Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
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Chapter 18, Problem 18.43E
Use equation 18.44 to show that
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For the decomposition reaction of N2O5(g): 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed:
N2O5 NO2 + NO3 (K1) | NO2 + NO3 → N2O5 (k-1) | NO2 + NO3 NO2 + O2 + NO (k2) | NO + N2O51 NO2 + NO2 + NO2 (K3)
→
Give the expression for the acceptable rate.
→
→
(A).
d[N205]
dt
==
2k,k₂[N₂O₂]
k₁+k₁₂
(B).
d[N2O5]
=-k₁[N₂O] + k₁[NO₂] [NO3] - k₂[NO₂]³
dt
(C).
d[N2O5]
=-k₁[N₂O] + k [NO] - k₂[NO] [NO]
d[N2O5]
(D).
=
dt
= -k₁[N2O5] - k¸[NO][N₂05]
dt
Do not apply the calculations, based on the approximation of the stationary state, to make them perform correctly. Basta discard
the 3 responses that you encounter that are obviously erroneous if you apply the formula to determine the speed of a reaction.
For the decomposition reaction of N2O5(g): 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed:
N2O5 NO2 + NO3 (K1) | NO2 + NO3 → N2O5 (k-1) | NO2 + NO3 NO2 + O2 + NO (k2) | NO + N2O51 NO2 + NO2 + NO2 (K3)
→
Give the expression for the acceptable rate.
→
→
(A).
d[N205]
dt
==
2k,k₂[N₂O₂]
k₁+k₁₂
(B).
d[N2O5]
=-k₁[N₂O] + k₁[NO₂] [NO3] - k₂[NO₂]³
dt
(C).
d[N2O5]
=-k₁[N₂O] + k [NO] - k₂[NO] [NO]
d[N2O5]
(D).
=
dt
= -k₁[N2O5] - k¸[NO][N₂05]
dt
Do not apply the calculations, based on the approximation of the stationary state, to make them perform correctly. Basta discard
the 3 responses that you encounter that are obviously erroneous if you apply the formula to determine the speed of a reaction.
R lactam or lactone considering as weak acid or weak base and why
Chapter 18 Solutions
Physical Chemistry
Ch. 18 - Prob. 18.1ECh. 18 - Prob. 18.2ECh. 18 - Prob. 18.3ECh. 18 - Prob. 18.4ECh. 18 - The following are the first four electronic energy...Ch. 18 - Prob. 18.6ECh. 18 - Prob. 18.7ECh. 18 - Prob. 18.8ECh. 18 - Prob. 18.9ECh. 18 - Prob. 18.10E
Ch. 18 - Prob. 18.11ECh. 18 - Prob. 18.12ECh. 18 - Prob. 18.13ECh. 18 - Prob. 18.14ECh. 18 - Prob. 18.15ECh. 18 - Prob. 18.16ECh. 18 - Prob. 18.17ECh. 18 - Prob. 18.18ECh. 18 - Prob. 18.19ECh. 18 - Prob. 18.20ECh. 18 - Prob. 18.21ECh. 18 - Prob. 18.22ECh. 18 - Prob. 18.23ECh. 18 - Prob. 18.24ECh. 18 - Prob. 18.25ECh. 18 - Prob. 18.26ECh. 18 - Prob. 18.27ECh. 18 - Prob. 18.28ECh. 18 - Prob. 18.29ECh. 18 - Prob. 18.30ECh. 18 - Prob. 18.31ECh. 18 - Prob. 18.32ECh. 18 - Prob. 18.33ECh. 18 - What are qnuc and qrot for N2(I=1)? See Table 18.3...Ch. 18 - The rovibrational spectrum of acetylene, HCCH,...Ch. 18 - Prob. 18.36ECh. 18 - Prob. 18.37ECh. 18 - Prob. 18.38ECh. 18 - Prob. 18.39ECh. 18 - Prob. 18.40ECh. 18 - Prob. 18.41ECh. 18 - Prob. 18.42ECh. 18 - Use equation 18.44 to show that pV=NkT.Ch. 18 - Prob. 18.44ECh. 18 - Determine E,H,G, and S for CH4 at standard...Ch. 18 - Prob. 18.48ECh. 18 - Prob. 18.49ECh. 18 - Calculate the heat capacity of NO2 at 298K and...Ch. 18 - Prob. 18.51ECh. 18 - In Chapters 17 and 18 we have derived expressions...Ch. 18 - Prob. 18.55ECh. 18 - Prob. 18.56ECh. 18 - Prob. 18.57ECh. 18 - Prob. 18.58ECh. 18 - Prob. 18.59ECh. 18 - Prob. 18.60E
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