The constitutional isomers of [ R u ( N H 3 ) 5 ( N O 2 ) ] C l should be drawn and labelled as linkage isomers and ionization isomers. Concept Introduction: Isomerism: Two chemical compounds are said to be isomers if they have same number and kind of atoms but different only in their orientation that is structural arrangements. Structural or Constitutional isomers: Have same molecular formula but different bonding arrangements of atoms. It is further classified as Linkage and Ionization isomers. Stereoisomers : Differ in their spatial arrangement of atoms. Linkage isomers: The metal bond to ligand via either of two different donor atoms present in ligand. E.g. [ C o ( N H 3 ) 5 ( N O 2 ) ] 2 + a n d [ C o ( N H 3 ) 5 ( O N O ) ] 2 + Ionization isomers: Two compounds which have only difference in their anion bonded to the metal are said to be ionization isomers. E.g. [ C o ( N H 3 ) 5 B r ] S O 4 a n d [ C o ( N H 3 ) 5 S O 4 ] B r

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Chapter 20, Problem 20.86SP

Interpretation Introduction

Interpretation:

The constitutional isomers of [Ru(NH3)5(NO2)]Cl should be drawn and labelled as linkage isomers and ionization isomers.

Concept Introduction:

Isomerism: Two chemical compounds are said to be isomers if they have same number and kind of atoms but different only in their orientation that is structural arrangements.

Structural or Constitutional isomers: Have same molecular formula but different bonding arrangements of atoms. It is further classified as Linkage and Ionization isomers.

Stereoisomers: Differ in their spatial arrangement of atoms.

Linkage isomers: The metal bond to ligand via either of two different donor atoms present in ligand. E.g. [Co(NH3)5(NO2)]2+ and [Co(NH3)5(ONO)]2+

Ionization isomers: Two compounds which have only difference in their anion bonded to the metal are said to be ionization isomers. E.g. [Co(NH3)5Br]SO4 and [Co(NH3)5SO4 ]Br

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