71SPCh. 20 - Prob. 20.72SPCh. 20 - Prob. 20.73SPCh. 20 - What is the formula of a complex that has each of...Ch. 20 - What is the formula, including the charge, for...Ch. 20 - Prob. 20.76SPCh. 20 - Prob. 20.77SPCh. 20 - Prob. 20.78SPCh. 20 - Prob. 20.79SPCh. 20 - Prob. 20.80SPCh. 20 - Prob. 20.81SPCh. 20 - What is the systematic name for each of the...Ch. 20 - Prob. 20.83SPCh. 20 - Prob. 20.84SPCh. 20 - Prob. 20.85SPCh. 20 - Prob. 20.86SPCh. 20 - Prob. 20.87SPCh. 20 - Prob. 20.88SPCh. 20 - Tell how many diastereoisomers are possible for...Ch. 20 - Which of the following complexes are chiral? (a)...Ch. 20 - Prob. 20.91SPCh. 20 - Prob. 20.92SPCh. 20 - Prob. 20.93SPCh. 20 - Prob. 20.94SPCh. 20 - Prob. 20.95SPCh. 20 - Prob. 20.96SPCh. 20 - Prob. 20.97SPCh. 20 - Prob. 20.98SPCh. 20 - Prob. 20.99SPCh. 20 - Prob. 20.100SPCh. 20 - Prob. 20.101SPCh. 20 - Prob. 20.102SPCh. 20 - Prob. 20.103SPCh. 20 - Prob. 20.104SPCh. 20 - Prob. 20.105SPCh. 20 - For each of the following complexes, draw a...Ch. 20 - Prob. 20.107SPCh. 20 - Prob. 20.108SPCh. 20 - Prob. 20.109SPCh. 20 - Prob. 20.110SPCh. 20 - Prob. 20.111SPCh. 20 - Prob. 20.112SPCh. 20 - Prob. 20.113SPCh. 20 - Prob. 20.114CHPCh. 20 - Prob. 20.115CHPCh. 20 - Prob. 20.116CHPCh. 20 - Prob. 20.117CHPCh. 20 - Prob. 20.118CHPCh. 20 - Prob. 20.119CHPCh. 20 - Prob. 20.120CHPCh. 20 - Prob. 20.121CHPCh. 20 - Prob. 20.122CHPCh. 20 - Prob. 20.123CHPCh. 20 - Prob. 20.124CHPCh. 20 - Draw a crystal field energy-level diagram, and...Ch. 20 - Prob. 20.126CHPCh. 20 - Prob. 20.127CHPCh. 20 - Prob. 20.128CHPCh. 20 - Prob. 20.129CHPCh. 20 - Prob. 20.130CHPCh. 20 - Look at the colors of the isomeric complexes in...Ch. 20 - The amount of paramagnetism for a first-series...Ch. 20 - Prob. 20.133CHPCh. 20 - Prob. 20.134CHPCh. 20 - Prob. 20.135CHPCh. 20 - For each of the following, (i) give the systematic...Ch. 20 - Prob. 20.137CHPCh. 20 - Prob. 20.138CHPCh. 20 - Prob. 20.139MPCh. 20 - Formation constants for the ammonia and...Ch. 20 - Prob. 20.141MPCh. 20 - Prob. 20.143MPCh. 20 - An alternative to cyanide leaching of gold ores is...
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