The example of a complex that has coordination number 2 should be identified. Concept Introduction: Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions. Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond. Monodentate ligand is ligands which donate only one pair of electrons to form bond with metal. It only makes one bond with metal. Polydentate ligand forms two or more coordination bond with metal ions to form a complex. Coordination number: The total number of ligands that forms bond with the metal atom. Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound.

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Answer 1

Question

Chapter 20, Problem 20.70SP

(a)

Interpretation Introduction

Interpretation:

The example of a complex that has coordination number 2 should be identified.

Concept Introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Monodentate ligand is ligands which donate only one pair of electrons to form bond with metal. It only makes one bond with metal. Polydentate ligand forms two or more coordination bond with metal ions to form a complex.

Coordination number: The total number of ligands that forms bond with the metal atom.

Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound.

(b)

Interpretation Introduction

Interpretation:

The example of a complex that has coordination number 4 should be identified.

Concept Introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Monodentate ligand is ligands which donate only one pair of electrons to form bond with metal. It only makes one bond with metal. Polydentate ligand forms two or more coordination bond with metal ions to form a complex.

Coordination number: The total number of ligands that forms bond with the metal atom.

Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound.

(c)

Interpretation Introduction

Interpretation:

The example of a complex that has coordination number 6 should be identified.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Monodentate ligand is ligands which donate only one pair of electrons to form bond with metal. It only makes one bond with metal. Polydentate ligand forms two or more coordination bond with metal ions to form a complex.

Coordination number: The total number of ligands that forms bond with the metal atom.

Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound.

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Consider a solution of 0.00304 moles of 4-nitrobenzoic acid (pKa = 3.442) dissolved in 25 mL water and titrated with 0.0991 M NaOH. Calculate the pH at the equivalence point

Answer 2

Question

Chapter 20, Problem 20.70SP

(a)

Interpretation Introduction

Interpretation:

The example of a complex that has coordination number 2 should be identified.

Concept Introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Monodentate ligand is ligands which donate only one pair of electrons to form bond with metal. It only makes one bond with metal. Polydentate ligand forms two or more coordination bond with metal ions to form a complex.

Coordination number: The total number of ligands that forms bond with the metal atom.

Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound.

(b)

Interpretation Introduction

Interpretation:

The example of a complex that has coordination number 4 should be identified.

Concept Introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Monodentate ligand is ligands which donate only one pair of electrons to form bond with metal. It only makes one bond with metal. Polydentate ligand forms two or more coordination bond with metal ions to form a complex.

Coordination number: The total number of ligands that forms bond with the metal atom.

Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound.

(c)

Interpretation Introduction

Interpretation:

The example of a complex that has coordination number 6 should be identified.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Monodentate ligand is ligands which donate only one pair of electrons to form bond with metal. It only makes one bond with metal. Polydentate ligand forms two or more coordination bond with metal ions to form a complex.

Coordination number: The total number of ligands that forms bond with the metal atom.

Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound.

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Answer 3

Question

Chapter 20, Problem 20.70SP

(a)

Interpretation Introduction

Interpretation:

The example of a complex that has coordination number 2 should be identified.

Concept Introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Monodentate ligand is ligands which donate only one pair of electrons to form bond with metal. It only makes one bond with metal. Polydentate ligand forms two or more coordination bond with metal ions to form a complex.

Coordination number: The total number of ligands that forms bond with the metal atom.

Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound.

(b)

Interpretation Introduction

Interpretation:

The example of a complex that has coordination number 4 should be identified.

Concept Introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Monodentate ligand is ligands which donate only one pair of electrons to form bond with metal. It only makes one bond with metal. Polydentate ligand forms two or more coordination bond with metal ions to form a complex.

Coordination number: The total number of ligands that forms bond with the metal atom.

Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound.

(c)

Interpretation Introduction

Interpretation:

The example of a complex that has coordination number 6 should be identified.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Monodentate ligand is ligands which donate only one pair of electrons to form bond with metal. It only makes one bond with metal. Polydentate ligand forms two or more coordination bond with metal ions to form a complex.

Coordination number: The total number of ligands that forms bond with the metal atom.

Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound.

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Answer 4

Question

Chapter 20, Problem 20.70SP

(a)

Interpretation Introduction

Interpretation:

The example of a complex that has coordination number 2 should be identified.

Concept Introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Monodentate ligand is ligands which donate only one pair of electrons to form bond with metal. It only makes one bond with metal. Polydentate ligand forms two or more coordination bond with metal ions to form a complex.

Coordination number: The total number of ligands that forms bond with the metal atom.

Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound.

(b)

Interpretation Introduction

Interpretation:

The example of a complex that has coordination number 4 should be identified.

Concept Introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Monodentate ligand is ligands which donate only one pair of electrons to form bond with metal. It only makes one bond with metal. Polydentate ligand forms two or more coordination bond with metal ions to form a complex.

Coordination number: The total number of ligands that forms bond with the metal atom.

Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound.

(c)

Interpretation Introduction

Interpretation:

The example of a complex that has coordination number 6 should be identified.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Monodentate ligand is ligands which donate only one pair of electrons to form bond with metal. It only makes one bond with metal. Polydentate ligand forms two or more coordination bond with metal ions to form a complex.

Coordination number: The total number of ligands that forms bond with the metal atom.

Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound.

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Answer 5

Chapter 20, Problem 20.70SP

(a)

Interpretation Introduction

Interpretation:

The example of a complex that has coordination number 2 should be identified.

Concept Introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Monodentate ligand is ligands which donate only one pair of electrons to form bond with metal. It only makes one bond with metal. Polydentate ligand forms two or more coordination bond with metal ions to form a complex.

Coordination number: The total number of ligands that forms bond with the metal atom.

Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound.

(b)

Interpretation Introduction

Interpretation:

The example of a complex that has coordination number 4 should be identified.

Concept Introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Monodentate ligand is ligands which donate only one pair of electrons to form bond with metal. It only makes one bond with metal. Polydentate ligand forms two or more coordination bond with metal ions to form a complex.

Coordination number: The total number of ligands that forms bond with the metal atom.

Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound.

(c)

Interpretation Introduction

Interpretation:

The example of a complex that has coordination number 6 should be identified.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Monodentate ligand is ligands which donate only one pair of electrons to form bond with metal. It only makes one bond with metal. Polydentate ligand forms two or more coordination bond with metal ions to form a complex.

Coordination number: The total number of ligands that forms bond with the metal atom.

Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound.

Answer 6

Chapter 20, Problem 20.70SP

(a)

Interpretation Introduction

Interpretation:

The example of a complex that has coordination number 2 should be identified.

Concept Introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Monodentate ligand is ligands which donate only one pair of electrons to form bond with metal. It only makes one bond with metal. Polydentate ligand forms two or more coordination bond with metal ions to form a complex.

Coordination number: The total number of ligands that forms bond with the metal atom.

Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound.

Answer 7

Chapter 20, Problem 20.70SP

(a)

Interpretation Introduction

Interpretation:

The example of a complex that has coordination number 2 should be identified.

Concept Introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Monodentate ligand is ligands which donate only one pair of electrons to form bond with metal. It only makes one bond with metal. Polydentate ligand forms two or more coordination bond with metal ions to form a complex.

Coordination number: The total number of ligands that forms bond with the metal atom.

Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The example of a complex that has coordination number 4 should be identified.

Concept Introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Monodentate ligand is ligands which donate only one pair of electrons to form bond with metal. It only makes one bond with metal. Polydentate ligand forms two or more coordination bond with metal ions to form a complex.

Coordination number: The total number of ligands that forms bond with the metal atom.

Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The example of a complex that has coordination number 4 should be identified.

Concept Introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Monodentate ligand is ligands which donate only one pair of electrons to form bond with metal. It only makes one bond with metal. Polydentate ligand forms two or more coordination bond with metal ions to form a complex.

Coordination number: The total number of ligands that forms bond with the metal atom.

Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The example of a complex that has coordination number 6 should be identified.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Monodentate ligand is ligands which donate only one pair of electrons to form bond with metal. It only makes one bond with metal. Polydentate ligand forms two or more coordination bond with metal ions to form a complex.

Coordination number: The total number of ligands that forms bond with the metal atom.

Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The example of a complex that has coordination number 6 should be identified.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Monodentate ligand is ligands which donate only one pair of electrons to form bond with metal. It only makes one bond with metal. Polydentate ligand forms two or more coordination bond with metal ions to form a complex.

Coordination number: The total number of ligands that forms bond with the metal atom.

Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound.

Answer 12

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Answer 13

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Answer 15

Ch. 20.1 - Write the electron configuration of the metal in...Ch. 20.1 - Prob. 20.2CP Ch. 20.3 - Prob. 20.3CP Ch. 20.4 - Prob. 20.4P Ch. 20.4 - Prob. 20.5P Ch. 20.5 - Prob. 20.6P Ch. 20.5 - Prob. 20.7P Ch. 20.6 - Prob. 20.8P Ch. 20.7 - Name each of the following: (a) [Cu(NH3)4]SO4, a...Ch. 20.7 - Prob. 20.10P

Solution Summary: The author explains that a complex with coordination number 2 should be identified.

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