Physical Chemistry
Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
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Chapter 12, Problem 12.34E

An anharmonic oscillator has the potential function

V = 1 2 k x 2 + c x 4

where c can be considered a sort of anharmonicity constant. Determine the energy correction to the ground state of the anharmonic oscillator in terms of c , assuming that H ^ ° is the ideal harmonic oscillator Hamiltonian operator. Use the integral table in Appendix 1 in this book.

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Chapter 12 Solutions

Physical Chemistry

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