Choose the BEST reagent for carrying out each of the following conversions.A.CO₂CH3CO₂CH30CO₂Ha.LiAlH4, etherC.CrO3, pyridineB.0Ha.C.NaBH4, ethanolNaOH, H2OCO₂HOHHDb. NaBH4, ethanold. H₂/PdCH₂OHb. CH₂PPh3d. All of the above

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Answered: Choose the BEST reagent for carrying…

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Choose the correct product for each reaction. A. B. C. D. PPh3 H PPh3 || I ။
CH2 H3C H3C COOH Reagents e. PB13 f. NaCN then H3O* g. NBS, CCI4 h. CrO3, H2SO4 а. HBr b. Mg, ether c. CO2, ether then H3O* d. BH3, THF then H2O2, OH"
What is the product? CALA © B. C OC. D OD. B MeO₂C A. CO₂Me H MeO₂C. ಚಿಕ C. MeO₂C B. MeO₂C. D.
Reagents a. C6H5CHO b. NaOH, ethanol h. BrCH2CH=CH2 i. Na* OEt, ethanol j. Br2, H* k. K* t-BuO c. Pyrrolidine, cat. H* d. H2C=CHCN e. H3O* f. I. CH2(CO2ET)2 -CH2CH2CN LDA m. heat g. ELOC(=0)CO2ET Select reagents from the table to synthesize this compound from cyclopentanone. Enter the letters of the chosen reagents, in the order that you wish to use them, without spaces or punctuation (i.e. geda).
None
3. Reactions H3C OH [0] CH3 H3C OH H2 .C. CH CH [0] H2C CH3 H2C-CH2 CH3 CH HO H,SO4 H2C CH H2C-CH2
chose the best reagent for carrying out the conversion
H₂N. Structure 1 ОН H₂N .OH Structure 2 HaN. Reaction Bank: Reaction A: 'N' لز (H3CC" Reaction B: DCCD, HCI Reaction C: CF3CO2H ہ C(CH3)3 OH
H₂C N. catalytic HCI
Choose the correct product of this reaction. H3C H3C CH3 1. excess KMnO,/NaOH/water 2. НО H3C H3C CH3 H3C CH3 H3C H3C C CH3 H3C CH3 H3C. ÇOOH COOH СООН CHO HO. C D. B. て

Qb 18.
Reagents m. 2 equivalents of NaNH2 H2, Lindlar's catalyst Na / NH3 p. H2SO4, HgSO4 q. (sia)2BH then H2O2, NaOH 1 equivalent of NaNH2 a. HCI b. HBr n. c. H20, H2SO4 d. Br2 0. n Cl2 е. H2, Pd g. Br2, H20 h. Cl2, H2O f. r. compound a Os04 then NaHSO3 j. Hg(OAc)2, H20 then NABH4 k. BH3 then H2O2, NaOH Oz then (CH3)2S i. compound b I. The above synthesis was designed using the Organic Chemistry Roadmaps in the appendix of your textbook. In this synthesis, reagents from the table (shown in blue) are used to carry out the indicated reactions. In the box below, draw the structure of compound b. • Use the wedge/hash bond tools to indicate stereochemistry where it exists. • Consider E/Z stereochemistry of alkenes. • If more than one structure fits the description, draw them all. • If a compound is formed more than once, add another sketcher and draw it again. • If the reaction produces a racemic mixture, draw both stereoisomers. Separate structures with + signs from the drop-down menu.

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Choose the BEST reagent for carrying out each of the following conversions. A. CO₂CH3 CO₂CH3 0 CO₂H a. LiAlH4, ether C. CrO3, pyridine B. 0 H a. C. NaBH4, ethanol NaOH, H2O CO₂H OH HD b. NaBH4, ethanol d. H₂/Pd CH₂OH b. CH₂PPh3 d. All of the above