Physical Chemistry
Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
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Chapter 18, Problem 18.58E
Interpretation Introduction

Interpretation:

The value of qrot at 298K term by term is to be calculated. The number of term at which the changed qrot is negligible is to be stated. The repetition of the calculation at 1000K is to be calculated.

Concept introduction:

The energy levels inside a molecules that represents the various possible methods by which a part of a molecule revolves around the bond present between the atoms is known as rotational energy level.

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(4) Determine the vibrational contribution to Cy for one mole of HCN, where ₁ = 2041 cm-¹, v₂ = 712 cm ¹(doubly degenerate), and 3 = 3369 cm¹ at T=298 K, 500 K and T=1000 K.
Calculate realtive population of the two rotational level for HCl at 300K
The diatomic molecule N2 has a rotational constant B(~) = 2.0 cm-1 and a vibrational constant v(~) = 2400 cm-1. The symmetry number for the molecule is 2.  Sorry that I cannot write the symbols properly here for the wavenumber versions of the spectroscopic constants. (a) Suppose that a high-temperature limit for a partition function gives the value q = 0.34. Comment on the value and whether the high-temperature limit is valid.
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