Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
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Question
Chapter 18, Problem 18.57E
Interpretation Introduction
Interpretation:
The vibrational partition function at different temperatures, starting at zero kelvins and going to
Concept introduction:
A molecule is made up of atoms that are bonded together by covalent bonds. These bonds do a to and fro moment to vibrate. This vibration of the molecule contributes to the overall partition function of the system. The vibrational partition function of the diatomic molecule at high temperature is represented as,
Where,
•
•
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For this question, if the product is racemic, input both enantiomers in the same Marvin editor.
A) Input the number that corresponds to the reagent which when added to (E)-but-2-ene will result in a
racemic product.
Input 1 for Cl, in the cold and dark
Input 2 for Oy followed by H₂O, Zn
Input 3 for D₂ with metal catalyst
Input 4 for H₂ with metal catalyst
B) Draw the skeletal structure of the major organic product made from the reagent in part A
Marvin JS
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Edit drawing
C) Draw the skeletal structure of the major organic product formed when (2)-but-2-ene is treated with
peroxyacetic acid.
Marvin 35
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Michael Reactions
19.52 Draw the products from the following Michael addition reactions.
1.
H&C CH
(a)
i
2. H₂O*
(b)
OEt
(c)
EtO
H₂NEt
(d)
ΕΙΟ
+
1. NaOEt
2. H₂O'
H
H
1. NaOEt
2. H₂O*
Rank the labeled protons (Ha-Hd) in order of increasing acidity, starting with the least acidic.
НОН НЬ
OHd
Онс
Chapter 18 Solutions
Physical Chemistry
Ch. 18 - Prob. 18.1ECh. 18 - Prob. 18.2ECh. 18 - Prob. 18.3ECh. 18 - Prob. 18.4ECh. 18 - The following are the first four electronic energy...Ch. 18 - Prob. 18.6ECh. 18 - Prob. 18.7ECh. 18 - Prob. 18.8ECh. 18 - Prob. 18.9ECh. 18 - Prob. 18.10E
Ch. 18 - Prob. 18.11ECh. 18 - Prob. 18.12ECh. 18 - Prob. 18.13ECh. 18 - Prob. 18.14ECh. 18 - Prob. 18.15ECh. 18 - Prob. 18.16ECh. 18 - Prob. 18.17ECh. 18 - Prob. 18.18ECh. 18 - Prob. 18.19ECh. 18 - Prob. 18.20ECh. 18 - Prob. 18.21ECh. 18 - Prob. 18.22ECh. 18 - Prob. 18.23ECh. 18 - Prob. 18.24ECh. 18 - Prob. 18.25ECh. 18 - Prob. 18.26ECh. 18 - Prob. 18.27ECh. 18 - Prob. 18.28ECh. 18 - Prob. 18.29ECh. 18 - Prob. 18.30ECh. 18 - Prob. 18.31ECh. 18 - Prob. 18.32ECh. 18 - Prob. 18.33ECh. 18 - What are qnuc and qrot for N2(I=1)? See Table 18.3...Ch. 18 - The rovibrational spectrum of acetylene, HCCH,...Ch. 18 - Prob. 18.36ECh. 18 - Prob. 18.37ECh. 18 - Prob. 18.38ECh. 18 - Prob. 18.39ECh. 18 - Prob. 18.40ECh. 18 - Prob. 18.41ECh. 18 - Prob. 18.42ECh. 18 - Use equation 18.44 to show that pV=NkT.Ch. 18 - Prob. 18.44ECh. 18 - Determine E,H,G, and S for CH4 at standard...Ch. 18 - Prob. 18.48ECh. 18 - Prob. 18.49ECh. 18 - Calculate the heat capacity of NO2 at 298K and...Ch. 18 - Prob. 18.51ECh. 18 - In Chapters 17 and 18 we have derived expressions...Ch. 18 - Prob. 18.55ECh. 18 - Prob. 18.56ECh. 18 - Prob. 18.57ECh. 18 - Prob. 18.58ECh. 18 - Prob. 18.59ECh. 18 - Prob. 18.60E
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