Physical Chemistry
Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
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Chapter 12, Problem 12.35E
Interpretation Introduction

Interpretation:

The reason as to why a perturbation H^=cx3 would not work for an energy correction to a ground-state harmonic oscillator is to be stated.

Concept introduction:

Perturbation theory assumes that a system can be approximated as a known, solvable system. The difference between the known system and system of interest is small and additive. Thus, the Hamiltonian for the real system can be written as given below.

H^system=H^ideal+H^perturb

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Chapter 12 Solutions

Physical Chemistry

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