Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
expand_more
expand_more
format_list_bulleted
Concept explainers
Question
Chapter 12, Problem 12.8E
Interpretation Introduction
Interpretation:
Whether the two spin functions
Concept introduction:
For the orthogonality of the two different wavefunctions, the product of the wave functions is integrated over the entire limits. It is expressed by the equation as given below.
Where,
Expert Solution & Answer
Trending nowThis is a popular solution!
Students have asked these similar questions
Since spin can have 2 possible orientations, what does this mean for the degeneracy?
For a He atom in the excited state with atomic electronic configuration 1s1 2s1:
write out the symmetric and antisymmetric spatial wavefunctions. These two are linear combination of ψ1s and ψ2s each with an electron in them.
combine each spatial wavefunction with the appropriate spin wavefunctions for two electrons (there are four of them) such that the total wavefunction is antisymmetric.
The nucleus of a boron-11 atom has a spin (s) quantum number of 3/2. Calculate the magnitude of the spin vector as well as the possible values it can take for the z-component of the spin vector? Is boron-11 a boson or fermion?
Chapter 12 Solutions
Physical Chemistry
Ch. 12 - In the Stern-Gerlach experiment, silver atoms were...Ch. 12 - Prob. 12.2ECh. 12 - Prob. 12.3ECh. 12 - Suppose s=12 for an electron. Into how many parts...Ch. 12 - Using and labels, write two possible...Ch. 12 - List all possible combinations of all four quantum...Ch. 12 - What are the degeneracies of the H atom...Ch. 12 - Prob. 12.8ECh. 12 - a Differentiate between the quantum numbers s and...Ch. 12 - Is the spin orbital 1s for the H atom still...
Ch. 12 - Draw a diagram analogous to Figure 11.15, but now...Ch. 12 - Are mathematical expressions for the following...Ch. 12 - Prob. 12.13ECh. 12 - Prob. 12.14ECh. 12 - a Assume that the electronic energy of Li was a...Ch. 12 - Spin orbitals are products of spatial and spin...Ch. 12 - If 1 and 2 are the individual wavefunctions for...Ch. 12 - Show that the correct behavior of a wavefunction...Ch. 12 - Prob. 12.19ECh. 12 - Why isnt the electron configuration of beryllium,...Ch. 12 - Prob. 12.21ECh. 12 - Write a Slater determinant for the lithide ion,...Ch. 12 - Why does the concept of antisymmetric...Ch. 12 - a Construct Slater determinant wavefunctions for...Ch. 12 - Prob. 12.25ECh. 12 - Prob. 12.26ECh. 12 - Prob. 12.27ECh. 12 - Suppose an electron had three possible values of...Ch. 12 - Using a periodic table or Table 12.1, find the...Ch. 12 - Write an acceptable electron configuration for...Ch. 12 - Prob. 12.31ECh. 12 - Prob. 12.32ECh. 12 - Prob. 12.33ECh. 12 - An anharmonic oscillator has the potential...Ch. 12 - Prob. 12.35ECh. 12 - In a particle-in-a-box having length a, the...Ch. 12 - Prob. 12.37ECh. 12 - Prob. 12.38ECh. 12 - Prob. 12.39ECh. 12 - The Stark effect is the change in energy of a...Ch. 12 - Prob. 12.41ECh. 12 - Prob. 12.42ECh. 12 - Prob. 12.43ECh. 12 - Show that a variation theory treatment of H using...Ch. 12 - Prob. 12.45ECh. 12 - Explain why assuming an effective nuclear charge,...Ch. 12 - Prob. 12.47ECh. 12 - Consider a real system. Assume that a real...Ch. 12 - Prob. 12.49ECh. 12 - Prob. 12.50ECh. 12 - Prob. 12.51ECh. 12 - Prob. 12.52ECh. 12 - State the Born-Oppenheimer approximation in words...Ch. 12 - Prob. 12.54ECh. 12 - Spectroscopy deals with differences in energy...Ch. 12 - Prob. 12.56ECh. 12 - What is the bond order for the lowest excited...Ch. 12 - The helium atom was defined as two electrons and a...Ch. 12 - Explain how we know that the first in equation...Ch. 12 - Prob. 12.60ECh. 12 - Prob. 12.61ECh. 12 - Use molecular orbital arguments to decide whether...Ch. 12 - Prob. 12.63ECh. 12 - Prob. 12.65ECh. 12 - Prob. 12.67ECh. 12 - Prob. 12.68E
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- What is the physical explanation of the difference between a particle having the 3-D rotational wavefunction 3,2 and an identical particle having the wavefunction 3,2?arrow_forwardIs the spin orbital 1s for the H atom still spherically symmetric? Explain your answer.arrow_forwardWhat are the degeneracies of the H atom wavefunctions when spin is accounted for? Give a general formula.arrow_forward
- 13. Write angular, spin and overall momenta of a state described by term ³P2?arrow_forwardDetermine the atomic term symbols for the allowed atomic states of p3 resulting from the coupling of orbital and spin angular momentums.arrow_forward7. Examine the normalized wavefunction for a system (given below). suppose that os are orthonormal eigenfunctions. Which of the following is an acceptable value of c. 1+i) V6 V5 10 3arrow_forward
- Sketch the form of the wavefunctions for the harmonic oscillator with quantum numbers v = 0 and 1. Use a symmetry argument to explain why these two wavefunctions are orthogonal (do not evaluate any integrals).arrow_forwardHow are the wave functions of the two electrons in a He atom constructed from the individual orbital and spin wave functions? Write down the antisymmetric wave function of the configuration in determinantal form that contains both orbital and spin components for Ms=1 in He.arrow_forwardc) What is the ground state energy and wave function of the system, and how can they be interpreted? Explain the difference with respect to the ground state of the particle in 1D box. d) What is the degree of degeneracy in the system, and how do the possible solutions for the same energy differ? Interpret that difference.arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Physical ChemistryChemistryISBN:9781133958437Author:Ball, David W. (david Warren), BAER, TomasPublisher:Wadsworth Cengage Learning,
Physical Chemistry
Chemistry
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Wadsworth Cengage Learning,