Physical Chemistry
Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
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Chapter 18, Problem 18.42E
Interpretation Introduction

Interpretation:

Of the heat capacities Cp and CV, the one which is larger is to be stated. Whether this will always be the case or not is to be explained.

Concept introduction:

The H is given by the formula,

H=NkT[(TlnQsysT)V+1]

The Qsys is given by the formula,

Qsys=qrotqtransqvibqnucqele

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