H CH تنی Cl 1. NaCN, DMF 2. LIAIH4, ether H₂O pyridine N NH₂ 5 CH H 1 HNO, H₂SO 2. Nal NH2 Br Br HNO₂ CuCl H₂SO HCI CH3 H3C NN HSO KCN CuCN 1. HNO₂, H₂SO O₂N NH2 2. OH ཀ་ལས། །ས་ཅན་ :i་དེ་མ་མ་སེ་ NH₂ CH3 1. HNO₂, H₂SO4 2. H3PO₂ 1 HNO2, H2SO4 2. Nal ive the major organic product(s) of each of the following reactions or sequences of reactions. Show all rant stereochemistry. [10 only] A. B. NaN3 1. LiAlH4, ether Br 2. H₂O CH3 HNO3 H₂/Pt H₂SO ethanol C. 0 0 CH3CC1 NaOH NHCCH AICI H₂O . NH₂ CH3CH2 N CH2CH3 + HCI CH₂CH 3 1. LIAIH, THE 2. H₂O

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter30: Orbitals And Organic Chemistry: Pericyclic Reactions
Section30.SE: Something Extra
Problem 36AP
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H
CH
تنی
Cl
1. NaCN, DMF
2. LIAIH4, ether
H₂O
pyridine
N
NH₂
5
CH
H
1 HNO, H₂SO
2. Nal
NH2
Br
Br
HNO₂
CuCl
H₂SO
HCI
CH3
H3C
NN HSO
KCN
CuCN
1. HNO₂, H₂SO
O₂N
NH2
2.
OH
ཀ་ལས། །ས་ཅན་ :i་དེ་མ་མ་སེ་
NH₂
CH3
1. HNO₂, H₂SO4
2. H3PO₂
1 HNO2, H2SO4
2. Nal
Transcribed Image Text:H CH تنی Cl 1. NaCN, DMF 2. LIAIH4, ether H₂O pyridine N NH₂ 5 CH H 1 HNO, H₂SO 2. Nal NH2 Br Br HNO₂ CuCl H₂SO HCI CH3 H3C NN HSO KCN CuCN 1. HNO₂, H₂SO O₂N NH2 2. OH ཀ་ལས། །ས་ཅན་ :i་དེ་མ་མ་སེ་ NH₂ CH3 1. HNO₂, H₂SO4 2. H3PO₂ 1 HNO2, H2SO4 2. Nal
ive the major organic product(s) of each of the following reactions or sequences of reactions. Show all
rant stereochemistry. [10 only]
A.
B.
NaN3
1. LiAlH4, ether
Br
2. H₂O
CH3
HNO3
H₂/Pt
H₂SO ethanol
C.
0
0
CH3CC1
NaOH
NHCCH
AICI
H₂O
.
NH₂
CH3CH2 N CH2CH3 + HCI
CH₂CH 3
1. LIAIH, THE
2. H₂O
Transcribed Image Text:ive the major organic product(s) of each of the following reactions or sequences of reactions. Show all rant stereochemistry. [10 only] A. B. NaN3 1. LiAlH4, ether Br 2. H₂O CH3 HNO3 H₂/Pt H₂SO ethanol C. 0 0 CH3CC1 NaOH NHCCH AICI H₂O . NH₂ CH3CH2 N CH2CH3 + HCI CH₂CH 3 1. LIAIH, THE 2. H₂O
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