Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question
![**Instructions:**
Draw the major product of the following reactions and include stereochemistry in the products.
**Reactions:**
1. **Starting Material:**
- Structure: Alcohol (OH group on a butane chain with branching on the second carbon).
- Reagents:
- PBr₃
- pyridine
2. **Starting Material:**
- Structure: Cyclohexyl alcohol with a methyl group on the axial position.
- Reagents:
- 1. TsCl/pyr.
- 2. NaCN
3. **Starting Material:**
- Structure: Isobutylene.
- Reagent: HI
4. **Starting Material:**
- Structure: 2-methylcyclopentanol with an oxygen atom and two axial positions (H and CH₃).
- Reagents:
- CH₃OH
- H₂SO₄
5. **Starting Material:**
- Structure: 2-methylcyclopentanol with an oxygen atom and two axial positions (H and CH₃).
- Reagents:
- 1. CH₃Li
- 2. H⁺, H₂O
6. **Starting Material:**
- Structure: 1-bromobutene (Br attached to terminal alkene).
- Reagent: (CH₃)₂CuLi
7. **Starting Material:**
- Structure: Tert-butylamine derivative with N(CH₃)₂.
- Reagents:
- 1. H₂O₂
- 2. Δ (heat)](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F10a1fb44-7f5a-4451-bc78-c0dfe8b374b6%2F96b05b1b-0e72-4fb0-b319-d037c095eb7a%2Fdd2iwep_processed.jpeg&w=3840&q=75)
Transcribed Image Text:**Instructions:**
Draw the major product of the following reactions and include stereochemistry in the products.
**Reactions:**
1. **Starting Material:**
- Structure: Alcohol (OH group on a butane chain with branching on the second carbon).
- Reagents:
- PBr₃
- pyridine
2. **Starting Material:**
- Structure: Cyclohexyl alcohol with a methyl group on the axial position.
- Reagents:
- 1. TsCl/pyr.
- 2. NaCN
3. **Starting Material:**
- Structure: Isobutylene.
- Reagent: HI
4. **Starting Material:**
- Structure: 2-methylcyclopentanol with an oxygen atom and two axial positions (H and CH₃).
- Reagents:
- CH₃OH
- H₂SO₄
5. **Starting Material:**
- Structure: 2-methylcyclopentanol with an oxygen atom and two axial positions (H and CH₃).
- Reagents:
- 1. CH₃Li
- 2. H⁺, H₂O
6. **Starting Material:**
- Structure: 1-bromobutene (Br attached to terminal alkene).
- Reagent: (CH₃)₂CuLi
7. **Starting Material:**
- Structure: Tert-butylamine derivative with N(CH₃)₂.
- Reagents:
- 1. H₂O₂
- 2. Δ (heat)
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