Concept explainers
Interpretation:
The complete Schrödinger equation for
Concept introduction:
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Chapter 12 Solutions
Physical Chemistry
- Is the uncertainty principle consistent with our description of the wavefunctions of the 1D particle-in-a-box? Hint: Remember that position is not an eigenvalue operator for the particle-in-a-box wavefunctions.arrow_forwardThe de Broglie equation for a particle can be applied to an electron orbiting a nucleus if one assumes that the electron must have an exact integral number of wavelengths as it covers the circumference of the orbit having radius r:n=2r. From this, derive Bohrs quantized angular momentum postulate.arrow_forwardShow that the normalization constants for the general form of the wavefunction =sin(nx/a) are the same and do not depend on the quantum number n.arrow_forward
- Verify that the following wavefunctions are indeed eigenfunctions of the Schrdinger equation, and determine their energy eigenvalues. a =eiKx where V=0 and K is a constant b =eiKx where V=k, k is some constant potential energy, and K is a constant c =2asinxa where V=0.arrow_forwardThe normalized wave function for a particle in a one-dimensional box in which the potential energy is zero is (x)=2/Lsin(nx/L) , where L is the length of the box (with the left wall at x=0 ). What is the probability that the particle will lie between x=0 and x=L/4 if the particle is in its n=2 state?arrow_forwardIn exercise 10.41a, the wavefunction is not normalized. Normalize the wavefunction and verify that it still satisfies the Schrdinger equation. The limits on x are 0 and 2. How does the expression for the energy eigenvalue differ?arrow_forward
- A particle on a ring has a wavefunction =12eim where equals 0 to 2 and m is a constant. Evaluate the angular momentum p of the particle if p=i How does the angular momentum depend on the constant m?arrow_forwardWhat is the probability of finding an electron in the 1s orbital within 0.1A of an Ne9+ nucleus? Compare your answer to the answer to exercise 11.77 and justify the difference.arrow_forwardWrite (x,t)=eiEt/(x) in terms of sine and cosine, using Eulers theorem: ei=cos+isin. What would a plot of (x,t) versus time look like?arrow_forward
- What is the numerical value of the total angular momentum of an electron in an f subshell of an H atom? What is it for an f electron in Li2+?arrow_forwardInstead of x=0 to a, assume that the limits on the 1-D box were x=+(a/2) to (a/2). Derive acceptable wavefunction for this particle-in-a-box. You may have to consult an integral table to determine the normalization constant. What are the quantized energies for the particle?arrow_forwardGraph the first five wavefunctions for the harmonic oscillators and their probabilities. Superimpose these graphs on the potential energy function for a harmonic oscillator and numerically determine the x values of the classical turning points. What is the probability that an oscillator will exist beyond the classical turning points? Do plots of the probability begin to show a distribution as expected by the correspondence principle?arrow_forward
- Physical ChemistryChemistryISBN:9781133958437Author:Ball, David W. (david Warren), BAER, TomasPublisher:Wadsworth Cengage Learning,Principles of Modern ChemistryChemistryISBN:9781305079113Author:David W. Oxtoby, H. Pat Gillis, Laurie J. ButlerPublisher:Cengage LearningChemistry: Matter and ChangeChemistryISBN:9780078746376Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl WistromPublisher:Glencoe/McGraw-Hill School Pub Co