Physical Chemistry
Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
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Chapter 18, Problem 18.40E
Interpretation Introduction

Interpretation:

The values of qrot for NO2(σ=2) at 295K and 400K are to be calculated.

Concept introduction:

The qrot is given by the formula,

qrot=Tσθr

The qrot for polyatomic molecules is given by the formula,

qrot=π1/2σ(T3θr, Aθr, Bθr, C)1/2

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