Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
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Chapter 12, Problem 12.10E
Is the spin orbital
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Chapter 12 Solutions
Physical Chemistry
Ch. 12 - In the Stern-Gerlach experiment, silver atoms were...Ch. 12 - Prob. 12.2ECh. 12 - Prob. 12.3ECh. 12 - Suppose s=12 for an electron. Into how many parts...Ch. 12 - Using and labels, write two possible...Ch. 12 - List all possible combinations of all four quantum...Ch. 12 - What are the degeneracies of the H atom...Ch. 12 - Prob. 12.8ECh. 12 - a Differentiate between the quantum numbers s and...Ch. 12 - Is the spin orbital 1s for the H atom still...
Ch. 12 - Draw a diagram analogous to Figure 11.15, but now...Ch. 12 - Are mathematical expressions for the following...Ch. 12 - Prob. 12.13ECh. 12 - Prob. 12.14ECh. 12 - a Assume that the electronic energy of Li was a...Ch. 12 - Spin orbitals are products of spatial and spin...Ch. 12 - If 1 and 2 are the individual wavefunctions for...Ch. 12 - Show that the correct behavior of a wavefunction...Ch. 12 - Prob. 12.19ECh. 12 - Why isnt the electron configuration of beryllium,...Ch. 12 - Prob. 12.21ECh. 12 - Write a Slater determinant for the lithide ion,...Ch. 12 - Why does the concept of antisymmetric...Ch. 12 - a Construct Slater determinant wavefunctions for...Ch. 12 - Prob. 12.25ECh. 12 - Prob. 12.26ECh. 12 - Prob. 12.27ECh. 12 - Suppose an electron had three possible values of...Ch. 12 - Using a periodic table or Table 12.1, find the...Ch. 12 - Write an acceptable electron configuration for...Ch. 12 - Prob. 12.31ECh. 12 - Prob. 12.32ECh. 12 - Prob. 12.33ECh. 12 - An anharmonic oscillator has the potential...Ch. 12 - Prob. 12.35ECh. 12 - In a particle-in-a-box having length a, the...Ch. 12 - Prob. 12.37ECh. 12 - Prob. 12.38ECh. 12 - Prob. 12.39ECh. 12 - The Stark effect is the change in energy of a...Ch. 12 - Prob. 12.41ECh. 12 - Prob. 12.42ECh. 12 - Prob. 12.43ECh. 12 - Show that a variation theory treatment of H using...Ch. 12 - Prob. 12.45ECh. 12 - Explain why assuming an effective nuclear charge,...Ch. 12 - Prob. 12.47ECh. 12 - Consider a real system. Assume that a real...Ch. 12 - Prob. 12.49ECh. 12 - Prob. 12.50ECh. 12 - Prob. 12.51ECh. 12 - Prob. 12.52ECh. 12 - State the Born-Oppenheimer approximation in words...Ch. 12 - Prob. 12.54ECh. 12 - Spectroscopy deals with differences in energy...Ch. 12 - Prob. 12.56ECh. 12 - What is the bond order for the lowest excited...Ch. 12 - The helium atom was defined as two electrons and a...Ch. 12 - Explain how we know that the first in equation...Ch. 12 - Prob. 12.60ECh. 12 - Prob. 12.61ECh. 12 - Use molecular orbital arguments to decide whether...Ch. 12 - Prob. 12.63ECh. 12 - Prob. 12.65ECh. 12 - Prob. 12.67ECh. 12 - Prob. 12.68E
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- What are the degeneracies of the H atom wavefunctions when spin is accounted for? Give a general formula.arrow_forward3- Consider the atom having the electron configuration 1s 2s2 2p 3s 3p. Assume that the z components of both the orbital and spin angular momenta of the electron in the 3p subshell are positive. What are the quantum numbers that describe the state of this electron? On=3,1= 1, m = 1, s = 1/2 n = 3,1 = 2, m = 1, s = 1/2 On= 3,1= 2, m 2, s =-1/2 On=3,13D 1, m = 2, s = 1/2 On=3,1 1, m = -1, s = 1/2 %3Darrow_forwardSketch the boundary surface of a dx2 −y2 and a py orbital. Be sure to show and label the axes.arrow_forward
- 2. Why can an atom with a singlet spin multiplicity (S=0) have no spin-spin coupling with any other atom?arrow_forward8d7. Before solving the problem please also give a brief explanation of the concept or associated equation(s) and variablesarrow_forwardQ1a) Why electron have spin half value? B) In multiplicity r=2S+1 as we see when S increase r also increase but this violate Pauli exclusion principle. Why?arrow_forward
- Consider the ground-state electron configurations of the atoms with the following atomic numbers: 7, 20, 26, 32, 37, 41, 85, 96. Calculate the total spin quantum number S for each, as well as its magnetic moment in Bohr magnetons.arrow_forwardThe wavefunction of one of the d orbitals is proportional to sin2θ sin 2ϕ. At what angles does it have nodal planes?arrow_forward1. Give the ground-state electron configuration for V2+ and write its Russell-Saunders term symbol. Also, what is the degeneracy?arrow_forward
- What is the answerarrow_forwardProve that the ground state for He2+ has a spin multiplicity = 2arrow_forward7. Examine the normalized wavefunction for a system (given below). suppose that os are orthonormal eigenfunctions. Which of the following is an acceptable value of c. 1+i) V6 V5 10 3arrow_forward
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